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<title>UTas ePrints - Tris[bis(1-methyl-1H-imidazol-2-yl)methanone-K2N3]iron(II) dichloride 5.5-hydrate, cis-bis[bis(1-methyl-1H-imidazol-2-yl)methanone-K2N3]dichloroiron(II) (ca 153 K) and di-mu-chloro-bis{[bis(1-methyl-1H-imidazol-2-yl)-methanone-K2N3]chloroiron(II)} methanol disolvate (ca 300 K)</title>
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<meta content="Batten, M. P." name="eprints.creators_name" />
<meta content="Canty, A.J." name="eprints.creators_name" />
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<meta content="Tris[bis(1-methyl-1H-imidazol-2-yl)methanone-K2N3]iron(II) dichloride 5.5-hydrate, cis-bis[bis(1-methyl-1H-imidazol-2-yl)methanone-K2N3]dichloroiron(II) (ca 153 K) and di-mu-chloro-bis{[bis(1-methyl-1H-imidazol-2-yl)-methanone-K2N3]chloroiron(II)} methanol disolvate (ca 300 K)" name="eprints.title" />
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<meta content="The first of the title compounds, [Fe(C9H10N4O)3]Cl2.5.5H2O, is the ®rst structurally characterized homoleptic tris[bis-(imidazol-2-yl) ketone]±metal complex to be structurally determined. In the second of the title compounds,[FeCl2(C9H10N4O)2], a pair of monodentate donors supplants one of the bidentate ligands. In the third complex,[Fe2Cl4(C9H10N4O)2].2CH3OH, a centrosymmetric binuclear compound with a pair of bridging chloride ligands, the introduction of a third chloro ligand results in ®ve-coordination about each of the metal atoms; the environments of the latter are square pyramidal, with a chloro ligand at the apex and the two bidentate arrays about the base of the pyramid." name="eprints.abstract" />
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<meta content="Acta Crystallographica. Section C: Crystal Structure Communications" name="eprints.publication" />
<meta content="C60" name="eprints.volume" />
<meta content="m316-m319" name="eprints.pagerange" />
<meta content="10.1107/S0108270104010881" name="eprints.id_number" />
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<meta content="Batten, M. P., Canty, A. J., Cavell, K. J., RuÈ ther, T., Skelton, B. W. & White,
A. H. (2004a). Acta Cryst. C60, m311±m313.
Batten, M. P., Canty, A. J., Cavell, K. J., RuÈ ther, T., Skelton, B. W. & White,
A. H. (2004b). Acta Cryst. C60, m314±m315.
Byers, P. K., Canty, A. J., Engelhardt, L. M., Patrick, J. M. & White, A. H.
(1985). J. Chem. Soc. Dalton Trans. pp. 981±986.
Chen, X.-M., Xu, Z.-T. & Mak, T. C. W. (1995). Polyhedron, 14, 319±322.
Elga®, S., Field, L. D., Messerle, B. A., Hambley, T. W. & Turner, P. (1997). J.
Chem. Soc. Dalton Trans. pp. 2341±2345.
Gorun, S. M., Stibrany, R. T., Katritzky, A. R., Slawinski, J. J., Faid-Allah, H. &
Brunner, F. (1996). Inorg. Chem. 35, 3±4.
Hall, S. R., King, G. S. D. & Stewart, J. M. (1995). The Xtal3.5 User's Manual.
University of Western Australia: Lamb, Perth.
Long, L.-S., Ren, R.-P., Huang, R.-B., Zheng, L.-S., Chen, X.-M. & Ng, S. W.
(2001). Main Group Met. Chem. 74, 463±464.
McMaster, J., Beddoes, R. L., Collison, D., Eardley, D. R., Helliwell, M. &
Garner, C. D. (1996). Chem. Eur. J. 2, 685±693.
Place, C., Zimmerman, J.-L., Mulliez, E., Guillot, G., Bois, C. & Chottard, J.-C.
(1998). Inorg. Chem. 37, 4030±4039.
RuÈ ther, T., Cavell, K. J., Brassaud, N. C., Skelton, B.W. & White, A. H. (2002).
J. Chem. Soc. Dalton Trans. pp. 4684±4693.
Sheldrick, G. M. (1996). SADABS. University of GoÈ ttingen, Germany.
Siemens (1995). SMART and SAINT. Siemens Analytical X-ray Instruments
Inc., Madison, Wisconsin, USA.
Stange, A. F. & Kaim, W. (1996). Z. Anorg. Allg. Chem. 622, 1118±1124." name="eprints.referencetext" />
<meta content="Batten, M. P. and Canty, A.J. and Cavell, K. J. and Ruther, T. and Skelton, B.W. and White, A.H. (2004) Tris[bis(1-methyl-1H-imidazol-2-yl)methanone-K2N3]iron(II) dichloride 5.5-hydrate, cis-bis[bis(1-methyl-1H-imidazol-2-yl)methanone-K2N3]dichloroiron(II) (ca 153 K) and di-mu-chloro-bis{[bis(1-methyl-1H-imidazol-2-yl)-methanone-K2N3]chloroiron(II)} methanol disolvate (ca 300 K). Acta Crystallographica. Section C: Crystal Structure Communications, C60 . m316-m319. ISSN 0108-2701" name="eprints.citation" />
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<meta content="Batten, M. P." name="DC.creator" />
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<h1 class="ep_tm_pagetitle">Tris[bis(1-methyl-1H-imidazol-2-yl)methanone-K2N3]iron(II) dichloride 5.5-hydrate, cis-bis[bis(1-methyl-1H-imidazol-2-yl)methanone-K2N3]dichloroiron(II) (ca 153 K) and di-mu-chloro-bis{[bis(1-methyl-1H-imidazol-2-yl)-methanone-K2N3]chloroiron(II)} methanol disolvate (ca 300 K)</h1>
<p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Batten, M. P.</span> and <span class="person_name">Canty, A.J.</span> and <span class="person_name">Cavell, K. J.</span> and <span class="person_name">Ruther, T.</span> and <span class="person_name">Skelton, B.W.</span> and <span class="person_name">White, A.H.</span> (2004) <xhtml:em>Tris[bis(1-methyl-1H-imidazol-2-yl)methanone-K2N3]iron(II) dichloride 5.5-hydrate, cis-bis[bis(1-methyl-1H-imidazol-2-yl)methanone-K2N3]dichloroiron(II) (ca 153 K) and di-mu-chloro-bis{[bis(1-methyl-1H-imidazol-2-yl)-methanone-K2N3]chloroiron(II)} methanol disolvate (ca 300 K).</xhtml:em> Acta Crystallographica. Section C: Crystal Structure Communications, C60 . m316-m319. ISSN 0108-2701</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2785/1/AC2CC602C_m316.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" border="0" class="ep_doc_icon" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2785/1/AC2CC602C_m316.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />309Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input value="3754" name="docid" accept-charset="utf-8" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1107/S0108270104010881">http://dx.doi.org/10.1107/S0108270104010881</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">The first of the title compounds, [Fe(C9H10N4O)3]Cl2.5.5H2O, is the ®rst structurally characterized homoleptic tris[bis-(imidazol-2-yl) ketone]±metal complex to be structurally determined. In the second of the title compounds,[FeCl2(C9H10N4O)2], a pair of monodentate donors supplants one of the bidentate ligands. In the third complex,[Fe2Cl4(C9H10N4O)2].2CH3OH, a centrosymmetric binuclear compound with a pair of bridging chloride ligands, the introduction of a third chloro ligand results in ®ve-coordination about each of the metal atoms; the environments of the latter are square pyramidal, with a chloro ligand at the apex and the two bidentate arrays about the base of the pyramid.</p></div><table style="margin-bottom: 1em" border="0" cellpadding="3" class="not_ep_block"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Additional Information:</th><td valign="top" class="ep_row">"The definitive version is available at www.blackwell-synergy.com"
</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/250201.html">250000 Chemical Sciences > 250200 Inorganic Chemistry > 250201 Transition Metal Chemistry</a></td></tr><tr><th valign="top" class="ep_row">Collections:</th><td valign="top" class="ep_row">UNSPECIFIED</td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2785</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">02 Jan 2008 13:41</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">01 Feb 2008 14:21</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2785;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=2785">item control page</a></p>
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