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<meta content="Byers, P.K." name="eprints.creators_name" />
<meta content="Canty, A.J." name="eprints.creators_name" />
<meta content="Honeyman, R.T." name="eprints.creators_name" />
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<meta content="The synthesis of tripodal nitrogen donor ligands and their characterization as Pd(II)Me2 and Pd(II)IMe derivatives" name="eprints.title" />
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<meta content="New tripod ligands containing pyridin-2-yl (py), N-methylimidazol-2-yl (mim), and pyrazol-l-y1 (pz) groups have been made by addition of 2-bromopyridine to
deprotonated (py)(mim)CH2 or (mim)2CH2 to form (py)2(mim)CH and (py)(mim)2CH, or by simple condensation reactions of (pz)2CO with (mim)CHO or (py)CHO to form (pz)2(mim)CH and (pz)2(py)CH. The ligands may have general application in coordination and organometallic chemistry, especially bis(pyrazol-lyl)(pyridin-2-yl)methane [(pz)2(py)CH], which can be readily synthesized and is an unsymmetrical tripod closely related to (pz)3CH and (py)3CH. Dimethylpalladium(
II) and methyl(iodo)palladium(II) complexes of the ligands have been isolated, and compared with complexes of (pz)3CH, (py)3CH, and (pz)4C." name="eprints.abstract" />
<meta content="1990" name="eprints.date" />
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<meta content="Journal of Organometallic Chemistry" name="eprints.publication" />
<meta content="385" name="eprints.volume" />
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<meta content="417-427" name="eprints.pagerange" />
<meta content="10.1016/0022-328X(90)85013-O" name="eprints.id_number" />
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S. Trofimenko, Progr. Inorg. Chem., 34 (1986) 115.
P.K. Byers, A.J. Canty, B.W. Skelton, and A.H. White, J. Chem. Sot., Chem. Commun., (1987) 1093.
P.K. Byers and A.J. Canty, J. Chem. Sot., Chem. Commun., (1988) 639.
P.K. Byers, A.J. Canty, B.W. Skelton, and A.H. White, Organometallics, 9 (1990) in press.
P.K. Byers and A.J. Canty, Inorg. Chim. Acta, 104 (1985) L13.
K.I. The and L.K. Peterson, Can. J. Chem., 51 (1973) 422.
K.I. The, L.K. Peterson, and E. Kiehlmann, Can. J. Chem., 51 (1973) 2448.
L.K. Peterson, E. Kiehlmann, A.R. Sanger, and K.I. The, Can. J. Chem., 52 (1974) 2367.
P.K. Byers and A.J. Canty, Organometallics, 9 (1990) in press.
A.J. Canty, N.J.Minchin, P.C. Healy, and A.H. White, J. Chem. Sot., Dalton Trans., (1982) 1795.
P.K. Byers, A.J. Canty, B.W. Skelton, and A.H. White, Aust. J. Chem., 38 (1985) 1251.
P.K. Byers, A.J. Canty, N.J. Minchin, J.M. Patrick, B W. Skelton, and A.H. White, J. Chem. Sot.,
Dalton Trans., (1985) 1183.
A.J. Canty, N.J. Minchin, J.M. Patrick, and A.H. White, Aust. J. Chem., 36 (1983) 1107.
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A.J. Canty, N.J. Minchin, L.M. Engelhardt, B.W. Skelton, and A.H. White, J. Chem. Sot., Dalton
Trans., (1986) 645.
P.K. Byers, A.J. Canty, L.M. Engelhardt, and A.H. White, J. Chem. Sot., Dalton Trans., (1986) 1731.
A.J. Canty, N. Chaichit, B.M. Gatehouse, E.E. George, and G. Hayhurst, Inorg. Chem., 20 (1981)
2414.
G.R. Newkome, V.K. Gupta, H.C.R. Taylor, and F.R. Fronczek, Organometallics, 3 (1984) 1549.
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P.E. Iversen and H. Lund, Acta Chem. Stand., 20 (1966) 2649." name="eprints.referencetext" />
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<meta content="New tripod ligands containing pyridin-2-yl (py), N-methylimidazol-2-yl (mim), and pyrazol-l-y1 (pz) groups have been made by addition of 2-bromopyridine to
deprotonated (py)(mim)CH2 or (mim)2CH2 to form (py)2(mim)CH and (py)(mim)2CH, or by simple condensation reactions of (pz)2CO with (mim)CHO or (py)CHO to form (pz)2(mim)CH and (pz)2(py)CH. The ligands may have general application in coordination and organometallic chemistry, especially bis(pyrazol-lyl)(pyridin-2-yl)methane [(pz)2(py)CH], which can be readily synthesized and is an unsymmetrical tripod closely related to (pz)3CH and (py)3CH. Dimethylpalladium(
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<h1 class="ep_tm_pagetitle">The synthesis of tripodal nitrogen donor ligands and their characterization as Pd(II)Me2 and Pd(II)IMe derivatives</h1>
<p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Byers, P.K.</span> and <span class="person_name">Canty, A.J.</span> and <span class="person_name">Honeyman, R.T.</span> (1990) <xhtml:em>The synthesis of tripodal nitrogen donor ligands and their characterization as Pd(II)Me2 and Pd(II)IMe derivatives.</xhtml:em> Journal of Organometallic Chemistry, 385 (3). pp. 417-427. ISSN 0022-328X</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2873/1/JOMC1990_2C_417.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" border="0" class="ep_doc_icon" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2873/1/JOMC1990_2C_417.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />831Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input value="4120" name="docid" accept-charset="utf-8" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1016/0022-328X(90)85013-O">http://dx.doi.org/10.1016/0022-328X(90)85013-O</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">New tripod ligands containing pyridin-2-yl (py), N-methylimidazol-2-yl (mim), and pyrazol-l-y1 (pz) groups have been made by addition of 2-bromopyridine to
deprotonated (py)(mim)CH2 or (mim)2CH2 to form (py)2(mim)CH and (py)(mim)2CH, or by simple condensation reactions of (pz)2CO with (mim)CHO or (py)CHO to form (pz)2(mim)CH and (pz)2(py)CH. The ligands may have general application in coordination and organometallic chemistry, especially bis(pyrazol-lyl)(pyridin-2-yl)methane [(pz)2(py)CH], which can be readily synthesized and is an unsymmetrical tripod closely related to (pz)3CH and (py)3CH. Dimethylpalladium(
II) and methyl(iodo)palladium(II) complexes of the ligands have been isolated, and compared with complexes of (pz)3CH, (py)3CH, and (pz)4C.</p></div><table style="margin-bottom: 1em" border="0" cellpadding="3" class="not_ep_block"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Additional Information:</th><td valign="top" class="ep_row">The definitive version is available at http://www.sciencedirect.com
</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/259901.html">250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2873</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">16 Jan 2008 11:17</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">16 Jan 2008 11:17</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2873;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=2873">item control page</a></p>
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