Bis[tris(1-methyl-1H-imidazol-2-yl)phosphine-3N3]iron(II) tetrachloroferrate(II) methanol tetrasolvate (ca 153 K) and bis[tris(1-methyl-1H-imidazol-2-yl)methanol-3N3]iron(III) bis[tetrachloroferrate(III)] chloride (redetermination, ca 153 K)

Batten, M. P. and Canty, A.J. and Cavell, K. J. and Ruther, T. and Skelton, B.W. and White, A.H. (2004) Bis[tris(1-methyl-1H-imidazol-2-yl)phosphine-3N3]iron(II) tetrachloroferrate(II) methanol tetrasolvate (ca 153 K) and bis[tris(1-methyl-1H-imidazol-2-yl)methanol-3N3]iron(III) bis[tetrachloroferrate(III)] chloride (redetermination, ca 153 K). Acta Crystallographica Section C, C60 . m311-m313. ISSN 0108-2701

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Official URL: http://dx.doi.org/10.1107/S0108270104010893

Abstract

The ®rst of the title compounds, [Fe(C12H15N6P)2][FeCl4]- 4CH4O, is the ®rst homoleptic bis(ligand)iron(II) species reported for this phosphorus bridgehead ligand; interestingly, the complex is isomorphous with its tris(1-methyl-1H-imidazol-2-yl)methanol counterpart, the second of the title compounds, [Fe(C13H16N6O)2][FeCl4]2Cl. In both compounds, the Fe atom of the cation lies on an inversion centre. The structure determinations presented here allow an interesting comparison of iron(II) and iron(III) species in similar coordination environments.

Item Type:	Article
Additional Information:	"The definitive version is available at www.blackwell-synergy.com"
Subjects:	250000 Chemical Sciences > 250200 Inorganic Chemistry > 250201 Transition Metal Chemistry
Collections:	UNSPECIFIED
ID Code:	2783
Deposited By:	Prof Allan J Canty
Deposited On:	21 Dec 2007 14:35
Last Modified:	01 Feb 2008 14:14
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