Crystal and Molecular Structure of (3,3'-Dimethyl-2,2'-bipyridyl)methylmercury(II) Nitrate; a Complex That May Have Weak Intramolecular Pi-Coordination

Canty, A.J. and Chaichit, N. and Gatehouse, B.M. and Marker, A. (1978) Crystal and Molecular Structure of (3,3'-Dimethyl-2,2'-bipyridyl)methylmercury(II) Nitrate; a Complex That May Have Weak Intramolecular Pi-Coordination. Acta Crystallographica Section B-Structural, B34 . pp. 3229-3233. ISSN 0108-7681

PDF - Full text restricted - Requires a PDF viewer
287Kb

Official URL: http://dx.doi.org/10.1107/S0567740878010559

Abstract

The title complex, C13H15HgN3O3, has a bent C(1)-Hg-N(1) group [172·7(5)] with Hg-C(l) 2·01(1) and Hg-N(1) 2·11(1) A, weak interaction between Hg and nitrate oxygen atoms, and evidence suggesting the presence of a weak intramolecular pi-interaction between Hg and the second pyridyl ring, with Hg-C(2') 3·11(1), Hg-N(1') 3·29(1) A and an angle of 100· 5 between the planes of the pyridyl rings.

Item Type:	Article
Additional Information:	The definitive version is available at www.blackwell-synergy.com
Subjects:	250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry
Collections:	UNSPECIFIED
ID Code:	3090
Deposited By:	Prof Allan J Canty
Deposited On:	05 Feb 2008 10:31
Last Modified:	05 Feb 2008 10:31
ePrint Statistics:	View statistics for this ePrint

Repository Staff Only: item control page