Synthesis of the First Organopalladium(IV) Cations, including the First X-Ray Study of Isostructural Organopalladium(IV) and Platinum(IV) Complexes, [fac-MMe3{tris(pyrazol-1-yI)methane-N,N’,N’’ }]I

Byers, P.K. and Canty, A.J. and Skelton, B.W. and White, A.H. (1987) Synthesis of the First Organopalladium(IV) Cations, including the First X-Ray Study of Isostructural Organopalladium(IV) and Platinum(IV) Complexes, [fac-MMe3{tris(pyrazol-1-yI)methane-N,N’,N’’ }]I. Chemical Communications . pp. 1093-1095. ISSN 1359-7345

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Official URL: http://dx.doi.org/10.1039/C39870001093

Abstract

Stable organopalladium(IV) complexes [fac-PdMe3(L)]1 (L = tridentate nitrogen donor ligand) are formed on oxidative addition of iodomethane to PdMe2(L); the tris(pyrazo1-1-yl)methane complex is isostructural with the platinum(IV) analogue.

Item Type:	Article
Subjects:	250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry
ID Code:	2859
Deposited By:	Prof Allan J Canty
Deposited On:	14 Jan 2008 11:35
Last Modified:	14 Jan 2008 11:35
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