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<meta content="Palladium is one of the most widely studied elements in organometallic chemistry, partly owing to the important
role of palladium complexes in organic synthesis and catalysis. Since the initial report of PdIMe3(bpy), a rich and diverse organopalladium(IV) chemistry has evolved, including reaction systems that are ideal for studying topics of contemporary interest, e.g., mechanisms of oxidative addition and reductive elimination reactions, selectivity in reductive elimination, and studies of alkyl group exchange between metal centers. An account of each of these topics is presented here, followed by an assessment of some of the possible roles of Pd(IV) in organic synthesis and catalysis. Palladium(IV) chemistry has developed rapidly since 1986 to include the isolation of alkyl-, benzyl-, (eta-l-allyl)-, and arylpalladium complexes. It is providing new comparisons of structure, solution dynamics, and reactivity among the nickel triad elements and is providing new systems for mechanistic studies." name="eprints.abstract" />
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<meta content="Palladium is one of the most widely studied elements in organometallic chemistry, partly owing to the important
role of palladium complexes in organic synthesis and catalysis. Since the initial report of PdIMe3(bpy), a rich and diverse organopalladium(IV) chemistry has evolved, including reaction systems that are ideal for studying topics of contemporary interest, e.g., mechanisms of oxidative addition and reductive elimination reactions, selectivity in reductive elimination, and studies of alkyl group exchange between metal centers. An account of each of these topics is presented here, followed by an assessment of some of the possible roles of Pd(IV) in organic synthesis and catalysis. Palladium(IV) chemistry has developed rapidly since 1986 to include the isolation of alkyl-, benzyl-, (eta-l-allyl)-, and arylpalladium complexes. It is providing new comparisons of structure, solution dynamics, and reactivity among the nickel triad elements and is providing new systems for mechanistic studies." name="DC.description" />
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<h1 class="ep_tm_pagetitle">Development of Organopalladium(IV) Chemistry: Fundamental Aspects and Systems for Studies of Mechanism in Organometallic Chemistry and Catalysis</h1>
<p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Canty, A.J.</span> (1992) <xhtml:em>Development of Organopalladium(IV) Chemistry: Fundamental Aspects and Systems for Studies of Mechanism in Organometallic Chemistry and Catalysis.</xhtml:em> Accounts of Chemical Research, 25 (2). pp. 83-90. ISSN 0001-4842</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2893/1/Accts1992_2C_83.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" border="0" class="ep_doc_icon" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2893/1/Accts1992_2C_83.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />1059Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input value="4166" name="docid" accept-charset="utf-8" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1021/ar00014a005">http://dx.doi.org/10.1021/ar00014a005</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">Palladium is one of the most widely studied elements in organometallic chemistry, partly owing to the important
role of palladium complexes in organic synthesis and catalysis. Since the initial report of PdIMe3(bpy), a rich and diverse organopalladium(IV) chemistry has evolved, including reaction systems that are ideal for studying topics of contemporary interest, e.g., mechanisms of oxidative addition and reductive elimination reactions, selectivity in reductive elimination, and studies of alkyl group exchange between metal centers. An account of each of these topics is presented here, followed by an assessment of some of the possible roles of Pd(IV) in organic synthesis and catalysis. Palladium(IV) chemistry has developed rapidly since 1986 to include the isolation of alkyl-, benzyl-, (eta-l-allyl)-, and arylpalladium complexes. It is providing new comparisons of structure, solution dynamics, and reactivity among the nickel triad elements and is providing new systems for mechanistic studies.</p></div><table style="margin-bottom: 1em" border="0" cellpadding="3" class="not_ep_block"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/259901.html">250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">Collections:</th><td valign="top" class="ep_row">UNSPECIFIED</td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2893</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">17 Jan 2008 14:14</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">17 Jan 2008 14:14</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2893;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=2893">item control page</a></p>
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