<!DOCTYPE html PUBLIC "-//W3C//DTD XHTML 1.0 Transitional//EN" "http://www.w3.org/TR/xhtml1/DTD/xhtml1-transitional.dtd"> <html> <head> <title>UTas ePrints - Reduced Kinetics Schemes for Oxides of Nitrogen Emissions from a Slow-Speed Marine Diesel Engine</title> <script type="text/javascript" src="http://eprints.utas.edu.au/javascript/auto.js"><!-- padder --></script> <style type="text/css" media="screen">@import url(http://eprints.utas.edu.au/style/auto.css);</style> <style type="text/css" media="print">@import url(http://eprints.utas.edu.au/style/print.css);</style> <link rel="icon" href="/images/eprints/favicon.ico" type="image/x-icon" /> <link rel="shortcut icon" href="/images/eprints/favicon.ico" type="image/x-icon" /> <link rel="Top" href="http://eprints.utas.edu.au/" /> <link rel="Search" href="http://eprints.utas.edu.au/cgi/search" /> <meta content="Goldsworthy, L." name="eprints.creators_name" /> <meta content="L.Goldsworthy@utas.edu.au" name="eprints.creators_id" /> <meta content="article" name="eprints.type" /> <meta content="2007-11-28 22:32:51" name="eprints.datestamp" /> <meta content="2008-01-08 15:30:00" name="eprints.lastmod" /> <meta content="show" name="eprints.metadata_visibility" /> <meta content="Reduced Kinetics Schemes for Oxides of Nitrogen Emissions from a Slow-Speed Marine Diesel Engine" name="eprints.title" /> <meta content="pub" name="eprints.ispublished" /> <meta content="291204" name="eprints.subjects" /> <meta content="restricted" name="eprints.full_text_status" /> <meta content="A number of reduced chemical kinetics schemes are compared for prediction of NOx emissions from a slow-speed marine diesel engine, using a zero-dimensional model. The kinetic evolution of NO is tracked in 10 representative parcels of burnt gas, formed sequentially during combustion. Dilution of the burnt gas by unburnt air is accounted for. The model is developed for use in a machinery space simulator for training marine engineers and in a predictive emissions monitoring system. It runs in real time on a standard PC and requires experimental data for calibration. Kinetics schemes modeled include the extended Zeldovich mechanism and five schemes involving nitrous oxide. The addition of nitrous oxide reactions to the extended Zeldovich mechanism increases predicted NOx by up to 15%. The N2O reactions which give the most significant contribution to NOx in the context of a large marine diesel engine have been identified. NO from fuel bound nitrogen is likely to be significant for engines operating on residual fuel oil." name="eprints.abstract" /> <meta content="2003" name="eprints.date" /> <meta content="published" name="eprints.date_type" /> <meta content="Energy & Fuels" name="eprints.publication" /> <meta content="17" name="eprints.volume" /> <meta content="2" name="eprints.number" /> <meta content="450-456" name="eprints.pagerange" /> <meta content="10.1021/ef020172c" name="eprints.id_number" /> <meta content="TRUE" name="eprints.refereed" /> <meta content="0887-0624" name="eprints.issn" /> <meta content="http://dx.doi.org/10.1021/ef020172c" name="eprints.official_url" /> <meta content="Goldsworthy, L. (2003) Reduced Kinetics Schemes for Oxides of Nitrogen Emissions from a Slow-Speed Marine Diesel Engine. Energy & Fuels, 17 (2). pp. 450-456. ISSN 0887-0624" name="eprints.citation" /> <meta content="http://eprints.utas.edu.au/2574/1/47111_E%26F_2003.pdf" name="eprints.document_url" /> <link rel="schema.DC" href="http://purl.org/DC/elements/1.0/" /> <meta content="Reduced Kinetics Schemes for Oxides of Nitrogen Emissions from a Slow-Speed Marine Diesel Engine" name="DC.title" /> <meta content="Goldsworthy, L." name="DC.creator" /> <meta content="291204 Marine Engineering" name="DC.subject" /> <meta content="A number of reduced chemical kinetics schemes are compared for prediction of NOx emissions from a slow-speed marine diesel engine, using a zero-dimensional model. The kinetic evolution of NO is tracked in 10 representative parcels of burnt gas, formed sequentially during combustion. Dilution of the burnt gas by unburnt air is accounted for. The model is developed for use in a machinery space simulator for training marine engineers and in a predictive emissions monitoring system. It runs in real time on a standard PC and requires experimental data for calibration. Kinetics schemes modeled include the extended Zeldovich mechanism and five schemes involving nitrous oxide. The addition of nitrous oxide reactions to the extended Zeldovich mechanism increases predicted NOx by up to 15%. The N2O reactions which give the most significant contribution to NOx in the context of a large marine diesel engine have been identified. NO from fuel bound nitrogen is likely to be significant for engines operating on residual fuel oil." name="DC.description" /> <meta content="2003" name="DC.date" /> <meta content="Article" name="DC.type" /> <meta content="PeerReviewed" name="DC.type" /> <meta content="application/pdf" name="DC.format" /> <meta content="http://eprints.utas.edu.au/2574/1/47111_E%26F_2003.pdf" name="DC.identifier" /> <meta content="http://dx.doi.org/10.1021/ef020172c" name="DC.relation" /> <meta content="Goldsworthy, L. 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border: solid 1px #ccc; padding: 3px"><tr> <td align="left"><a href="http://eprints.utas.edu.au/cgi/users/home">Login</a> | <a href="http://eprints.utas.edu.au/cgi/register">Create Account</a></td> <td align="right" style="white-space: nowrap"> <form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/search" style="display:inline"> <input class="ep_tm_searchbarbox" size="20" type="text" name="q" /> <input class="ep_tm_searchbarbutton" value="Search" type="submit" name="_action_search" /> <input type="hidden" name="_order" value="bytitle" /> <input type="hidden" name="basic_srchtype" value="ALL" /> <input type="hidden" name="_satisfyall" value="ALL" /> </form> </td> </tr></table></td></tr> <tr> <td class="toplinks"><!-- InstanceBeginEditable name="content" --> <div align="center"> <table width="720" class="ep_tm_main"><tr><td align="left"> <h1 class="ep_tm_pagetitle">Reduced Kinetics Schemes for Oxides of Nitrogen Emissions from a Slow-Speed Marine Diesel Engine</h1> <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Goldsworthy, L.</span> (2003) <xhtml:em>Reduced Kinetics Schemes for Oxides of Nitrogen Emissions from a Slow-Speed Marine Diesel Engine.</xhtml:em> Energy & Fuels, 17 (2). pp. 450-456. ISSN 0887-0624</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2574/1/47111_E%26F_2003.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2574/1/47111_E%26F_2003.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />115Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input accept-charset="utf-8" value="3381" name="docid" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1021/ef020172c">http://dx.doi.org/10.1021/ef020172c</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">A number of reduced chemical kinetics schemes are compared for prediction of NOx emissions from a slow-speed marine diesel engine, using a zero-dimensional model. The kinetic evolution of NO is tracked in 10 representative parcels of burnt gas, formed sequentially during combustion. Dilution of the burnt gas by unburnt air is accounted for. The model is developed for use in a machinery space simulator for training marine engineers and in a predictive emissions monitoring system. It runs in real time on a standard PC and requires experimental data for calibration. Kinetics schemes modeled include the extended Zeldovich mechanism and five schemes involving nitrous oxide. The addition of nitrous oxide reactions to the extended Zeldovich mechanism increases predicted NOx by up to 15%. The N2O reactions which give the most significant contribution to NOx in the context of a large marine diesel engine have been identified. NO from fuel bound nitrogen is likely to be significant for engines operating on residual fuel oil.</p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/291204.html">290000 Engineering and Technology > 291200 Maritime Engineering > 291204 Marine Engineering</a></td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2574</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Scholarly Publications Librarian</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">29 Nov 2007 09:32</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">09 Jan 2008 02:30</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2574;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=2574">item control page</a></p> </td></tr></table> </div> <!-- InstanceEndEditable --></td> </tr> <tr> <td><!-- #BeginLibraryItem "/Library/footer_eprints.lbi" --> <table width="795" border="0" align="left" cellpadding="0" class="footer"> <tr valign="top"> <td colspan="2"><div align="center"><a href="http://www.utas.edu.au">UTAS home</a> | <a href="http://www.utas.edu.au/library/">Library home</a> | <a href="/">ePrints home</a> | <a href="/contact.html">contact</a> | <a href="/information.html">about</a> | <a href="/view/">browse</a> | <a href="/perl/search/simple">search</a> | <a href="/perl/register">register</a> | <a href="/perl/users/home">user area</a> | <a href="/help/">help</a></div><br /></td> </tr> <tr><td colspan="2"><p><img src="/images/eprints/footerline.gif" width="100%" height="4" /></p></td></tr> <tr valign="top"> <td width="68%" class="footer">Authorised by the University Librarian<br /> © University of Tasmania ABN 30 764 374 782<br /> <a href="http://www.utas.edu.au/cricos/">CRICOS Provider Code 00586B</a> | <a href="http://www.utas.edu.au/copyright/copyright_disclaimers.html">Copyright & Disclaimers</a> | <a href="http://www.utas.edu.au/accessibility/index.html">Accessibility</a> | <a href="http://eprints.utas.edu.au/feedback/">Site Feedback</a> </td> <td width="32%"><div align="right"> <p align="right" class="NoPrint"><a href="http://www.utas.edu.au/"><img src="http://www.utas.edu.au/shared/logos/unioftasstrip.gif" alt="University of Tasmania Home Page" width="260" height="16" border="0" align="right" /></a></p> <p align="right" class="NoPrint"><a href="http://www.utas.edu.au/"><br /> </a></p> </div></td> </tr> <tr valign="top"> <td><p> </p></td> <td><div align="right"><span class="NoPrint"><a href="http://www.eprints.org/software/"><img src="/images/eprintslogo.gif" alt="ePrints logo" width="77" height="29" border="0" align="bottom" /></a></span></div></td> </tr> </table> <!-- #EndLibraryItem --> <div align="center"></div></td> </tr> </table> </body> </html>