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    <title>UTas ePrints - Djerfisherite in the Udachnaya-East pipe kimberlites (Sakha-Yakutia, Russia): paragenesis, composition and origin</title>
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<meta content="Djerfisherite, an unusual potassium- and chlorine-bearing sulphide K6Na(Fe,Ni,Cu)(24)S26Cl, is found in remarkably fresh rocks of the Udachnaya-East kimberlite pipe, including several varieties of kimberlite and a kimberlite-hosted phlogopite-spinel lherzolite xenolith. In both kimberlite breccia and monticellite kimberlite djerfisherite is a common groundmass mineral. Djerfisherite is also present as a daughter phase in olivine-hosted inclusions of trapped carbonate-chloride melt and sulphide melt. The mineral is present as irregular or rounded grains (up to 80-100 mu m) in association with magnetite and pyrrhotite in the kimberlite groundmass, and together with carbonates, Na-K-chlorides, silicates, magnetite, sulphates and Fe-Ni-sulphides in melt inclusions. Djerfisherite in the lherzolite xenolith is mainly interstitial (up to 100 mu m) and commonly rims primary mantle sulphides that show clear signs of replacement. Broad compositional variations in Fe, Ni and Cu are common in djerfisherite from different occurrences of the Udachnaya-East pipe. Textural relations, heating stage experiments with melt inclusions and compositional data, suggest a late magmatic origin of djerfisherite in the Udachnaya-East kimberlite groundmass, at shallow depths and at T <= 800 degrees C. In contrast, djerfisherite in the lherzolite xenolith appears to be a product of direct precipitation from evolved kimberlite magma infiltrating into lithospheric xenoliths or reactions of evolved kimberlite fluids/melts with primary minerals in xenoliths." name="eprints.abstract" />
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<meta content="Djerfisherite, an unusual potassium- and chlorine-bearing sulphide K6Na(Fe,Ni,Cu)(24)S26Cl, is found in remarkably fresh rocks of the Udachnaya-East kimberlite pipe, including several varieties of kimberlite and a kimberlite-hosted phlogopite-spinel lherzolite xenolith. In both kimberlite breccia and monticellite kimberlite djerfisherite is a common groundmass mineral. Djerfisherite is also present as a daughter phase in olivine-hosted inclusions of trapped carbonate-chloride melt and sulphide melt. The mineral is present as irregular or rounded grains (up to 80-100 mu m) in association with magnetite and pyrrhotite in the kimberlite groundmass, and together with carbonates, Na-K-chlorides, silicates, magnetite, sulphates and Fe-Ni-sulphides in melt inclusions. Djerfisherite in the lherzolite xenolith is mainly interstitial (up to 100 mu m) and commonly rims primary mantle sulphides that show clear signs of replacement. Broad compositional variations in Fe, Ni and Cu are common in djerfisherite from different occurrences of the Udachnaya-East pipe. Textural relations, heating stage experiments with melt inclusions and compositional data, suggest a late magmatic origin of djerfisherite in the Udachnaya-East kimberlite groundmass, at shallow depths and at T <= 800 degrees C. In contrast, djerfisherite in the lherzolite xenolith appears to be a product of direct precipitation from evolved kimberlite magma infiltrating into lithospheric xenoliths or reactions of evolved kimberlite fluids/melts with primary minerals in xenoliths." name="DC.description" />
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    <h1 class="ep_tm_pagetitle">Djerfisherite in the Udachnaya-East pipe kimberlites (Sakha-Yakutia, Russia): paragenesis, composition and origin</h1>
    <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Sharygin, V.V.</span> and <span class="person_name">Golovin, A.V.</span> and <span class="person_name">Pokhilenko, N.P.</span> and <span class="person_name">Kamenetsky, V.S.</span> (2007) <xhtml:em>Djerfisherite in the Udachnaya-East pipe kimberlites (Sakha-Yakutia, Russia): paragenesis, composition and origin.</xhtml:em> European Journal of Mineralogy, 19 (1). pp. 51-63. ISSN 0935-1221</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2610/1/EJM_2007-djerfisherite.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" border="0" class="ep_doc_icon" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2610/1/EJM_2007-djerfisherite.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />2853Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input value="3419" name="docid" accept-charset="utf-8" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1127/0935-1221/2007/0019-0051">http://dx.doi.org/10.1127/0935-1221/2007/0019-0051</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">Djerfisherite, an unusual potassium- and chlorine-bearing sulphide K6Na(Fe,Ni,Cu)(24)S26Cl, is found in remarkably fresh rocks of the Udachnaya-East kimberlite pipe, including several varieties of kimberlite and a kimberlite-hosted phlogopite-spinel lherzolite xenolith. In both kimberlite breccia and monticellite kimberlite djerfisherite is a common groundmass mineral. Djerfisherite is also present as a daughter phase in olivine-hosted inclusions of trapped carbonate-chloride melt and sulphide melt. The mineral is present as irregular or rounded grains (up to 80-100 mu m) in association with magnetite and pyrrhotite in the kimberlite groundmass, and together with carbonates, Na-K-chlorides, silicates, magnetite, sulphates and Fe-Ni-sulphides in melt inclusions. Djerfisherite in the lherzolite xenolith is mainly interstitial (up to 100 mu m) and commonly rims primary mantle sulphides that show clear signs of replacement. Broad compositional variations in Fe, Ni and Cu are common in djerfisherite from different occurrences of the Udachnaya-East pipe. Textural relations, heating stage experiments with melt inclusions and compositional data, suggest a late magmatic origin of djerfisherite in the Udachnaya-East kimberlite groundmass, at shallow depths and at T &lt;= 800 degrees C. In contrast, djerfisherite in the lherzolite xenolith appears to be a product of direct precipitation from evolved kimberlite magma infiltrating into lithospheric xenoliths or reactions of evolved kimberlite fluids/melts with primary minerals in xenoliths.</p></div><table style="margin-bottom: 1em" border="0" cellpadding="3" class="not_ep_block"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Additional Information:</th><td valign="top" class="ep_row">http://eurjmin.geoscienceworld.org/content/vol19/issue1/</td></tr><tr><th valign="top" class="ep_row">Keywords:</th><td valign="top" class="ep_row">djerfisherite, kimberlite, carbonatite, magma, mantle xenolith, potassium iron sulfide, kola-peninsula, oldoinyo-lengai, unaltered kimberlites, carbonatite volcano, crystal-structure, alkali chlorides, xenoliths, siberia, mantle</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/260300.html">260000 Earth Sciences &gt; 260300 Geochemistry</a><br /><a href="http://eprints.utas.edu.au/view/subjects/260100.html">260000 Earth Sciences &gt; 260100 Geology</a></td></tr><tr><th valign="top" class="ep_row">Collections:</th><td valign="top" class="ep_row">UNSPECIFIED</td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2610</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Vadim Kamenetsky</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">10 Dec 2007 13:39</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">20 Jan 2008 23:08</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2610;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&amp;eprintid=2610">item control page</a></p>
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