Arylation of palladium(II) and platinum(II) by diphenyliodonium triflate to form metal(IV) species, and a structural analysis of an isomer of PtIMe2Ph(bpy) (bpy = 2,2’-bipyridine)

Bayler, A. and Canty, A.J. and Ryan, J.H. and Skelton, B.W. and White, A.H. (2000) Arylation of palladium(II) and platinum(II) by diphenyliodonium triflate to form metal(IV) species, and a structural analysis of an isomer of PtIMe2Ph(bpy) (bpy = 2,2’-bipyridine). Inorganic Chemistry Communications, 3 (11). pp. 575-578. ISSN 1387-7003

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Official URL: http://dx.doi.org/10.1016/S1387-7003(00)00144-1

Abstract

The first example of aryl transfer to palladium(II) with concomitant oxidation to palladium(IV) is reported, utilising the reaction of PdMe2(bpy) (bpy = 2,2’-bipyridine)with [IPh2][O3SCF3], together with studies of an analogous platinum system and a structural analysis of trans-PtIMe2Ph(bpy) (bpy = 2,2’-bipyridine).

Item Type:	Article
Additional Information:	The definitive version is available at http://www.sciencedirect.com
Keywords:	Organopalladium(IV); Organoplatinum(IV); Iodonium; Exchange reactions
Subjects:	250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry
ID Code:	2810
Deposited By:	Prof Allan J Canty
Deposited On:	09 Jan 2008 15:37
Last Modified:	09 Jan 2008 15:38
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