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    <title>UTas ePrints - Regional geochemistry of tertiary igneous rocks in Central Chile: Implications for the geodynamic environment of giant porphyry copper and epithermal gold mineralization</title>
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    <meta content="Hollings, P." name="eprints.creators_name" />
<meta content="Cooke, D.R." name="eprints.creators_name" />
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<meta content="Regional geochemistry of tertiary igneous rocks in Central Chile: Implications for the geodynamic environment of giant porphyry copper and epithermal gold mineralization" name="eprints.title" />
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<meta content="The giant porphyry copper-molybdenum deposits of central Chile formed within a thick sequence of Cretaceous
to Pliocene volcanic rocks. The predominantly calc-alkaline basaltic andesites of the Cretaceous Las
Chilcas Formation are characterized by La/Smn ratios of 1.8 to 2.5 and Sm/Ybn of 1.8 to 2.8. The upper
Oligocene to lower Miocene Abanico Formation (variously defined as the Los Pelambres, Abanico, or Coya
Machali Formations) ranges from basalt to rhyolite in composition and exhibits a broad southward transition
from calc-alkaline to tholeiitic. All samples from this formation are characterized by LREE enrichment and
moderately, or locally strongly, fractionated HREE (La/Smn = 1.3-4.1; Sm/Ybn = 1.5-5.8). The basaltic andesites
and andesites of the middle Miocene Salamanca Formation have REE chemistry similar to that of the
Upper Cretaceous strata (La/Smn = 1.5-2.7; Sm/Ybn = 1.6-2.7). The overlying middle Miocene Farellones Formation
ranges from tholeiitic to calc-alkaline and from basalt to andesitic and has a similar LREE enrichment
and fractionated HREE (La/Smn = 1.7-2.5; Sm/Ybn = 1.7-3.3). The Pliocene La Copa Rhyolite Complex, however,
is strongly LREE enriched and HREE depleted (La/Smn = 3.8-3.9; Sm/Ybn = 4.2-4.7). Overall, the trace
element geochemistry of the Cretaceous to middle Miocene volcanic rocks is characterized by enriched LREE
and negative Nb anomalies, consistent with an arc setting, with only minor differences in the abundance of
most elements. Crustal thickening during the Miocene in central Chile has been suggested to have been responsible
for a transition from an amphibole- to garnet-dominated residual mineralogy resulting in the release
of fluids that enabled the formation of giant copper porphyry deposits. However, the gradual increase in La/Yb
through the early, middle, and late Miocene reported in earlier studies and interpreted to be a response to
crustal thickening is not observed in the regional data. Instead, a rapid change in the geochemical signature between
the end of the eruption of the Farellones Formation and the eruption of the high La/Yb La Copa Rhyolite
Complex implies a more abrupt change in the tectonic environment. Isotopic data broadly support this,
although lower epsilon Nd values in the Farellones Formation imply a greater role for crustal contamination in younger suites. In the absence of gradual crustal thickening, it is suggested that the subduction of the Juan Fernandez Ridge may have been the key geodynamic process responsible for the genesis of the three middle Miocene to
lower Pliocene giant porphyry copper deposits in central Chile, possibly by promoting crustal-scale faulting and
even acting as a source of metals." name="eprints.abstract" />
<meta content="2005" name="eprints.date" />
<meta content="published" name="eprints.date_type" />
<meta content="Economic Geology" name="eprints.publication" />
<meta content="100" name="eprints.volume" />
<meta content="5" name="eprints.number" />
<meta content="887-904" name="eprints.pagerange" />
<meta content="10.2113/100.5.887" name="eprints.id_number" />
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<meta content="Allmendinger, R.W., Figueroa, D., Snyder, D., Beer, J., Mpodozis, C., and Isacks, B., 1990, Foreland shortening and crustal balancing in the Andes at 30 degrees S latitude: Tectonics, v. 9, p. 789-809.
Baksi, A.K., Archibald, D.A., and Farrar, E., 1996, Intercalibration of 40Ar/39Ar dating standards: Chemical Geology, v. 129, p. 307-324.
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Bertens, A., Deckart, K., and Gonzalez, A., 2003, Geocronologia U-Pb, Re-Os y 40Ar-39Ar del porfido de Cu-Mo Los Pelambres, Chile Central [abs.]: Congreso Geologico Chileno, 10th, 2003, Universidad de Concepcion,
Departamento de Ciencias de la Tierra, Abstracts, p. 40.
Bissig, T., 2001, Metallogenesis of the Miocene El Indio-Pascua gold-silvercopper belt, Chile/Argentina: Geodynamic, geomorphological and petrochemical controls on epithermal mineralization: Unpublished Ph.D. thesis, Kingston, Ontario, Queens University, 208 p.
Bissig, T., Lee, J., Clark, A., and Heather, K., 2001, The Neogene history of volcanism and hydrothermal alteration in the central Andean flat-slab: New 40Ar-39Ar constraints from the El Indio-Pascua Au (Ag, Cu) belt, III/IV Region,
Chile, Provincia San Juan, Argentina: International Geology Reviews, v. 43, p. 312-340.
Bissig, T., Clark, A., and Lee, J., 2002, Miocene landscape evolution and geomorphologic controls on epithermal processes in the El Indio-Pascua Au-Ag-Cu belt, Chile and Argentina: ECONOMIC GEOLOGY, v. 97, p. 971-996.
Bissig, T., Clark, A., Lee, J., and von Quadt, A., 2003, Petrogenetic and metallogenic responses to Miocene slab flattening: Constraints from the El Indio-Pascua Au-Ag-Cu belt, Chile/Argentina: Mineralium Deposita, v. 38,
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Cahill, T., and Isacks, B., 1992, Seismicity and shape of the subducted Nazca plate: Journal of Geophysical Research, v. 97, p. 17503-17529.
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Cannell, J., Cooke, D.R., Stein, H.J., and Markey, R.J., 2003, New paragenetically constrained Re-Os molybdenite ages for El Teniente Cu-Mo porphyry deposit, central Chile, in Eliopoulos, D., Allan, C., Baker, T., Barriga,
F., Beaudoin, G., Benardos, A., et al., eds., Mineral exploration and sustainable development: Rotterdam, Millpress, v. 1, p. 255-258.
Charrier, R., Baeza, O., Elgueta, S., Flynn, J., Gans, P., Kay, S., Munoz, N., Wyss, A., and Zurita, E., 2002, Evidence for Cenozoic extensional basin development
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Deckart, K., Clark, A.H., Aquilar A, C., and Vargas R, R, 2005, Magmatic and hydrothermal chronology of the giant Rio Blanco porphyry copper deposit, central Chile: Implications of an integrated U-Pb and 40Ar-39Ar database: ECONOMIC GEOLOGY,v. 100, p. 905-934.
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Hall, C.M., 1981, The application of K-Ar and 40Ar/39Ar methods to the dating of recent volcanics and the Laschamp event: Unpublished Ph.D. thesis, Toronto, Canada, University of Toronto, 186 p.
Harris, A.C., Golding, S.D., and White, N.C., 2005, Bajo de la Alumbrera Cu-Au: Stable isotope evidence for a porphyry-related hydrothermal system dominated by magmatic aqueous fluids: ECONOMIC GEOLOGY, v. 100, p. 863-886.
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-2002, Magmatism as a probe to the Neogene shallowing of the Nazca plate beneath the modern Chilean flat-slab: Journal of South American Earth Sciences, v. 15, p. 39-57.
Kay, S.M., Mpodozis, C., Ramos, V., and Munizaga, F., 1991, Magma source variations for mid-late Tertiary magmatic rocks associated with a shallowing subduction zone and a thickening crust in the central Andes (28-33degrees S):
Geological Society of America Special Paper 265, p. 113-137.
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Kurtz, A.C., Kay, S.M., Charrier, R., and Farrar, E., 1997, Geochronology of Miocene plutons and exhumation history of the El Teniente region, central Chile (34-35 degrees S): Revista Geologica de Chile, v. 24, p. 75-90.
Maksaev, V., Munizaga, F., McWilliams, M., Fanning, M., Mathur, R., Ruiz, J., and Thiele, K., 2002, El Teniente porphyry copper deposit in the Chilean Andes: New geochronological time frame and duration of hydrothermal
activity [abs.]: Geological Society of America Abstracts with Programs, v. 34, p. 336.
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on Andean Geodynamics 2, p. 411-414.
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Yanez, G., Cembrano, J., Pardo, M., Ranero, C., and Selles, D., 2002, The Challenger-Juan Fernandez-Maipo major tectonic transition of the Nazca-Andean subduction system at 33-34 degrees S: Geodynamic evidence and implications:
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Yu, Z., Robinson P., and McGoldrick P., 2001, An evaluation of methods for the chemical decomposition of geological materials for trace element determination using ICP-MS: Geostandards Newsletter: Journal of Geostandards and Geoanalysis, v. 25, p. 199-217." name="eprints.referencetext" />
<meta content="Hollings, P. and Cooke, D.R. and Clark, A.H. (2005) Regional geochemistry of tertiary igneous rocks in Central Chile: Implications for the geodynamic environment of giant porphyry copper and epithermal gold mineralization. Economic Geology, 100 (5). pp. 887-904. ISSN 0361-0128" name="eprints.citation" />
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<meta content="Regional geochemistry of tertiary igneous rocks in Central Chile: Implications for the geodynamic environment of giant porphyry copper and epithermal gold mineralization" name="DC.title" />
<meta content="Hollings, P." name="DC.creator" />
<meta content="Cooke, D.R." name="DC.creator" />
<meta content="Clark, A.H." name="DC.creator" />
<meta content="260300 Geochemistry" name="DC.subject" />
<meta content="260100 Geology" name="DC.subject" />
<meta content="The giant porphyry copper-molybdenum deposits of central Chile formed within a thick sequence of Cretaceous
to Pliocene volcanic rocks. The predominantly calc-alkaline basaltic andesites of the Cretaceous Las
Chilcas Formation are characterized by La/Smn ratios of 1.8 to 2.5 and Sm/Ybn of 1.8 to 2.8. The upper
Oligocene to lower Miocene Abanico Formation (variously defined as the Los Pelambres, Abanico, or Coya
Machali Formations) ranges from basalt to rhyolite in composition and exhibits a broad southward transition
from calc-alkaline to tholeiitic. All samples from this formation are characterized by LREE enrichment and
moderately, or locally strongly, fractionated HREE (La/Smn = 1.3-4.1; Sm/Ybn = 1.5-5.8). The basaltic andesites
and andesites of the middle Miocene Salamanca Formation have REE chemistry similar to that of the
Upper Cretaceous strata (La/Smn = 1.5-2.7; Sm/Ybn = 1.6-2.7). The overlying middle Miocene Farellones Formation
ranges from tholeiitic to calc-alkaline and from basalt to andesitic and has a similar LREE enrichment
and fractionated HREE (La/Smn = 1.7-2.5; Sm/Ybn = 1.7-3.3). The Pliocene La Copa Rhyolite Complex, however,
is strongly LREE enriched and HREE depleted (La/Smn = 3.8-3.9; Sm/Ybn = 4.2-4.7). Overall, the trace
element geochemistry of the Cretaceous to middle Miocene volcanic rocks is characterized by enriched LREE
and negative Nb anomalies, consistent with an arc setting, with only minor differences in the abundance of
most elements. Crustal thickening during the Miocene in central Chile has been suggested to have been responsible
for a transition from an amphibole- to garnet-dominated residual mineralogy resulting in the release
of fluids that enabled the formation of giant copper porphyry deposits. However, the gradual increase in La/Yb
through the early, middle, and late Miocene reported in earlier studies and interpreted to be a response to
crustal thickening is not observed in the regional data. Instead, a rapid change in the geochemical signature between
the end of the eruption of the Farellones Formation and the eruption of the high La/Yb La Copa Rhyolite
Complex implies a more abrupt change in the tectonic environment. Isotopic data broadly support this,
although lower epsilon Nd values in the Farellones Formation imply a greater role for crustal contamination in younger suites. In the absence of gradual crustal thickening, it is suggested that the subduction of the Juan Fernandez Ridge may have been the key geodynamic process responsible for the genesis of the three middle Miocene to
lower Pliocene giant porphyry copper deposits in central Chile, possibly by promoting crustal-scale faulting and
even acting as a source of metals." name="DC.description" />
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<meta content="Hollings, P. and Cooke, D.R. and Clark, A.H. (2005) Regional geochemistry of tertiary igneous rocks in Central Chile: Implications for the geodynamic environment of giant porphyry copper and epithermal gold mineralization. Economic Geology, 100 (5). pp. 887-904. ISSN 0361-0128" name="DC.identifier" />
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    <h1 class="ep_tm_pagetitle">Regional geochemistry of tertiary igneous rocks in Central Chile: Implications for the geodynamic environment of giant porphyry copper and epithermal gold mineralization</h1>
    <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Hollings, P.</span> and <span class="person_name">Cooke, D.R.</span> and <span class="person_name">Clark, A.H.</span> (2005) <xhtml:em>Regional geochemistry of tertiary igneous rocks in Central Chile: Implications for the geodynamic environment of giant porphyry copper and epithermal gold mineralization.</xhtml:em> Economic Geology, 100 (5). pp. 887-904. ISSN 0361-0128</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/1942/1/Hollings%2C_Cooke_et_al_ECON_GEOL_2005.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" border="0" class="ep_doc_icon" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/1942/1/Hollings%2C_Cooke_et_al_ECON_GEOL_2005.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />330Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input value="2422" name="docid" accept-charset="utf-8" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.2113/100.5.887">http://dx.doi.org/10.2113/100.5.887</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">The giant porphyry copper-molybdenum deposits of central Chile formed within a thick sequence of Cretaceous&#13;
to Pliocene volcanic rocks. The predominantly calc-alkaline basaltic andesites of the Cretaceous Las&#13;
Chilcas Formation are characterized by La/Smn ratios of 1.8 to 2.5 and Sm/Ybn of 1.8 to 2.8. The upper&#13;
Oligocene to lower Miocene Abanico Formation (variously defined as the Los Pelambres, Abanico, or Coya&#13;
Machali Formations) ranges from basalt to rhyolite in composition and exhibits a broad southward transition&#13;
from calc-alkaline to tholeiitic. All samples from this formation are characterized by LREE enrichment and&#13;
moderately, or locally strongly, fractionated HREE (La/Smn = 1.3-4.1; Sm/Ybn = 1.5-5.8). The basaltic andesites&#13;
and andesites of the middle Miocene Salamanca Formation have REE chemistry similar to that of the&#13;
Upper Cretaceous strata (La/Smn = 1.5-2.7; Sm/Ybn = 1.6-2.7). The overlying middle Miocene Farellones Formation&#13;
ranges from tholeiitic to calc-alkaline and from basalt to andesitic and has a similar LREE enrichment&#13;
and fractionated HREE (La/Smn = 1.7-2.5; Sm/Ybn = 1.7-3.3). The Pliocene La Copa Rhyolite Complex, however,&#13;
is strongly LREE enriched and HREE depleted (La/Smn = 3.8-3.9; Sm/Ybn = 4.2-4.7). Overall, the trace&#13;
element geochemistry of the Cretaceous to middle Miocene volcanic rocks is characterized by enriched LREE&#13;
and negative Nb anomalies, consistent with an arc setting, with only minor differences in the abundance of&#13;
most elements. Crustal thickening during the Miocene in central Chile has been suggested to have been responsible&#13;
for a transition from an amphibole- to garnet-dominated residual mineralogy resulting in the release&#13;
of fluids that enabled the formation of giant copper porphyry deposits. However, the gradual increase in La/Yb&#13;
through the early, middle, and late Miocene reported in earlier studies and interpreted to be a response to&#13;
crustal thickening is not observed in the regional data. Instead, a rapid change in the geochemical signature between&#13;
the end of the eruption of the Farellones Formation and the eruption of the high La/Yb La Copa Rhyolite&#13;
Complex implies a more abrupt change in the tectonic environment. Isotopic data broadly support this,&#13;
although lower epsilon Nd values in the Farellones Formation imply a greater role for crustal contamination in younger suites. In the absence of gradual crustal thickening, it is suggested that the subduction of the Juan Fernandez Ridge may have been the key geodynamic process responsible for the genesis of the three middle Miocene to&#13;
lower Pliocene giant porphyry copper deposits in central Chile, possibly by promoting crustal-scale faulting and&#13;
even acting as a source of metals.</p></div><table style="margin-bottom: 1em" border="0" cellpadding="3" class="not_ep_block"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Keywords:</th><td valign="top" class="ep_row">ridge, subduction, crustal thickening, volcanism ,plutonism</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/260300.html">260000 Earth Sciences &gt; 260300 Geochemistry</a><br /><a href="http://eprints.utas.edu.au/view/subjects/260100.html">260000 Earth Sciences &gt; 260100 Geology</a></td></tr><tr><th valign="top" class="ep_row">Collections:</th><td valign="top" class="ep_row">UNSPECIFIED</td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">1942</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Mrs Katrina Keep</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">19 Sep 2007</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">23 Jan 2008 15:00</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=1942;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&amp;eprintid=1942">item control page</a></p>
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