Methylmercury(II) Derivatives of Pyridine-2(1H)-thione

Canty, A.J. and Marker, A. (1976) Methylmercury(II) Derivatives of Pyridine-2(1H)-thione. Australian Journal of Chemistry, 29 (6). pp. 1383-1387. ISSN 0004-9425

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Abstract

Methylmercuric nitrate reacts with pyridine-2(lH)-thione (C5H5NS) in acetone to give methyl(pyridine-2(1H)-thione)mercury(II) nitrate, [MeHg(C5H5NS)]NO3. This complex reacts with sodium bicarbonate in acetone to give methyl(pyridine-2-thiolato)mercury(II), MeHg(C5H4NS). Infrared, Raman, and nuclear magnetic resonance spectra indicate that MeHg(II) is bonded to sulphur in both complexes, and that protonation of nitrogen occurs on reaction of MeHg(C5H4NS) with nitric acid to give [MeHg(C5H5NS)]NO3.

Item Type:	Article
Subjects:	250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry
Collections:	UNSPECIFIED
ID Code:	2923
Deposited By:	Prof Allan J Canty
Deposited On:	30 Jan 2008 13:59
Last Modified:	30 Jan 2008 13:59
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