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  5.     <title>UTas ePrints - Synthesis and Characterization of Ambient Temperature Stable Organopalladium(IV) Complexes, Including Aryl-, hl-Allyl-, Ethylpalladium(IV), and Pallada(IV)cyclopentane Complexes. Structures of the Poly(pyrazo1-l-y1)borate Complexes PdMe3{(pz)3BH} and PdMe3{(pz)4B} and Three Polymorphs of PdMe2Et{(pz)3BH}</title>
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  13.     <meta content="Canty, A.J." name="eprints.creators_name" />
  14. <meta content="Jin, H." name="eprints.creators_name" />
  15. <meta content="Roberts, A.S." name="eprints.creators_name" />
  16. <meta content="Skelton, B.W." name="eprints.creators_name" />
  17. <meta content="Traill, P.R." name="eprints.creators_name" />
  18. <meta content="White, A.H." name="eprints.creators_name" />
  19. <meta content="allan.canty@utas.edu.au" name="eprints.creators_id" />
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  26. <meta content="2007-10-09 04:53:36" name="eprints.datestamp" />
  27. <meta content="2008-02-01T03:33:31Z" name="eprints.lastmod" />
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  29. <meta content="Synthesis and Characterization of Ambient Temperature
  30. Stable Organopalladium(IV) Complexes, Including Aryl-,
  31. hl-Allyl-, Ethylpalladium(IV), and
  32. Pallada(IV)cyclopentane Complexes. Structures of the
  33. Poly(pyrazo1-l-y1)borate Complexes PdMe3{(pz)3BH} and
  34. PdMe3{(pz)4B} and Three Polymorphs of
  35. PdMe2Et{(pz)3BH}" name="eprints.title" />
  36. <meta content="pub" name="eprints.ispublished" />
  37. <meta content="259901" name="eprints.subjects" />
  38. <meta content="restricted" name="eprints.full_text_status" />
  39. <meta content="The palladium(I1) complexes PdMeZ(tmeda1, PdMePh(tmeda), and Pd(CH2CHzCHzCHz)-
  40. (tmeda) (tmeda = tetramethylethylenediamine)r eact with potassium tris(pyrazo1-l-y1)borate
  41. and organohalides RX in acetone to form the octahedral palladium(IV) complexes PdMeRR”-
  42. {(pz)sBH}( R = Me, Ph) and Pd(CH2CHzCHzCH~)R{(pz)3BH(R} X = MeI, EtI, PhCHzBr,
  43. CHz=CHCH&amp;. The complexes are stable in the solid state and in solution at ambient
  44. temperature, PdMe3{(pz)3BH} is more stable than the iodide salt of isoelectronic [PdMes{(pz)a-
  45. CH}]+, and the aryl- and 17l-propenylpalladium(IV)c omplexes are the first examples of aryland
  46. allylpalladium(IV) complexes that are stable above 0 “C. The tris(pyrazo1-l-y1)borate
  47. ligand considerably enhances the stability of palladium( IV) complexes when compared with
  48. related neutral donor ligands. The ethylpalladium(rV) complexes have stabilities in solution
  49. similar to that of the most stable ethylpalladium(I1) complexes reported. The complex PdMea-
  50. {(~Z)~(B2)} h as been prepared, and structural studies of this complex and PdMe~R{(pz)3-
  51. BH} [ R= Me (l)E, t (3>]c ompleted, allowing the first comparison of structural parameters
  52. of ethylpalladium( 11, IV) complexes and of PdMe3{ (pz)3BH} with the “isoelectronic” cation
  53. [PdMe3{(pz)3CH}]+. Three polymorphs of PdMezEt{ (pz)3BH} were examined: complex 3a
  54. is ordered, but the other polymorphs exhibit disordering in the conformation of the ethyl
  55. group (3b) and in the position of the ethyl group and one of the methyl groups (3c).
  56. Crystallographic data: for 1, monoclinic, space group P21/c, a = 16.559(16) A, b = 7.859(4) A,c = 13.774(15)A , p = 118.88(8)”2, = 4, R = 0.032, R, = 0,043; for 2, monoclinic, space
  57. group P21/c, a = 11.453(1) A, b = 9.729(2) A, c = 16.973(9) A, p = 107.25(3)”, 2 = 4, R =
  58. 0.053, R, = 0.055; for 3a, monoclinic, P2&amp;, a = 9.384(3) A, b = 12.795(3) A, c = 15.119(8)
  59. A, p = 115.22(3)”, 2 = 4, R = 0.055, R, = 0.052; for 3b, orthorhombic, P212121, a = 13.955-
  60. (3) A, b = 13.152(18) A, c = 9.047(6) A, 2 = 4, R = 0.052, R, = 0.053; for 3c, tetragonal,
  61. P43212, a = 12.305(4) A, c = 21.542(7) A, 2 = 8, R = R, = 0.035." name="eprints.abstract" />
  62. <meta content="1995" name="eprints.date" />
  63. <meta content="published" name="eprints.date_type" />
  64. <meta content="Organometallics" name="eprints.publication" />
  65. <meta content="14" name="eprints.volume" />
  66. <meta content="199-206" name="eprints.pagerange" />
  67. <meta content="TRUE" name="eprints.refereed" />
  68. <meta content="Canty, A.J. and Jin, H. and Roberts, A.S. and Skelton, B.W. and Traill, P.R. and White, A.H. (1995) Synthesis and Characterization of Ambient Temperature Stable Organopalladium(IV) Complexes, Including Aryl-, hl-Allyl-, Ethylpalladium(IV), and Pallada(IV)cyclopentane Complexes. Structures of the Poly(pyrazo1-l-y1)borate Complexes PdMe3{(pz)3BH} and PdMe3{(pz)4B} and Three Polymorphs of PdMe2Et{(pz)3BH}. Organometallics, 14 . pp. 199-206." name="eprints.citation" />
  69. <meta content="http://eprints.utas.edu.au/2071/1/om00001a031.pdf" name="eprints.document_url" />
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  71. <meta content="Synthesis and Characterization of Ambient Temperature
  72. Stable Organopalladium(IV) Complexes, Including Aryl-,
  73. hl-Allyl-, Ethylpalladium(IV), and
  74. Pallada(IV)cyclopentane Complexes. Structures of the
  75. Poly(pyrazo1-l-y1)borate Complexes PdMe3{(pz)3BH} and
  76. PdMe3{(pz)4B} and Three Polymorphs of
  77. PdMe2Et{(pz)3BH}" name="DC.title" />
  78. <meta content="Canty, A.J." name="DC.creator" />
  79. <meta content="Jin, H." name="DC.creator" />
  80. <meta content="Roberts, A.S." name="DC.creator" />
  81. <meta content="Skelton, B.W." name="DC.creator" />
  82. <meta content="Traill, P.R." name="DC.creator" />
  83. <meta content="White, A.H." name="DC.creator" />
  84. <meta content="259901 Organometallic Chemistry" name="DC.subject" />
  85. <meta content="The palladium(I1) complexes PdMeZ(tmeda1, PdMePh(tmeda), and Pd(CH2CHzCHzCHz)-
  86. (tmeda) (tmeda = tetramethylethylenediamine)r eact with potassium tris(pyrazo1-l-y1)borate
  87. and organohalides RX in acetone to form the octahedral palladium(IV) complexes PdMeRR”-
  88. {(pz)sBH}( R = Me, Ph) and Pd(CH2CHzCHzCH~)R{(pz)3BH(R} X = MeI, EtI, PhCHzBr,
  89. CHz=CHCH&amp;. The complexes are stable in the solid state and in solution at ambient
  90. temperature, PdMe3{(pz)3BH} is more stable than the iodide salt of isoelectronic [PdMes{(pz)a-
  91. CH}]+, and the aryl- and 17l-propenylpalladium(IV)c omplexes are the first examples of aryland
  92. allylpalladium(IV) complexes that are stable above 0 “C. The tris(pyrazo1-l-y1)borate
  93. ligand considerably enhances the stability of palladium( IV) complexes when compared with
  94. related neutral donor ligands. The ethylpalladium(rV) complexes have stabilities in solution
  95. similar to that of the most stable ethylpalladium(I1) complexes reported. The complex PdMea-
  96. {(~Z)~(B2)} h as been prepared, and structural studies of this complex and PdMe~R{(pz)3-
  97. BH} [ R= Me (l)E, t (3>]c ompleted, allowing the first comparison of structural parameters
  98. of ethylpalladium( 11, IV) complexes and of PdMe3{ (pz)3BH} with the “isoelectronic” cation
  99. [PdMe3{(pz)3CH}]+. Three polymorphs of PdMezEt{ (pz)3BH} were examined: complex 3a
  100. is ordered, but the other polymorphs exhibit disordering in the conformation of the ethyl
  101. group (3b) and in the position of the ethyl group and one of the methyl groups (3c).
  102. Crystallographic data: for 1, monoclinic, space group P21/c, a = 16.559(16) A, b = 7.859(4) A,c = 13.774(15)A , p = 118.88(8)”2, = 4, R = 0.032, R, = 0,043; for 2, monoclinic, space
  103. group P21/c, a = 11.453(1) A, b = 9.729(2) A, c = 16.973(9) A, p = 107.25(3)”, 2 = 4, R =
  104. 0.053, R, = 0.055; for 3a, monoclinic, P2&amp;, a = 9.384(3) A, b = 12.795(3) A, c = 15.119(8)
  105. A, p = 115.22(3)”, 2 = 4, R = 0.055, R, = 0.052; for 3b, orthorhombic, P212121, a = 13.955-
  106. (3) A, b = 13.152(18) A, c = 9.047(6) A, 2 = 4, R = 0.052, R, = 0.053; for 3c, tetragonal,
  107. P43212, a = 12.305(4) A, c = 21.542(7) A, 2 = 8, R = R, = 0.035." name="DC.description" />
  108. <meta content="1995" name="DC.date" />
  109. <meta content="Article" name="DC.type" />
  110. <meta content="PeerReviewed" name="DC.type" />
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  112. <meta content="http://eprints.utas.edu.au/2071/1/om00001a031.pdf" name="DC.identifier" />
  113. <meta content="Canty, A.J. and Jin, H. and Roberts, A.S. and Skelton, B.W. and Traill, P.R. and White, A.H. (1995) Synthesis and Characterization of Ambient Temperature Stable Organopalladium(IV) Complexes, Including Aryl-, hl-Allyl-, Ethylpalladium(IV), and Pallada(IV)cyclopentane Complexes. Structures of the Poly(pyrazo1-l-y1)borate Complexes PdMe3{(pz)3BH} and PdMe3{(pz)4B} and Three Polymorphs of PdMe2Et{(pz)3BH}. Organometallics, 14 . pp. 199-206." name="DC.identifier" />
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  220.     <h1 class="ep_tm_pagetitle">Synthesis and Characterization of Ambient Temperature Stable Organopalladium(IV) Complexes, Including Aryl-, hl-Allyl-, Ethylpalladium(IV), and Pallada(IV)cyclopentane Complexes. Structures of the Poly(pyrazo1-l-y1)borate Complexes PdMe3{(pz)3BH} and PdMe3{(pz)4B} and Three Polymorphs of PdMe2Et{(pz)3BH}</h1>
  221.     <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Canty, A.J.</span> and <span class="person_name">Jin, H.</span> and <span class="person_name">Roberts, A.S.</span> and <span class="person_name">Skelton, B.W.</span> and <span class="person_name">Traill, P.R.</span> and <span class="person_name">White, A.H.</span> (1995) <xhtml:em>Synthesis and Characterization of Ambient Temperature Stable Organopalladium(IV) Complexes, Including Aryl-, hl-Allyl-, Ethylpalladium(IV), and Pallada(IV)cyclopentane Complexes. Structures of the Poly(pyrazo1-l-y1)borate Complexes PdMe3{(pz)3BH} and PdMe3{(pz)4B} and Three Polymorphs of PdMe2Et{(pz)3BH}.</xhtml:em> Organometallics, 14 . pp. 199-206.</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2071/1/om00001a031.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" border="0" class="ep_doc_icon" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2071/1/om00001a031.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />983Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input value="2609" name="docid" accept-charset="utf-8" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">The palladium(I1) complexes PdMeZ(tmeda1, PdMePh(tmeda), and Pd(CH2CHzCHzCHz)-&#13;
  222. (tmeda) (tmeda = tetramethylethylenediamine)r eact with potassium tris(pyrazo1-l-y1)borate&#13;
  223. and organohalides RX in acetone to form the octahedral palladium(IV) complexes PdMeRR”-&#13;
  224. {(pz)sBH}( R = Me, Ph) and Pd(CH2CHzCHzCH~)R{(pz)3BH(R} X = MeI, EtI, PhCHzBr,&#13;
  225. CHz=CHCH&amp;. The complexes are stable in the solid state and in solution at ambient&#13;
  226. temperature, PdMe3{(pz)3BH} is more stable than the iodide salt of isoelectronic [PdMes{(pz)a-&#13;
  227. CH}]+, and the aryl- and 17l-propenylpalladium(IV)c omplexes are the first examples of aryland&#13;
  228. allylpalladium(IV) complexes that are stable above 0 “C. The tris(pyrazo1-l-y1)borate&#13;
  229. ligand considerably enhances the stability of palladium( IV) complexes when compared with&#13;
  230. related neutral donor ligands. The ethylpalladium(rV) complexes have stabilities in solution&#13;
  231. similar to that of the most stable ethylpalladium(I1) complexes reported. The complex PdMea-&#13;
  232. {(~Z)~(B2)} h as been prepared, and structural studies of this complex and PdMe~R{(pz)3-&#13;
  233. BH} [ R= Me (l)E, t (3&gt;]c ompleted, allowing the first comparison of structural parameters&#13;
  234. of ethylpalladium( 11, IV) complexes and of PdMe3{ (pz)3BH} with the “isoelectronic” cation&#13;
  235. [PdMe3{(pz)3CH}]+. Three polymorphs of PdMezEt{ (pz)3BH} were examined: complex 3a&#13;
  236. is ordered, but the other polymorphs exhibit disordering in the conformation of the ethyl&#13;
  237. group (3b) and in the position of the ethyl group and one of the methyl groups (3c).&#13;
  238. Crystallographic data: for 1, monoclinic, space group P21/c, a = 16.559(16) A, b = 7.859(4) A,c = 13.774(15)A , p = 118.88(8)”2, = 4, R = 0.032, R, = 0,043; for 2, monoclinic, space&#13;
  239. group P21/c, a = 11.453(1) A, b = 9.729(2) A, c = 16.973(9) A, p = 107.25(3)”, 2 = 4, R =&#13;
  240. 0.053, R, = 0.055; for 3a, monoclinic, P2&amp;, a = 9.384(3) A, b = 12.795(3) A, c = 15.119(8)&#13;
  241. A, p = 115.22(3)”, 2 = 4, R = 0.055, R, = 0.052; for 3b, orthorhombic, P212121, a = 13.955-&#13;
  242. (3) A, b = 13.152(18) A, c = 9.047(6) A, 2 = 4, R = 0.052, R, = 0.053; for 3c, tetragonal,&#13;
  243. P43212, a = 12.305(4) A, c = 21.542(7) A, 2 = 8, R = R, = 0.035.</p></div><table style="margin-bottom: 1em" border="0" cellpadding="3" class="not_ep_block"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/259901.html">250000 Chemical Sciences &gt; 259900 Other Chemical Sciences &gt; 259901 Organometallic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">Collections:</th><td valign="top" class="ep_row">UNSPECIFIED</td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2071</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">09 Oct 2007 15:53</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">01 Feb 2008 14:33</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2071;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&amp;eprintid=2071">item control page</a></p>
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