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<title>UTas ePrints - Structural Chemistry of the Platinum Group Metals: MC12(bpy) (M = Pd, Pt; bpy = 2,2'-Bipyridine)</title>
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<meta content="Canty, A.J." name="eprints.creators_name" />
<meta content="Skelton, B.W." name="eprints.creators_name" />
<meta content="Traill, P.R." name="eprints.creators_name" />
<meta content="White, A.H." name="eprints.creators_name" />
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<meta content="A single crystal X-ray structure determination of (2,2'-bipyridine)dichloropalladium(II), isomorphous
with the 'yellow' form of the platinum(II) analogue, has been carried out. Crystals are orthorhombic, Pbca, a l8.144(5), b 15.952(5), c 7.494(2) A, Z 8, 1113 diffractometer
reflections being refined by full matrix least squares to a residual of 0.052. The planar molecules of PdCl2(bpy) are stacked into columns along the c direction, at a separation of c/2, neighbouring molecules in the stacks being related by glide planes with Pd...Pd separations
of 4.587(2) A." name="eprints.abstract" />
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Byers, P. K., Canty, A. J., Skelton, B. W., and White, A. H., J. Chem. Soc., Chem.
Commun., 1986, 1722; Organometallics, 1990, 9, 826.
Canty, A. J., Watson, A. A., Skelton, B. W., and White, A. H., J. Organomet. Chem., 1989,
367, C25; Byers, P. K., Canty, A. J., Skelton, B. W., Traill, P. R., Watson, A. A., and White,
A. H., Organometallics, 1990, 9, 3080.
Canty, A. J., Traill, P. R., Skelton, B. W., and White, A. H., J. Organomet. Chem., 1991,
402, C33.
Livingstone, S. E., J. Proc. R. Soc. N.S. W., 1952, 86, 32.
Gray, L. R., Gulliver, D. J., Levason, W., and Webster, M., J. Chem. Soc., Dalton Bans.,
1983, 133.
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Hambley, T. W., Acta Crystallogr., Sect. C, 1986, 42, 49.
Ibers, J. A., and Hamilton, W. C., (Eds) 'International Tables for X-Ray Crystallography'
Vol. 4 (Kynoch Press: Birmingham 1974).
Hall, S. R., and Stewart, J. M., 'The XTAL Users Manual-Version 3.0', Universities of
Western Australia and Maryland, 1990
Anbei, J., Kruger, C., and Pfeil, B., Acta Crystallogr., Sect. C, 1987, 43, 2334.
Fronczek, F. R., Kahwa, I., Lu, S., Newkome, G. R., Ollino, M. A., Pitts, W. D., Sittattrakul,
A., Wang, J.-C., and Watkins, S. F., Acta Crystallogr., Sect. C, 1988, 44, 933.
Newkome, G. R., Fronczek, F. R., Gupta, V. K., Puckett, W. E., Pantaleo, D. C., and
Kiefer, G. E., J. Am. Chem. Soc., 1982, 104, 1782." name="eprints.referencetext" />
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<meta content="A single crystal X-ray structure determination of (2,2'-bipyridine)dichloropalladium(II), isomorphous
with the 'yellow' form of the platinum(II) analogue, has been carried out. Crystals are orthorhombic, Pbca, a l8.144(5), b 15.952(5), c 7.494(2) A, Z 8, 1113 diffractometer
reflections being refined by full matrix least squares to a residual of 0.052. The planar molecules of PdCl2(bpy) are stacked into columns along the c direction, at a separation of c/2, neighbouring molecules in the stacks being related by glide planes with Pd...Pd separations
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<h1 class="ep_tm_pagetitle">Structural Chemistry of the Platinum Group Metals: MC12(bpy) (M = Pd, Pt; bpy = 2,2'-Bipyridine)</h1>
<p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Canty, A.J.</span> and <span class="person_name">Skelton, B.W.</span> and <span class="person_name">Traill, P.R.</span> and <span class="person_name">White, A.H.</span> (1992) <xhtml:em>Structural Chemistry of the Platinum Group Metals: MC12(bpy) (M = Pd, Pt; bpy = 2,2'-Bipyridine).</xhtml:em> Australian Journal of Chemistry, 45 (2). pp. 417-422. ISSN 0004-9425</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2858/1/AJC1992_2C_417.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" border="0" class="ep_doc_icon" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2858/1/AJC1992_2C_417.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />254Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input value="4078" name="docid" accept-charset="utf-8" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://www.publish.csiro.au/nid/51/paper/CH9920417.htm">http://www.publish.csiro.au/nid/51/paper/CH9920417.htm</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">A single crystal X-ray structure determination of (2,2'-bipyridine)dichloropalladium(II), isomorphous
with the 'yellow' form of the platinum(II) analogue, has been carried out. Crystals are orthorhombic, Pbca, a l8.144(5), b 15.952(5), c 7.494(2) A, Z 8, 1113 diffractometer
reflections being refined by full matrix least squares to a residual of 0.052. The planar molecules of PdCl2(bpy) are stacked into columns along the c direction, at a separation of c/2, neighbouring molecules in the stacks being related by glide planes with Pd...Pd separations
of 4.587(2) A.</p></div><table style="margin-bottom: 1em" border="0" cellpadding="3" class="not_ep_block"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/250200.html">250000 Chemical Sciences > 250200 Inorganic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2858</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">15 Jan 2008 12:22</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">15 Jan 2008 12:22</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2858;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=2858">item control page</a></p>
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