Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)-methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine)(PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes[Mo(CO)4(L2-N,N')]

Batten, M. P. and Canty, A.J. and Cavell, K. J. and Skelton, B.W. and White, A.H. (2006) Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)-methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine)(PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes[Mo(CO)4(L2-N,N')]. Zeitschrift fur Anorganische und Allgemein Chemie, 632 (5). pp. 876-878. ISSN 0044-2313

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Official URL: http://dx.doi.org/10.1002/zaac.200500531

Abstract

The complexes [Mo(CO)4(L2-N,N')] [L2 = 1-methylimidazol- 2-yl(pyridin-2-yl)methanone and 1-benzylimidazol-2-yl(1- phenylaldimine)] have been synthesized from hexacarbonylmolybdenum(0) in order to define the coordination characteristics of the bidentate nitrogen-donor ligands; the complexes exhibit distorted octahedral coordination for molybdenum(0) and cis-bidentate ligand configurations.

Item Type:	Article
Additional Information:	"Submitted to/accepted for publication in (Zeitschrift fur Anorganische und Allgemein Chemie) (2006) WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",
Keywords:	Molybdenum; Carbonyl; Imidazole; Crystal structure
Subjects:	250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry
Collections:	UNSPECIFIED
ID Code:	2788
Deposited By:	Prof Allan J Canty
Deposited On:	02 Jan 2008 12:18
Last Modified:	01 Feb 2008 14:12
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