Platinum-Tin Bonded Complexes, Including a Structural Analysis of the Octahedral Tris(pyrazol-1-yl)borate Complex Pt(SnMe3)Me2{(pz)3BH-N,N',N"}

Canty, A.J. and Jin, H. and Skelton, B.W. and White, A.H. (1999) Platinum-Tin Bonded Complexes, Including a Structural Analysis of the Octahedral Tris(pyrazol-1-yl)borate Complex Pt(SnMe3)Me2{(pz)3BH-N,N',N"}. Australian Journal of Chemistry, 52 (5). pp. 417-419. ISSN 0004-9425

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Abstract

The platinum(II) complex K[PtMe2{(pz)3BH-N,N'}] reacts with SnCl2Me2 to form Pt(SnClMe2)Me2{(pz)3BH-N,N',N"} ([(pz)3BH]- =tris(pyrazol-1-yl)borate). The closely related complex Pt(SnMe3)Me2{(pz)3BH-N,N',N"} has distorted octahedral geometry for platinum with Pt-Sn 2.5727(8) A. The Pt-N distance trans to the SnMe3 group [2.237(7) A] is longer than those trans to the Me groups [2.127(7) and 2.131(6) A], indicating for the trimethylstannyl group a trans influence which is higher than that for the methyl group.

Item Type:	Article
Subjects:	250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry
ID Code:	2879
Deposited By:	Prof Allan J Canty
Deposited On:	16 Jan 2008 09:11
Last Modified:	16 Jan 2008 09:11
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