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- <meta content="Chang, Z." name="eprints.creators_name" />
- <meta content="Vervoort, J. D." name="eprints.creators_name" />
- <meta content="McClelland, W. C." name="eprints.creators_name" />
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- <meta content="In this study we used LA-ICP-MS (laser ablation-inductively coupled plasma-mass spectrometry) to
- determine U-Pb ages of 5 zircon samples of known age (1800 Ma to 50 Ma) in order to determine the
- reproducibility, precision, and accuracy of this geochronologic technique. This work was performed using
- a ThermoFinnigan Element2 magnetic sector double-focusing ICP-MS coupled with a New Wave
- Research UP-213 laser system. The laser ablation pit sizes ranged from 30 to 40 mm in diameter. Laserinduced
- time-dependent fractionation is corrected by normalizing measured ratios in both standards and
- samples to the beginning of the analysis using the intercept method. Static fractionation, including those
- caused during laser ablation and due to instrumental discrimination, is corrected using external zircon
- standards. Total uncertainty for each laser analysis of an unknown is combined quadratically from the
- uncertainty in the measured isotope ratios of the unknown and the uncertainty in the fractionation factors
- calculated from the measurement of standards. For individual analyses we estimate that the accuracy and
- precision are better than 4% at the 2 sigma level, with the largest contribution in uncertainty from the
- measurement of the standards. Accuracy of age determinations in this study is on the order of 1% on the
- basis of comparing the weighted average of the LA-ICP-MS determinations to the TIMS ages. Due to
- unresolved contributions to uncertainty from the lack of a common Pb correction and from potential matrix
- effects between standards and unknowns, however, this estimate cannot be universally applied to all
- unknowns. Nevertheless, the results of this study provide an example of the type of precision and accuracy
- that may be possible with this technique under ideal conditions. In summary, the laser ablation technique,
- using a magnetic sector ICP-MS, can be used for the U-Pb dating of zircons with a wide range of ages and
- is a useful complement to the established TIMS and SHRIMP techniques. This technique is especially well
- suited to reconnaissance geochronologic and detrital zircon studies." name="eprints.abstract" />
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- <meta content="In this study we used LA-ICP-MS (laser ablation-inductively coupled plasma-mass spectrometry) to
- determine U-Pb ages of 5 zircon samples of known age (1800 Ma to 50 Ma) in order to determine the
- reproducibility, precision, and accuracy of this geochronologic technique. This work was performed using
- a ThermoFinnigan Element2 magnetic sector double-focusing ICP-MS coupled with a New Wave
- Research UP-213 laser system. The laser ablation pit sizes ranged from 30 to 40 mm in diameter. Laserinduced
- time-dependent fractionation is corrected by normalizing measured ratios in both standards and
- samples to the beginning of the analysis using the intercept method. Static fractionation, including those
- caused during laser ablation and due to instrumental discrimination, is corrected using external zircon
- standards. Total uncertainty for each laser analysis of an unknown is combined quadratically from the
- uncertainty in the measured isotope ratios of the unknown and the uncertainty in the fractionation factors
- calculated from the measurement of standards. For individual analyses we estimate that the accuracy and
- precision are better than 4% at the 2 sigma level, with the largest contribution in uncertainty from the
- measurement of the standards. Accuracy of age determinations in this study is on the order of 1% on the
- basis of comparing the weighted average of the LA-ICP-MS determinations to the TIMS ages. Due to
- unresolved contributions to uncertainty from the lack of a common Pb correction and from potential matrix
- effects between standards and unknowns, however, this estimate cannot be universally applied to all
- unknowns. Nevertheless, the results of this study provide an example of the type of precision and accuracy
- that may be possible with this technique under ideal conditions. In summary, the laser ablation technique,
- using a magnetic sector ICP-MS, can be used for the U-Pb dating of zircons with a wide range of ages and
- is a useful complement to the established TIMS and SHRIMP techniques. This technique is especially well
- suited to reconnaissance geochronologic and detrital zircon studies." name="DC.description" />
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- <h1 class="ep_tm_pagetitle">U-Pb dating of zircon by LA-ICP-MS</h1>
- <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Chang, Z.</span> and <span class="person_name">Vervoort, J. D.</span> and <span class="person_name">McClelland, W. C.</span> and <span class="person_name">Knaack, C.</span> (2006) <xhtml:em>U-Pb dating of zircon by LA-ICP-MS.</xhtml:em> Geochemistry Geophysics Geosystems, 7 (5). ISSN 1525-2027</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/693/1/Chang_et_al.%2C_GGG%2C_2006.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/693/1/Chang_et_al.%2C_GGG%2C_2006.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />701Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input accept-charset="utf-8" value="705" name="docid" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1029/2005GC001100">http://dx.doi.org/10.1029/2005GC001100</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">In this study we used LA-ICP-MS (laser ablation-inductively coupled plasma-mass spectrometry) to
- determine U-Pb ages of 5 zircon samples of known age (1800 Ma to 50 Ma) in order to determine the
- reproducibility, precision, and accuracy of this geochronologic technique. This work was performed using
- a ThermoFinnigan Element2 magnetic sector double-focusing ICP-MS coupled with a New Wave
- Research UP-213 laser system. The laser ablation pit sizes ranged from 30 to 40 mm in diameter. Laserinduced
- time-dependent fractionation is corrected by normalizing measured ratios in both standards and
- samples to the beginning of the analysis using the intercept method. Static fractionation, including those
- caused during laser ablation and due to instrumental discrimination, is corrected using external zircon
- standards. Total uncertainty for each laser analysis of an unknown is combined quadratically from the
- uncertainty in the measured isotope ratios of the unknown and the uncertainty in the fractionation factors
- calculated from the measurement of standards. For individual analyses we estimate that the accuracy and
- precision are better than 4% at the 2 sigma level, with the largest contribution in uncertainty from the
- measurement of the standards. Accuracy of age determinations in this study is on the order of 1% on the
- basis of comparing the weighted average of the LA-ICP-MS determinations to the TIMS ages. Due to
- unresolved contributions to uncertainty from the lack of a common Pb correction and from potential matrix
- effects between standards and unknowns, however, this estimate cannot be universally applied to all
- unknowns. Nevertheless, the results of this study provide an example of the type of precision and accuracy
- that may be possible with this technique under ideal conditions. In summary, the laser ablation technique,
- using a magnetic sector ICP-MS, can be used for the U-Pb dating of zircons with a wide range of ages and
- is a useful complement to the established TIMS and SHRIMP techniques. This technique is especially well
- suited to reconnaissance geochronologic and detrital zircon studies.</p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Additional Information:</th><td valign="top" class="ep_row">http://www.agu.org/pubs/crossref/2006/2005GC001100.shtml</td></tr><tr><th valign="top" class="ep_row">Keywords:</th><td valign="top" class="ep_row">laser ablation; magnetic sector ICP-MS; U-Pb dating; zircon dating.</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/260100.html">260000 Earth Sciences > 260100 Geology</a></td></tr><tr><th valign="top" class="ep_row">Collections:</th><td valign="top" class="ep_row">UNSPECIFIED</td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">693</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Mr Ruben Chan</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">08 Feb 2007</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">31 Jan 2008 13:41</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=693;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=693">item control page</a></p>
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