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<meta content="Assignments of vas(SMS) and vsym(SMS) for the complexes
M(SR)2 (M = Zn, Cd, Hg; R = Et, But) and Hg(SMe)2 from infrared and Raman spectroscopy are reported. Comparison of frequencies for the complex Hg(SBut)2 containing four-coordinate mercury with those of Hg(SR)2 (R = Me, Et) containing two-coordinate mercury permits assignment of a polymeric structure with linear coordination for the 1:I
complex of Hg(II) with the antidote for mercury poisoning 2,3-dimercaptopropanol (British anti-Lewisite)." name="eprints.abstract" />
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<meta content="1 See, e.g. (a) L. A. Stocken, Biochem. J., 41, 358 (1947);
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Med., 4I. 503 (1949); (d) A. Swensson and U. Ulfvarson,
ht. Arch. Gewerbepath. Gewerbehyg., 24, 12 (1967).
2 A. Gilman, R. P. Allen, F. S. Philips, and E. St. John,
J. Clin. Invest., 25, 549 (1946).
3 A. J. Canty and R. Kishimoto, Nature, 253, 123 (1975).
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51 I (1972).
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2258 (1964).
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Dalton, 2140 (1974).
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361 (1967).
See, e.g. (a) R. Benesch and R. E. Benesch, Arch. Biothem.
Biophys., 38, 425 (1952) (b) A. Shulman and
F. P. Dwyer in “Chelating Agents and Metal Chelates”,
I;. P. Dwyer and D. P. Mellor (Eds.), Academic Press,
New York, 1964, p. 388.
D. Grdenid, Quart. Rev., CYtem. Sot., 19, 303 (1965).
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2786 (1965).
H.-B. Biirgi, Helv. C%im. Acta, 57. 513 (1974).
P. Strickler; Chem. Commun., 655 (1969).
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Chem., 130, 133 (1931).
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397 (1956).
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303 (1972).
(a) H. J. Verwcel and J. M. Bijvoet, Z. Krist., 77, 122
(1931); (b) H. Braekken, Z. Krist., 81, 152 (1932).
H. Poulet and J. P. Mathieu, J. Chim. Phys., 60, 442
(1963).
K. V. K. Rao, Proc. Ind. Acad. Sci., 14A, 521 (1941" name="eprints.referencetext" />
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M(SR)2 (M = Zn, Cd, Hg; R = Et, But) and Hg(SMe)2 from infrared and Raman spectroscopy are reported. Comparison of frequencies for the complex Hg(SBut)2 containing four-coordinate mercury with those of Hg(SR)2 (R = Me, Et) containing two-coordinate mercury permits assignment of a polymeric structure with linear coordination for the 1:I
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<h1 class="ep_tm_pagetitle">Metal-Sulphur Stretching Frequencies and Structures of Complexes of Zinc, Cadmium, and Mercury with Thiols</h1>
<p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Canty, A.J.</span> and <span class="person_name">Kishimoto, R.</span> and <span class="person_name">Deacon, G.B.</span> and <span class="person_name">Farquharson, G.J.</span> (1976) <xhtml:em>Metal-Sulphur Stretching Frequencies and Structures of Complexes of Zinc, Cadmium, and Mercury with Thiols.</xhtml:em> Inorganica Chimica Acta, 20 . pp. 161-166. ISSN 0020-1693</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2827/1/ICA1976_2C_161.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2827/1/ICA1976_2C_161.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />504Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input accept-charset="utf-8" value="4034" name="docid" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1016/S0020-1693(00)94110-0">http://dx.doi.org/10.1016/S0020-1693(00)94110-0</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">Assignments of vas(SMS) and vsym(SMS) for the complexes
M(SR)2 (M = Zn, Cd, Hg; R = Et, But) and Hg(SMe)2 from infrared and Raman spectroscopy are reported. Comparison of frequencies for the complex Hg(SBut)2 containing four-coordinate mercury with those of Hg(SR)2 (R = Me, Et) containing two-coordinate mercury permits assignment of a polymeric structure with linear coordination for the 1:I
complex of Hg(II) with the antidote for mercury poisoning 2,3-dimercaptopropanol (British anti-Lewisite).</p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Additional Information:</th><td valign="top" class="ep_row">The definitive version is available at http://www.sciencedirect.com
</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/250200.html">250000 Chemical Sciences > 250200 Inorganic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2827</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">11 Jan 2008 11:49</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">11 Jan 2008 11:49</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2827;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=2827">item control page</a></p>
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