Interaction of MeSHgO2CMe with Imidazole and Related Ligands
Canty, A.J. and Tyson, R.K. (1978) Interaction of MeSHgO2CMe with Imidazole and Related Ligands. Inorganica Chimica Acta, 29 . pp. 227-230. ISSN 0020-1693 | PDF - Full text restricted - Requires a PDF viewer 382Kb | |
Official URL: http://dx.doi.org/10.1016/S0020-1693(00)89652-8 AbstractThe complex methanethiolatomercury(II) acetate, MeSHgO2Me, reacts with imidazole (LH) in 1:l or 2:1 mol ratio in water at low pH to form a complex of stoichiometry (MeSHg)2(O2CMe)(L), but in the absence of acetic acid forms
a new phase of bis(methanethiolato)mercury(II), Hg(SMe)2. Stirred suspensions of MeSHgO2CMe with imidazole or 2-methylimidazole in 1:l mol ratio in ethanol form (MeSHg)2(O2CMe)(L) and the 2-methylimidazole analogue. Solutions
of MeSHgO2CMe or the new phase of Hg(SMe)2 in
N-methylimidazole deposit crystals of the previously
known phase of Hg(SMe)2. Repository Staff Only: item control page
|