Weak Intramolecular Pi Coordination to Methylmercury(II). Structure of (2-Benzylpyridine)methylmercury(II) Nitrate

Canty, A.J. and Chaichit, N. and Gatehouse, B.M. (1980) Weak Intramolecular Pi Coordination to Methylmercury(II). Structure of (2-Benzylpyridine)methylmercury(II) Nitrate. Acta Crystallographica Section B-Structural, B36 (P4). pp. 786-789. ISSN 0108-7681

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Official URL: http://dx.doi.org/10.1107/S0567740880004530

Abstract

The title complex, [Hg(CH3)(C12HllN)]N03,C13HI4HgN+.N03-, has a linear C-Hg-N group with Hg-C 2·07(3) and Hg-N 2·10(2) A; there is a weak intramolecular pi interaction between Hg and a C=C bond of the phenyl ring with Hg-C distances of 3·23(2) and 3·33(3) A.

Item Type:	Article
Additional Information:	The definitive version is available at www.blackwell-synergy.com
Subjects:	250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry
Collections:	UNSPECIFIED
ID Code:	3089
Deposited By:	Prof Allan J Canty
Deposited On:	06 Feb 2008 09:09
Last Modified:	06 Feb 2008 09:09
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