Chloro(phenyl)(1H-pyrazole-KN2)-(triphenylphosphine-KP)palladium(II)

Canty, A.J. and Skelton, B.W. and White, A.H. (2004) Chloro(phenyl)(1H-pyrazole-KN2)-(triphenylphosphine-KP)palladium(II). Acta Crystallographica Section C, C60 . m405-m406. ISSN 0108-2701

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Official URL: http://dx.doi.org/10.1107/S010827010401491X

Abstract

In the title compound, [Pd(C6H5)Cl(C3H4N2){P(C6H5)3}], PdClPh(pyrazole)(PPh3), the phenyl and Cl ligands lie mutually trans. The compound is the first structurally characterized complex with four monodentate Cl, P, N and (non-carbenoid) C ligands in a squareplanar four-coordinate palladium(II) environment. The pyrazole ligand is coplanar with the latter array. The pyrazole NH group forms a bifurcated hydrogen bond to Cl, with an intra and intermolecular component.

Item Type:	Article
Additional Information:	"The definitive version is available at www.blackwell-synergy.com"
Subjects:	250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry
Collections:	UNSPECIFIED
ID Code:	2784
Deposited By:	Prof Allan J Canty
Deposited On:	21 Dec 2007 14:52
Last Modified:	01 Feb 2008 14:10
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