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<title>UTas ePrints - Transition Metal Organometallic Synthesis Utilising Diorganoiodine(III) Reagents</title>
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<meta content="Canty, A.J." name="eprints.creators_name" />
<meta content="Rodemann, Thomas" name="eprints.creators_name" />
<meta content="Ryan, John H." name="eprints.creators_name" />
<meta content="West, Robert" name="eprints.editors_name" />
<meta content="Hill, Anthony" name="eprints.editors_name" />
<meta content="book_section" name="eprints.type" />
<meta content="2007-08-27" name="eprints.datestamp" />
<meta content="2008-01-18T01:42:55Z" name="eprints.lastmod" />
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<meta content="Transition Metal Organometallic Synthesis Utilising Diorganoiodine(III) Reagents" name="eprints.title" />
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<meta content="250000" name="eprints.subjects" />
<meta content="restricted" name="eprints.full_text_status" />
<meta content=" Iodonium Organometallic Diorganoiodine(III), Oxidation Organic synthesis Alkynyl Alkenyl Iodine(III) " name="eprints.keywords" />
<meta content="Hypervalent iodine reagents have a prominent role in organic synthesis, but there is only a slowly emerging chemistry employing these reagents for transition metal organometallic synthesis, despite the early promising results reported in the 1960s. and extensive reports of the application of diorganoiodine(III) reagents in organic synthesis involving metal centres. This review summarises the fundamental aspects of mechanisms proposed for organic chemistry applications, reviews representative reports in organometallic chemistry with this perspective, and highlights the potential for further developments in the field.
" name="eprints.abstract" />
<meta content="2006" name="eprints.date" />
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<meta content="55" name="eprints.volume" />
<meta content="Elsevier" name="eprints.publisher" />
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<meta content="0 12 031152 6" name="eprints.isbn" />
<meta content="Advances in Organometallic Chemistry" name="eprints.book_title" />
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<meta content="(1) For a summary of reviews and books on this subject up to 2002, see Wirth, T. in Topics in Current Chemistry, Vol. 224, Hypervalent Iodine Chemistry -/- Modern Developments in Organic Synthesis, Wirth, T. Ed.; Springer-Verlag Publishers: Berlin Heidelberg 2003, Chapter 1, pp 1-4. (2) Varvoglis, A. Synthesis 1984, 709. (3) Varvoglis, A. The Organic Chemistry of Polycoordinated iodine; VCH Publishers, Inc.: New York, 1992. (4) Varvoglis, A. Hypervalent Iodine in Organic Synthesis, Academic Press: London, 1997. (5) Varvoglis, A. and Spyroudis, S. Syn. Lett. 1998, 221. (6) Stang, P. J.; and Zhdankin, V. V. Chem. Rev. 1996, 96, 1123. (7) Zhdankin, V. V.; Stang, P. J. Chem.Rev. 2002, 102, 2523. (8) Stang, P. J. J. Org. Chem. 2003, 68, 2997. (9) Koser, G. F. In The Chemistry of Functional Groups, Suppl. D; Patai, S. Rappaport, Z., Eds; Wiley-Interscience: Chichester, 1983; Chapters 18 and 25, pp 721 - 811 and 1265-1351. (10) Koser, G. F. In The Chemistry of Halides, Pseudo-Halides and Azides, Suppl. D2, Patai, S. Rappaport, Z., Eds; Wiley-Interscience: Chichester, 1995; Chapter 21, pp 1173-1274. (11) Akiba, K., Ed. Chemistry of Hypervalent Compounds; VCH Publishers: New York, 1999. (12) Wirth, T. Ed. Topics in Current Chemistry, Vol. 224, 2002 Hypervalent Iodine Chemistry -/- Modern Developments in Organic Synthesis; Springer-Verlag Publishers: Berlin Heidelberg 2003. (13) Nesmeyanov, A. N.; Chapovskii, Yu. A.; Lokshin, B. V.; Kisin, A. V.; Makarova, L. G. Dokl. Akad. Nauk SSSR, 1966, 171, 637. (14) Nesmeyanov, A. N.; Chapovsky, Yu. A.; Polovyanuk, I. V.; Makarova, L.G. J. Organomet. Chem. 1967, 7, 329. (15) Ochiai, M. J. Organomet. Chem. 2000, 611, 494. (16) Ochiai, M.; Kida, M.; Sato, K.; Takino, T.; Goto, S.; Donkai, N.; Okuyama, T. Tetrahedron Lett. 1999, 1559. (17) Canty, A.J.; Patel, J.; Rodemann, T.; Ryan, J. H.; Skelton, B. W.; White, A. H. Organometallics, 2004, 23, 3466. 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<meta content="Canty, A.J. and Rodemann, Thomas and Ryan, John H. (2006) Transition Metal Organometallic Synthesis Utilising Diorganoiodine(III) Reagents. In: Advances in Organometallic Chemistry. . Elsevier, USA. ISBN 0 12 031152 6 (In Press)" name="eprints.citation" />
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<meta content="Hypervalent iodine reagents have a prominent role in organic synthesis, but there is only a slowly emerging chemistry employing these reagents for transition metal organometallic synthesis, despite the early promising results reported in the 1960s. and extensive reports of the application of diorganoiodine(III) reagents in organic synthesis involving metal centres. This review summarises the fundamental aspects of mechanisms proposed for organic chemistry applications, reviews representative reports in organometallic chemistry with this perspective, and highlights the potential for further developments in the field.
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<h1 class="ep_tm_pagetitle">Transition Metal Organometallic Synthesis Utilising Diorganoiodine(III) Reagents</h1>
<p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Canty, A.J.</span> and <span class="person_name">Rodemann, Thomas</span> and <span class="person_name">Ryan, John H.</span> (2006) <xhtml:em>Transition Metal Organometallic Synthesis Utilising Diorganoiodine(III) Reagents.</xhtml:em> In: Advances in Organometallic Chemistry. . Elsevier, USA. ISBN 0 12 031152 6 (In Press)</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/1628/1/Adv_Organomet_Chem_Oct_06_v2.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/1628/1/Adv_Organomet_Chem_Oct_06_v2.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />356Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input accept-charset="utf-8" value="2102" name="docid" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://www.elsevier.com/wps/find/bookdescription.cws_home/BS_AOC/description#description">http://www.elsevier.com/wps/find/bookdescription.cws_home/BS_AOC/description#description</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">Hypervalent iodine reagents have a prominent role in organic synthesis, but there is only a slowly emerging chemistry employing these reagents for transition metal organometallic synthesis, despite the early promising results reported in the 1960s. and extensive reports of the application of diorganoiodine(III) reagents in organic synthesis involving metal centres. This review summarises the fundamental aspects of mechanisms proposed for organic chemistry applications, reviews representative reports in organometallic chemistry with this perspective, and highlights the potential for further developments in the field.
</p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Book Chapter</td></tr><tr><th valign="top" class="ep_row">Keywords:</th><td valign="top" class="ep_row"> Iodonium Organometallic Diorganoiodine(III), Oxidation Organic synthesis Alkynyl Alkenyl Iodine(III) </td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/250000.html">250000 Chemical Sciences</a></td></tr><tr><th valign="top" class="ep_row">Collections:</th><td valign="top" class="ep_row">UNSPECIFIED</td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">1628</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">UTas Digital Archives Librarian</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">27 Aug 2007</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">18 Jan 2008 12:42</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=1628;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=1628">item control page</a></p>
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