Synthesis and Structure of Potassium 1-Benzylimidazole-2-carboxylate·2/3Hydrate

Batten, M. P. and Canty, A.J. and Cavell, K. J. and Skelton, B.W. and White, A.H. (2006) Synthesis and Structure of Potassium 1-Benzylimidazole-2-carboxylate·2/3Hydrate. Zeitschrift fur Anorganische und Allgemein Chemie, 632 . pp. 655-658.

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Official URL: http://dx.doi.org/10.1002/zaac.200500519

Abstract

The title compound, K[bimCO2]·2/3H2O (C11H19N2O2K· 2/3H2O), has been synthesized, and characterized by a single crystal X-ray study; it has the grouping [K3(bimCO2)3(OH2)2] cross-linked into a polymeric sheet in which potassium environments are diverse and unsymmetrical, containing six-coordinate and seven-coordinate geometries.

Item Type:	Article
Additional Information:	Submitted to/accepted for publication in Zeitschrift fur Anorganische und Allgemein Chemie 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Keywords:	Potassium; Imidazole; Benzimidazole; Benzimidazole carboxylate; Bidentate Ligand; Crystal Structure
Subjects:	250000 Chemical Sciences > 250300 Organic Chemistry > 250301 Organic Chemical Synthesis
Collections:	UNSPECIFIED
ID Code:	2789
Deposited By:	Prof Allan J Canty
Deposited On:	04 Jan 2008 08:10
Last Modified:	01 Feb 2008 14:10
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