Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(p-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy=2,2'-bipyridine)

Casado Lacabra, M.A. and Canty, A.J. and Lutz, M. and Patel, J. and Spek, A.L. and Sun, H. and van Koten, G. (2002) Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(p-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy=2,2'-bipyridine). Inorganica Chimica Acta, 327 (1). pp. 15-19. ISSN 0020-1693

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Official URL: http://dx.doi.org/10.1016/S0020-1693(01)00681-8

Abstract

The complex trans-PtCl(p-Tol)(SEt2)2 is obtained from the reaction of [Pt(p-Tol)2(SEt2)]2 with PtCl2(SEt2)2 and SEt2 in mole ratio 1:2:2. The mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide react with 2,2'-bipyridine to form the complexes PtX(p-Tol)(bpy) (X=p-Tol, Cl) and are useful reagents for organoplatinum chemistry. X-ray crystal structures are presented for square planar PtCl(p-Tol)(bpy) and the centrosymmetric dimer [Pt(p-Tol)2(mu-SEt2)]2.

Item Type:	Article
Additional Information:	The definitive version is available at http://www.sciencedirect.com
Keywords:	Organoplatinum; 2,2-Bipyridine; Diethylsulfide; Crystal structures
Subjects:	250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry
ID Code:	2793
Deposited By:	Prof Allan J Canty
Deposited On:	04 Jan 2008 09:19
Last Modified:	09 Jan 2008 02:30
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