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<meta content="Colton, R." name="eprints.creators_name" />
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<meta content="Pi-Bonded alkene and arene complexes of silver(I): an electrospray mass spectrometric study" name="eprints.title" />
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<meta content="Electrospray mass spectra have been observed for a number of alkene and arene complexes of Ag(1) formed by the interaction of AgN03 and the organometallic ligand in water/methanol solution. The ES mass spectra show that almost all the alkene and arene ligands in stoichiometric excess form labile 1:2 cationic complexes with Ag(I) which are easily decomposed by collisional activation to the 1:l species. However, with a deficiency of organic ligand polymeric species are observed. The cation [Ag(cod)2]+ (cod = 1,5-cyclooctadiene) was reacted with a variety of other potential ligands, such as PPh3, AsPh3, PhSCHSPh etc. In most cases, mixed complexes [Ag(cod)(ligand)]+ were observed, and excess ligand usually produced [Ag(ligand)2]+." name="eprints.abstract" />
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<h1 class="ep_tm_pagetitle">Pi-Bonded alkene and arene complexes of silver(I): an electrospray mass spectrometric study</h1>
<p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Canty, A.J.</span> and <span class="person_name">Colton, R.</span> (1994) <xhtml:em>Pi-Bonded alkene and arene complexes of silver(I): an electrospray mass spectrometric study.</xhtml:em> Inorganica Chimica Acta, 220 (1 - 2). pp. 99-105. ISSN 0020-1693</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2864/1/ICA1994_2C_99.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" border="0" class="ep_doc_icon" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2864/1/ICA1994_2C_99.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />681Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input value="4084" name="docid" accept-charset="utf-8" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1016/0020-1693(94)03861-9">http://dx.doi.org/10.1016/0020-1693(94)03861-9</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">Electrospray mass spectra have been observed for a number of alkene and arene complexes of Ag(1) formed by the interaction of AgN03 and the organometallic ligand in water/methanol solution. The ES mass spectra show that almost all the alkene and arene ligands in stoichiometric excess form labile 1:2 cationic complexes with Ag(I) which are easily decomposed by collisional activation to the 1:l species. However, with a deficiency of organic ligand polymeric species are observed. The cation [Ag(cod)2]+ (cod = 1,5-cyclooctadiene) was reacted with a variety of other potential ligands, such as PPh3, AsPh3, PhSCHSPh etc. In most cases, mixed complexes [Ag(cod)(ligand)]+ were observed, and excess ligand usually produced [Ag(ligand)2]+.</p></div><table style="margin-bottom: 1em" border="0" cellpadding="3" class="not_ep_block"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Additional Information:</th><td valign="top" class="ep_row">The definitive version is available at http://www.sciencedirect.com
</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/259901.html">250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2864</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">14 Jan 2008 15:36</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">14 Jan 2008 15:36</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2864;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=2864">item control page</a></p>
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