The Oxidative Addition of Iodomethane to [PdMe2(bpy)] and the X-Ray Structure of the Organopalladium(IV) Product fac-[PdMe3(bpy)l] (bpy = 2,2'-bipyridyl)

Byers, P.K. and Canty, A.J. and Skelton, B.W. and White, A.H. (1986) The Oxidative Addition of Iodomethane to [PdMe2(bpy)] and the X-Ray Structure of the Organopalladium(IV) Product fac-[PdMe3(bpy)l] (bpy = 2,2'-bipyridyl). Journal of the Chemical Society, Chemical Communications, 23 . pp. 1722-1724. ISSN 1359-7345

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Official URL: http://dx.doi.org/10.1039/C39860001722

Abstract

Oxidative addition of iodomethane to dimethyl(2,2'-bipyridyl)palladium(II) in acetone has resulted in isolation of the first hydrocarbylpalladium(IV) complex, fac-trimethyl(2,2'-bipyridyl)iodopalladium(IV); the complex has been structurally characterized, and reductively eliminates ethane in solution to form methyl(2,2'-bipyridy1)iodopalladium(II).

Item Type:	Article
Subjects:	250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry
Collections:	UNSPECIFIED
ID Code:	2906
Deposited By:	Prof Allan J Canty
Deposited On:	29 Jan 2008 11:51
Last Modified:	29 Jan 2008 11:51
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