High Co-ordination Numbers for Methylmercury(II); X-Ray and 1H N.M.R. Studies of [MeHgL]NO3 (L = 4,4’,4”-Triethyl-2,2’:6’,2”-terpyridyl and Di-2-pyridylmethane)

Canty, A.J. and Hayhurst, G. and Chaichit, N. and Gatehouse, B.M. (1980) High Co-ordination Numbers for Methylmercury(II); X-Ray and 1H N.M.R. Studies of [MeHgL]NO3 (L = 4,4’,4”-Triethyl-2,2’:6’,2”-terpyridyl and Di-2-pyridylmethane). Journal of the Chemical Society, Chemical Communications, 7 . pp. 316-318. ISSN 1477-9226

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Official URL: http://dx.doi.org/10.1039/C39800000316

Abstract

Methylmercury(II) forms complexes [MeHgL]NO3 (L = 2,2’: 6’,2”-terpyridyls and di-2-pyridylmethane) where the ligands L are bidentate in methanol, but tridentate and bidentate, respectively, in the solid state with co-ordination geometries for mercury based on a near linear dominant C-Hg-N unit with additional weak Hg-N bonding.

Item Type:	Article
Subjects:	250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry
Collections:	UNSPECIFIED
ID Code:	2937
Deposited By:	Prof Allan J Canty
Deposited On:	06 Feb 2008 09:27
Last Modified:	06 Feb 2008 09:27
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