Newer
Older
Digital_Repository / Misc / Mass downloads / UTas / 2884.html
  1. <!DOCTYPE html PUBLIC "-//W3C//DTD XHTML 1.0 Transitional//EN"
  2. "http://www.w3.org/TR/xhtml1/DTD/xhtml1-transitional.dtd">
  3. <html>
  4. <head>
  5. <title>UTas ePrints - Organoplatinum(IV) and Palladium(IV) Complexes Containing Intramolecular Coordination Systems Based on the 8-Methylquinolinyl Group (mq), Including Structures of the Cation [Pt(mq)Me2(bpy)]+ (bpy = 2,2'-bipyridine) and the Palladium(IV) Complexes Pd(mq)MeR{(pz)2BH2} (R = Me, Ph; [(pz)2BH2]- = Bis(pyrazol-1-yl)borate)</title>
  6. <script type="text/javascript" src="http://eprints.utas.edu.au/javascript/auto.js"><!-- padder --></script>
  7. <style type="text/css" media="screen">@import url(http://eprints.utas.edu.au/style/auto.css);</style>
  8. <style type="text/css" media="print">@import url(http://eprints.utas.edu.au/style/print.css);</style>
  9. <link rel="icon" href="/images/eprints/favicon.ico" type="image/x-icon" />
  10. <link rel="shortcut icon" href="/images/eprints/favicon.ico" type="image/x-icon" />
  11. <link rel="Top" href="http://eprints.utas.edu.au/" />
  12. <link rel="Search" href="http://eprints.utas.edu.au/cgi/search" />
  13. <meta content="Canty, A.J." name="eprints.creators_name" />
  14. <meta content="Hoare, J.L." name="eprints.creators_name" />
  15. <meta content="Patel, J." name="eprints.creators_name" />
  16. <meta content="Pfeffer, M." name="eprints.creators_name" />
  17. <meta content="Skelton, B.W." name="eprints.creators_name" />
  18. <meta content="White, A.H." name="eprints.creators_name" />
  19. <meta content="allan.canty@utas.edu.au" name="eprints.creators_id" />
  20. <meta content="" name="eprints.creators_id" />
  21. <meta content="" name="eprints.creators_id" />
  22. <meta content="" name="eprints.creators_id" />
  23. <meta content="" name="eprints.creators_id" />
  24. <meta content="" name="eprints.creators_id" />
  25. <meta content="article" name="eprints.type" />
  26. <meta content="2008-01-16 03:22:03" name="eprints.datestamp" />
  27. <meta content="2008-01-16T03:34:59Z" name="eprints.lastmod" />
  28. <meta content="show" name="eprints.metadata_visibility" />
  29. <meta content="Organoplatinum(IV) and Palladium(IV) Complexes Containing Intramolecular Coordination Systems Based on the 8-Methylquinolinyl Group (mq), Including Structures of the Cation [Pt(mq)Me2(bpy)]+ (bpy = 2,2'-bipyridine) and the Palladium(IV) Complexes Pd(mq)MeR{(pz)2BH2} (R = Me, Ph; [(pz)2BH2]- = Bis(pyrazol-1-yl)borate)" name="eprints.title" />
  30. <meta content="pub" name="eprints.ispublished" />
  31. <meta content="259901" name="eprints.subjects" />
  32. <meta content="restricted" name="eprints.full_text_status" />
  33. <meta content="Oxidative addition of 8-(bromomethyl)quinoline (mqBr) to PdMeR(bpy) (R = Me, Ph; bpy = 2,2'-bipyridine) and [PdMeR{(pz)2BH2}]- (R = Me, Ph; [(pz)2BH2]- = bis(pyrazol-1-yl)borate]) has given the first isolable palladium(IV) complexes containing an intramolecular coordination system, [Pd(mq)MeR(bpy)]Br [R = Me (1), Ph (2)] and [Pd(mq)MeR{(pz)2BH2}- [R = Me (7), Ph (8)]. The pallada(IV)cyclic complex [Pd(CH2CH2CH2CH2)(mq)(bpy)]Br (6) has also been isolated. The first structural analysis of an arylpalladium(IV) complex, Pd(mq)MePh{(pz)2BH2} (8), is reported. Complex 8 occurs as two isomers and the one examined
  34. by X-ray crystallography has the fac-PdC3 configuration with the phenyl group trans to the quinoline nitrogen donor. NMR spectra of 8 indicate that the other isomer has the methyl group trans to the quinoline nitrogen donor. Similar geometric isomerism occurs for [Pd(mq)MePh(bpy)]BF4 (4). Structural studies of the dimethylpalladium(IV) complex Pd(mq)Me2{(pz)2BH2} (7) and the platinum(IV) cation in [Pt(mq)Me2(bpy)]BF4.0.75(CH2Cl2) (5) reveal
  35. similar structures. The cation [Pd(mq)Me2(bpy)]+ is less stable than the methyl(phenyl)palladium(IV) analogue (2), decomposing in (CD3)2CO by reductive elimination to form ethane and 8-ethylquinoline in ~1:2 ratio, together with the Pd(II) products [Pd(mq)(bpy)]Br and PdBrMe(bpy). A complex mixture of 8-substituted-quinolines (saturated and unsaturated substituents) were obtained as the major products of decomposition of [Pd(CH2CH2CH2CH2)(mq)(bpy)]Br (6), consistent with mq...CH2 coupling to give Pd(II) species that undergo further decomposition." name="eprints.abstract" />
  36. <meta content="1999" name="eprints.date" />
  37. <meta content="published" name="eprints.date_type" />
  38. <meta content="Organometallics" name="eprints.publication" />
  39. <meta content="18" name="eprints.volume" />
  40. <meta content="14" name="eprints.number" />
  41. <meta content="2660-2667" name="eprints.pagerange" />
  42. <meta content="10.1021/om99010k" name="eprints.id_number" />
  43. <meta content="TRUE" name="eprints.refereed" />
  44. <meta content="0276-7333" name="eprints.issn" />
  45. <meta content="http://dx.doi.org/10.1021/om990130k" name="eprints.official_url" />
  46. <meta content="(1) (a) Ryabov, A. D. Synthesis 1985, 233. (b) Pfeffer, M. Recl. Trav.
  47. Chim. Pays-Bas 1990, 109, 567. (c) Pfeffer, M. Pure Appl. Chem. 1992,
  48. 64, 335. (d) Spencer, J.; Pfeffer, M. In Advanced Metal-Organic
  49. Chemistry Liebeskind, L. S., Ed.; JAI Press: London, 1998; Vol. 6, p
  50. 103.
  51. (2) (a) Canty, A. J. Acc. Chem. Res. 1992, 25, 83. (b) Canty, A. J. In
  52. Comprehensive Organometallic Chemistry, 2nd ed.; Puddephatt, R. J.,
  53. Ed.; Pergamon Press: New York, 1995; Vol. 9, Chapter 5, p 225.
  54.  
  55. (3) Weinberg, E. L.; Hunter, B. K.; Baird, M. C. J. Organomet. Chem.
  56. 1982, 240, 95.
  57. (4) Alsters, P. L.; Engel, P. F.; Hogerheide, M. P.; Copijn, M.; Spek,
  58. A. L.; van Koten, G. Organometallics 1993, 12, 1831.
  59. (5) Byers, P. K.; Canty, A. J.; Skelton, B. W.; Traill, P. R.; Watson,
  60. A. A.; White, A. H. Organometallics 1990, 9, 3080.
  61.  
  62. (6) Canty, A. J.; Jin, H.; Roberts, A. S.; Skelton, B. W.; Traill, P. R.;
  63. White, A. H. Organometallics 1995, 14, 199.
  64. (7) de Graaf, W.; Boersma, J.; van Koten, G. Organometallics 1990,
  65. 9, 1479.
  66. (8) (a) Markies, B. A.; Canty, A. J.; Boersma, J.; van Koten, G.
  67. Organometallics 1994, 13, 2053. (b) Kruis, D.; Markies, B. A.; Canty,
  68. A. J.; Boersma, J.; van Koten, G. J. Organomet. Chem. 1997, 532, 235.
  69. (9) (a) Hartwell, G. E.; Lawrence, R. V.; Smas, M. J. J. Chem. Soc.
  70. D 1970, 912. (b) Bahsoun, A.; Dehand, J.; Pfeffer, M.; Zinsius, M.;
  71. Bouaoud, S.-E.; Le Borgne, G. J. Chem. Soc., Dalton Trans. 1979, 547.
  72. (c) Pfeffer, M.; Grandjean, D.; Le Borgne, G. Inorg. Chem. 1981, 20,
  73. 4426. (d) Braunstein, P.; Matt, D.; Dusausoy, Y.; Fischer, J.; Mitschler,
  74. A.; Ricard, L. J. Am. Chem. Soc. 1981, 103, 5115. (e) Deeming, A. J.;
  75. Rothwell, I. P. J. Organomet. Chem. 1981, 205, 117. (f) Dehand, J.;
  76. Mauro, A.; Ossor, H.; Pfeffer, M.; Santos, R. H. De A.; Lechat, J. R. J.
  77. Organomet. Chem. 1983, 250, 537. (g) Arlen, C.; Pfeffer, M.; Bars, O.;
  78. Grandjean, D. J. Chem. Soc., Dalton Trans. 1983, 1535. (h) Braunstein,
  79. P.; Fischer, J.; Matt, D.; Pfeffer, M. J. Am. Chem. Soc. 1984, 106, 410.
  80. (i) Suggs, J. W.; Lee, K. S. J. Organomet. Chem. 1986, 299, 297. (j)
  81. Maassarani, F.; Pfeffer, M.; Le Borgne, G.; Jastrzebski, J. T. B. H.;
  82. van Koten, G. Organometallics 1987, 6, 1111. (k) Ossor, H.; Pfeffer,
  83. M.; Jastrzebski, J. T. B. H.; Stam, C. H. Inorg. Chem. 1987, 26, 1169.
  84. (l) Rheingold, A. L.; Wu, G.; Heck, R. F. Inorg. Chim. Acta 1987, 131,
  85. 147. (m) Pfeffer, M. Inorg. Synth. 1989, 26, 211. (n) Ara, I.; Fornie´s,
  86. J.; Navarro, R.; Sicilia, V.; Urriolabeitia, Polyhedron 1997, 16, 1963.
  87. (o) Fornie´s, J.; Navarro, R.; Sicilia, V. Polyhedron 1988, 7, 2659. (p)
  88. El-ghayoury, A.; Douce, L.; Skoulios, A.; Ziessel, R. Angew. Chem., Int.
  89. Ed. 1998, 37, 1255. (q) Fornie´s, J.; Navarro, R.; Sicilia, V.; Tomas, M.
  90. Inorg. Chim. Acta 1990, 168, 201.
  91. (10) ) (a) Wu, G.; Rheingold, A. L.; Heck, R. F. Organometallics 1986,
  92. 5, 1922. (b) Maassarani, F.; Pfeffer, M.; Le Borgne, G. J. Chem. Soc.,
  93. Chem. Commun. 1987, 565. (c) Maassarani, F.; Pfeffer, M.; Le Borgne,
  94. G. Organometallics 1987, 6, 2029. (d) Pfeffer, M.; Rotteveel, Rcl. Trav.
  95. Chim. Pays-Bas 1989, 108, 317. (e) Pereira, M. T.; Pfeffer, M.;
  96. Rotteveel, M. A. J. Organomet. Chem. 1989, 375, 139. (f) Pfeffer, M.;
  97. Rotteveel, M. A.; Le Borgne, G.; Fischer, J. J. Org. Chem. 1992, 57,
  98. 2147. (g) Pfeffer, M.; Sutter, J. P.; DeCian, A.; Fischer, J. Organometallics
  99. 1993, 12, 1167. (h) Camargo, M.; Dani, P.; Dupont, J.; de Souza,
  100. R. F.; Pfeffer, M.; Tkatchenko, I. J. Mol. Catal. A 1996, 109, 127.
  101.  
  102. (11) Trofimenko, S. Inorg. Chem. 1970, 12, 102.
  103. (12) Byers, P. K.; Canty, A. J. Organometallics 1990, 9, 210.
  104. (13) Markies, B. A.; Canty, A. J.; de Graaf, W.; Boersma, J.; Janssen,
  105. M.; Hogerheide, M. P.; Smeets, W. J. J.; Spek, A. L.; van Koten, G. J.
  106. Organomet. Chem. 1994, 482, 191.
  107. (14) Byers, P. K.; Canty, A. J.; Jin, H.; Kruis, D.; Markies, B. A.;
  108. Boersma, J.; van Koten, G. Inorg. Synth. 1998, 32, 162.
  109. (15) de Graaf, W.; Boersma, J.; Smeets, W. J. J.; Spek, A. L.; van
  110. Koten, G. Organometallics 1989, 8, 2907.
  111. (16) (a) Diversi, P.; Ingrosso, G.; Lucherini, A.; Murtas, S. J. Chem.
  112. Soc., Dalton Trans. 1980, 1633. (b) Diversi, P.; Ingrosso, G.; Lucherini,
  113. A. Inorg. Synth. 1993, 22, 167.
  114. (17) Kuyper, J.; van der Laan, R.; Jeanneaus, F.; Vrieze, K.
  115. Transition Met. Chem. 1976, 1, 199.
  116. (18) Buu-Hoı¨, N. G. Rcl. Trav. Chim. Pays-Bas 1954, 73, 197.
  117.  
  118. (19) Hall, S. R.; Stewart, J. M. The XTAL User’s Manual, Version
  119. 3.0; Universities of Western Australia and Maryland, 1990.
  120. (20) ) Canty, A. J.; Jin, H.; Roberts, A. S.; Skelton, B. W.; White, A.
  121. H. Organometallics 1996, 15, 5713.
  122. (21) Canty, A. J.; Fritsche, S. D.; Jin, H.; Patel, J.; Skelton, B. W.;
  123. White, A. H. Organometallics 1997, 16, 2175.
  124.  
  125. (22) Byers, P. K.; Canty, A. J.; Skelton, B. W.; White, A. H.
  126. Organometallics 1990, 9, 826.
  127. (23) Brown, D. G.; Byers, P. K.; Canty, A. J. Organometallics 1990,
  128. 9, 1231.
  129.  
  130. (24) Canty, A. J.; Hoare, J. L.; Davies, N. W.; Traill, P. R. Organometallics
  131. 1988, 17, 2046.
  132. (25) (a) Byers, P. K.; Canty, A. J.; Crespo, M.; Puddephatt, R. J.;
  133. Scott, J. D. Organometallics 1988, 7, 1363. (b) Du¨ cker-Benfer, C.; van
  134. Eldik, R.; Canty, A. J. Organometallics 1994, 13, 2412.
  135. (26) (a) Goldberg, K. I.; Yan, J.; Winter, E. L. J. Am. Chem. Soc.
  136. 1994, 116, 1573. (b) Goldberg, K. I.; Yan, J.; Breitung, E. M. J. Am.
  137. Chem. Soc. 1995, 117, 6889. (c) Williams, B. S.; Holland, A. W.;
  138. Goldberg, K. I. J. Am. Chem. Soc. 1999, 121, in press.
  139. (27) Hill, G. S.; Puddephatt, R. J. Organometallics 1998, 117, 1478.
  140. (28) van Asselt, R.; Rijnberg, E.; Elsevier, C. J. Organometallics
  141. 1994, 13, 706.
  142. Scheme 1. Synthesis of Complexes
  143. [Pd(mq)Me2(bpy)]Br f 0.35 {Me-Me +
  144. [Pd(mq)(bpy)]Br} + 0.65 {Me-mq + PdBrMe(bpy)}
  145. (1)
  146. Scheme 2. Reductive Elimination
  147.  
  148. (29) (a) Fahey, D. R. J. Organomet. Chem. 1971, 27, 283. (b) Alsters,
  149. P. L.; Engel, P. F.; Hogerheide, M. P.; Copijn, M.; Spek, A. L.; van
  150. Koten, G. Organometallics 1993, 12, 1831. (c) Canty, A. J.; Jin, H.;
  151. Roberts, A. S.; Skelton, B. W.; White, A. H. Organometallics 1996, 15,
  152. 5713.
  153. (30) ) (a) Catellani, M.; Fagnola, M. C. Angew. Chem., Int. Ed. Engl.
  154. 1994, 33, 2421. (b) Catellani, M.; Frignani, F.; Rangoni, A. Angew.
  155. Chem., Int. Ed. Engl. 1997, 36, 119. (c) Catellani, M.; Chiusoli, G. P.
  156. Gazz. Chim. Ital. 1993, 123, 1.
  157. (31) (a) Stock, L. M.; Tse, K-t.; Vorvick, L. J.; Walstrum, S. A. J.
  158. Org. Chem. 1981, 46, 1759. (b) Yoneyama, T.; Crabtree, R. H. J. Mol.
  159. Catal. A 1996, 108, 35. (c) Canty, A. J.; Jin, H.; Skelton, B. W.; White,
  160. A. H. Inorg. Chem. 1998, 37, 3975." name="eprints.referencetext" />
  161. <meta content="Canty, A.J. and Hoare, J.L. and Patel, J. and Pfeffer, M. and Skelton, B.W. and White, A.H. (1999) Organoplatinum(IV) and Palladium(IV) Complexes Containing Intramolecular Coordination Systems Based on the 8-Methylquinolinyl Group (mq), Including Structures of the Cation [Pt(mq)Me2(bpy)]+ (bpy = 2,2'-bipyridine) and the Palladium(IV) Complexes Pd(mq)MeR{(pz)2BH2} (R = Me, Ph; [(pz)2BH2]- = Bis(pyrazol-1-yl)borate). Organometallics, 18 (14). pp. 2660-2667. ISSN 0276-7333" name="eprints.citation" />
  162. <meta content="http://eprints.utas.edu.au/2884/1/Organomet1999_2C_2660.pdf" name="eprints.document_url" />
  163. <link rel="schema.DC" href="http://purl.org/DC/elements/1.0/" />
  164. <meta content="Organoplatinum(IV) and Palladium(IV) Complexes Containing Intramolecular Coordination Systems Based on the 8-Methylquinolinyl Group (mq), Including Structures of the Cation [Pt(mq)Me2(bpy)]+ (bpy = 2,2'-bipyridine) and the Palladium(IV) Complexes Pd(mq)MeR{(pz)2BH2} (R = Me, Ph; [(pz)2BH2]- = Bis(pyrazol-1-yl)borate)" name="DC.title" />
  165. <meta content="Canty, A.J." name="DC.creator" />
  166. <meta content="Hoare, J.L." name="DC.creator" />
  167. <meta content="Patel, J." name="DC.creator" />
  168. <meta content="Pfeffer, M." name="DC.creator" />
  169. <meta content="Skelton, B.W." name="DC.creator" />
  170. <meta content="White, A.H." name="DC.creator" />
  171. <meta content="259901 Organometallic Chemistry" name="DC.subject" />
  172. <meta content="Oxidative addition of 8-(bromomethyl)quinoline (mqBr) to PdMeR(bpy) (R = Me, Ph; bpy = 2,2'-bipyridine) and [PdMeR{(pz)2BH2}]- (R = Me, Ph; [(pz)2BH2]- = bis(pyrazol-1-yl)borate]) has given the first isolable palladium(IV) complexes containing an intramolecular coordination system, [Pd(mq)MeR(bpy)]Br [R = Me (1), Ph (2)] and [Pd(mq)MeR{(pz)2BH2}- [R = Me (7), Ph (8)]. The pallada(IV)cyclic complex [Pd(CH2CH2CH2CH2)(mq)(bpy)]Br (6) has also been isolated. The first structural analysis of an arylpalladium(IV) complex, Pd(mq)MePh{(pz)2BH2} (8), is reported. Complex 8 occurs as two isomers and the one examined
  173. by X-ray crystallography has the fac-PdC3 configuration with the phenyl group trans to the quinoline nitrogen donor. NMR spectra of 8 indicate that the other isomer has the methyl group trans to the quinoline nitrogen donor. Similar geometric isomerism occurs for [Pd(mq)MePh(bpy)]BF4 (4). Structural studies of the dimethylpalladium(IV) complex Pd(mq)Me2{(pz)2BH2} (7) and the platinum(IV) cation in [Pt(mq)Me2(bpy)]BF4.0.75(CH2Cl2) (5) reveal
  174. similar structures. The cation [Pd(mq)Me2(bpy)]+ is less stable than the methyl(phenyl)palladium(IV) analogue (2), decomposing in (CD3)2CO by reductive elimination to form ethane and 8-ethylquinoline in ~1:2 ratio, together with the Pd(II) products [Pd(mq)(bpy)]Br and PdBrMe(bpy). A complex mixture of 8-substituted-quinolines (saturated and unsaturated substituents) were obtained as the major products of decomposition of [Pd(CH2CH2CH2CH2)(mq)(bpy)]Br (6), consistent with mq...CH2 coupling to give Pd(II) species that undergo further decomposition." name="DC.description" />
  175. <meta content="1999" name="DC.date" />
  176. <meta content="Article" name="DC.type" />
  177. <meta content="PeerReviewed" name="DC.type" />
  178. <meta content="application/pdf" name="DC.format" />
  179. <meta content="http://eprints.utas.edu.au/2884/1/Organomet1999_2C_2660.pdf" name="DC.identifier" />
  180. <meta content="http://dx.doi.org/10.1021/om990130k" name="DC.relation" />
  181. <meta content="Canty, A.J. and Hoare, J.L. and Patel, J. and Pfeffer, M. and Skelton, B.W. and White, A.H. (1999) Organoplatinum(IV) and Palladium(IV) Complexes Containing Intramolecular Coordination Systems Based on the 8-Methylquinolinyl Group (mq), Including Structures of the Cation [Pt(mq)Me2(bpy)]+ (bpy = 2,2'-bipyridine) and the Palladium(IV) Complexes Pd(mq)MeR{(pz)2BH2} (R = Me, Ph; [(pz)2BH2]- = Bis(pyrazol-1-yl)borate). Organometallics, 18 (14). pp. 2660-2667. ISSN 0276-7333" name="DC.identifier" />
  182. <meta content="http://eprints.utas.edu.au/2884/" name="DC.relation" />
  183. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2884/BibTeX/epprod-eprint-2884.bib" title="BibTeX" type="text/plain" />
  184. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2884/ContextObject/epprod-eprint-2884.xml" title="OpenURL ContextObject" type="text/xml" />
  185. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2884/ContextObject::Dissertation/epprod-eprint-2884.xml" title="OpenURL Dissertation" type="text/xml" />
  186. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2884/ContextObject::Journal/epprod-eprint-2884.xml" title="OpenURL Journal" type="text/xml" />
  187. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2884/DC/epprod-eprint-2884.txt" title="Dublin Core" type="text/plain" />
  188. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2884/DIDL/epprod-eprint-2884.xml" title="DIDL" type="text/xml" />
  189. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2884/EndNote/epprod-eprint-2884.enw" title="EndNote" type="text/plain" />
  190. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2884/HTML/epprod-eprint-2884.html" title="HTML Citation" type="text/html; charset=utf-8" />
  191. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2884/METS/epprod-eprint-2884.xml" title="METS" type="text/xml" />
  192. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2884/MODS/epprod-eprint-2884.xml" title="MODS" type="text/xml" />
  193. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2884/RIS/epprod-eprint-2884.ris" title="Reference Manager" type="text/plain" />
  194. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2884/Refer/epprod-eprint-2884.refer" title="Refer" type="text/plain" />
  195. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2884/Simple/epprod-eprint-2884text" title="Simple Metadata" type="text/plain" />
  196. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2884/Text/epprod-eprint-2884.txt" title="ASCII Citation" type="text/plain; charset=utf-8" />
  197. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2884/XML/epprod-eprint-2884.xml" title="EP3 XML" type="text/xml" />
  198.  
  199. </head>
  200. <body bgcolor="#ffffff" text="#000000" onLoad="loadRoutine(); MM_preloadImages('images/eprints/ePrints_banner_r5_c5_f2.gif','images/eprints/ePrints_banner_r5_c7_f2.gif','images/eprints/ePrints_banner_r5_c8_f2.gif','images/eprints/ePrints_banner_r5_c9_f2.gif','images/eprints/ePrints_banner_r5_c10_f2.gif','images/eprints/ePrints_banner_r5_c11_f2.gif','images/eprints/ePrints_banner_r6_c4_f2.gif')">
  201. <div class="ep_noprint"><noscript><style type="text/css">@import url(http://eprints.utas.edu.au/style/nojs.css);</style></noscript></div>
  202.  
  203.  
  204.  
  205.  
  206. <table width="795" border="0" cellspacing="0" cellpadding="0">
  207. <tr>
  208. <td><script language="JavaScript1.2">mmLoadMenus();</script>
  209. <table border="0" cellpadding="0" cellspacing="0" width="795">
  210. <!-- fwtable fwsrc="eprints_banner_final2.png" fwbase="ePrints_banner.gif" fwstyle="Dreamweaver" fwdocid = "1249563342" fwnested="0" -->
  211. <tr>
  212. <td><img src="/images/eprints/spacer.gif" width="32" height="1" border="0" alt="" /></td>
  213. <td><img src="/images/eprints/spacer.gif" width="104" height="1" border="0" alt="" /></td>
  214. <td><img src="/images/eprints/spacer.gif" width="44" height="1" border="0" alt="" /></td>
  215. <td><img src="/images/eprints/spacer.gif" width="105" height="1" border="0" alt="" /></td>
  216. <td><img src="/images/eprints/spacer.gif" width="41" height="1" border="0" alt="" /></td>
  217. <td><img src="/images/eprints/spacer.gif" width="16" height="1" border="0" alt="" /></td>
  218. <td><img src="/images/eprints/spacer.gif" width="68" height="1" border="0" alt="" /></td>
  219. <td><img src="/images/eprints/spacer.gif" width="68" height="1" border="0" alt="" /></td>
  220. <td><img src="/images/eprints/spacer.gif" width="68" height="1" border="0" alt="" /></td>
  221. <td><img src="/images/eprints/spacer.gif" width="82" height="1" border="0" alt="" /></td>
  222. <td><img src="/images/eprints/spacer.gif" width="69" height="1" border="0" alt="" /></td>
  223. <td><img src="/images/eprints/spacer.gif" width="98" height="1" border="0" alt="" /></td>
  224. <td><img src="/images/eprints/spacer.gif" width="1" height="1" border="0" alt="" /></td>
  225. </tr>
  226. <tr>
  227. <td colspan="12"><img name="ePrints_banner_r1_c1" src="/images/eprints/ePrints_banner_r1_c1.gif" width="795" height="10" border="0" alt="" /></td>
  228. <td><img src="/images/eprints/spacer.gif" width="1" height="10" border="0" alt="" /></td>
  229. </tr>
  230. <tr>
  231. <td rowspan="6"><img name="ePrints_banner_r2_c1" src="/images/eprints/ePrints_banner_r2_c1.gif" width="32" height="118" border="0" alt="" /></td>
  232. <td rowspan="5"><a href="http://www.utas.edu.au/"><img name="ePrints_banner_r2_c2" src="/images/eprints/ePrints_banner_r2_c2.gif" width="104" height="103" border="0" alt="" /></a></td>
  233. <td colspan="10"><img name="ePrints_banner_r2_c3" src="/images/eprints/ePrints_banner_r2_c3.gif" width="659" height="41" border="0" alt="" /></td>
  234. <td><img src="/images/eprints/spacer.gif" width="1" height="41" border="0" alt="" /></td>
  235. </tr>
  236. <tr>
  237. <td colspan="3"><a href="http://eprints.utas.edu.au/"><img name="ePrints_banner_r3_c3" src="/images/eprints/ePrints_banner_r3_c3.gif" width="190" height="31" border="0" alt="" /></a></td>
  238. <td rowspan="2" colspan="7"><img name="ePrints_banner_r3_c6" src="/images/eprints/ePrints_banner_r3_c6.gif" width="469" height="37" border="0" alt="" /></td>
  239. <td><img src="/images/eprints/spacer.gif" width="1" height="31" border="0" alt="" /></td>
  240. </tr>
  241. <tr>
  242. <td colspan="3"><img name="ePrints_banner_r4_c3" src="/images/eprints/ePrints_banner_r4_c3.gif" width="190" height="6" border="0" alt="" /></td>
  243. <td><img src="/images/eprints/spacer.gif" width="1" height="6" border="0" alt="" /></td>
  244. </tr>
  245. <tr>
  246. <td colspan="2"><img name="ePrints_banner_r5_c3" src="/images/eprints/ePrints_banner_r5_c3.gif" width="149" height="1" border="0" alt="" /></td>
  247. <td rowspan="2" colspan="2"><a href="/information.html" onMouseOut="MM_swapImgRestore();MM_startTimeout()" onMouseOver="MM_showMenu(window.mm_menu_0821132634_0,0,25,null,'ePrints_banner_r5_c5');MM_swapImage('ePrints_banner_r5_c5','','/images/eprints/ePrints_banner_r5_c5_f2.gif',1);"><img name="ePrints_banner_r5_c5" src="/images/eprints/ePrints_banner_r5_c5.gif" width="57" height="25" border="0" alt="About" /></a></td>
  248. <td rowspan="2"><a href="/view/" onMouseOut="MM_swapImgRestore();MM_startTimeout()" onMouseOver="MM_showMenu(window.mm_menu_0821133021_1,0,25,null,'ePrints_banner_r5_c7');MM_swapImage('ePrints_banner_r5_c7','','/images/eprints/ePrints_banner_r5_c7_f2.gif',1);"><img name="ePrints_banner_r5_c7" src="/images/eprints/ePrints_banner_r5_c7.gif" width="68" height="25" border="0" alt="Browse" /></a></td>
  249. <td rowspan="2"><a href="/perl/search/simple" onMouseOut="MM_swapImgRestore();MM_startTimeout()" onMouseOver="MM_showMenu(window.mm_menu_0821133201_2,0,25,null,'ePrints_banner_r5_c8');MM_swapImage('ePrints_banner_r5_c8','','/images/eprints/ePrints_banner_r5_c8_f2.gif',1);"><img name="ePrints_banner_r5_c8" src="/images/eprints/ePrints_banner_r5_c8.gif" width="68" height="25" border="0" alt="Search" /></a></td>
  250. <td rowspan="2"><a href="/perl/register" onMouseOut="MM_swapImgRestore();MM_startTimeout();" onMouseOver="MM_showMenu(window.mm_menu_1018171924_3,0,25,null,'ePrints_banner_r5_c9');MM_swapImage('ePrints_banner_r5_c9','','/images/eprints/ePrints_banner_r5_c9_f2.gif',1);"><img name="ePrints_banner_r5_c9" src="/images/eprints/ePrints_banner_r5_c9.gif" width="68" height="25" border="0" alt="register" /></a></td>
  251. <td rowspan="2"><a href="/perl/users/home" onMouseOut="MM_swapImgRestore();MM_startTimeout()" onMouseOver="MM_showMenu(window.mm_menu_0821133422_4,0,25,null,'ePrints_banner_r5_c10');MM_swapImage('ePrints_banner_r5_c10','','/images/eprints/ePrints_banner_r5_c10_f2.gif',1);"><img name="ePrints_banner_r5_c10" src="/images/eprints/ePrints_banner_r5_c10.gif" width="82" height="25" border="0" alt="user area" /></a></td>
  252. <td rowspan="2"><a href="/help/" onMouseOut="MM_swapImgRestore();MM_startTimeout()" onMouseOver="MM_showMenu(window.mm_menu_0821133514_5,0,25,null,'ePrints_banner_r5_c11');MM_swapImage('ePrints_banner_r5_c11','','/images/eprints/ePrints_banner_r5_c11_f2.gif',1);"><img name="ePrints_banner_r5_c11" src="/images/eprints/ePrints_banner_r5_c11.gif" width="69" height="25" border="0" alt="Help" /></a></td>
  253. <td rowspan="3" colspan="4"><img name="ePrints_banner_r5_c12" src="/images/eprints/ePrints_banner_r5_c12.gif" width="98" height="40" border="0" alt="" /></td>
  254. <td><img src="/images/eprints/spacer.gif" width="1" height="1" border="0" alt="" /></td>
  255. </tr>
  256. <tr>
  257. <td rowspan="2"><img name="ePrints_banner_r6_c3" src="/images/eprints/ePrints_banner_r6_c3.gif" width="44" height="39" border="0" alt="ePrints home" /></td>
  258. <td><a href="/" onMouseOut="MM_swapImgRestore()" onMouseOver="MM_swapImage('ePrints_banner_r6_c4','','/images/eprints/ePrints_banner_r6_c4_f2.gif',1);"><img name="ePrints_banner_r6_c4" src="/images/eprints/ePrints_banner_r6_c4.gif" width="105" height="24" border="0" alt="ePrints home" /></a></td>
  259. <td><img src="/images/eprints/spacer.gif" width="1" height="24" border="0" alt="" /></td>
  260. </tr>
  261. <tr>
  262. <td><img name="ePrints_banner_r7_c2" src="/images/eprints/ePrints_banner_r7_c2.gif" width="104" height="15" border="0" alt="" /></td>
  263. <td colspan="8"><img name="ePrints_banner_r7_c4" src="/images/eprints/ePrints_banner_r7_c4.gif" width="517" height="15" border="0" alt="" /></td>
  264. <td><img src="/images/eprints/spacer.gif" width="1" height="15" border="0" alt="" /></td>
  265. </tr>
  266. </table></td>
  267. </tr>
  268. <tr><td><table width="100%" style="font-size: 90%; border: solid 1px #ccc; padding: 3px"><tr>
  269. <td align="left"><a href="http://eprints.utas.edu.au/cgi/users/home">Login</a> | <a href="http://eprints.utas.edu.au/cgi/register">Create Account</a></td>
  270. <td align="right" style="white-space: nowrap">
  271. <form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/search" style="display:inline">
  272. <input class="ep_tm_searchbarbox" size="20" type="text" name="q" />
  273. <input class="ep_tm_searchbarbutton" value="Search" type="submit" name="_action_search" />
  274. <input type="hidden" name="_order" value="bytitle" />
  275. <input type="hidden" name="basic_srchtype" value="ALL" />
  276. <input type="hidden" name="_satisfyall" value="ALL" />
  277. </form>
  278. </td>
  279. </tr></table></td></tr>
  280. <tr>
  281. <td class="toplinks"><!-- InstanceBeginEditable name="content" -->
  282.  
  283.  
  284. <div align="center">
  285. <table width="720" class="ep_tm_main"><tr><td align="left">
  286. <h1 class="ep_tm_pagetitle">Organoplatinum(IV) and Palladium(IV) Complexes Containing Intramolecular Coordination Systems Based on the 8-Methylquinolinyl Group (mq), Including Structures of the Cation [Pt(mq)Me2(bpy)]+ (bpy = 2,2'-bipyridine) and the Palladium(IV) Complexes Pd(mq)MeR{(pz)2BH2} (R = Me, Ph; [(pz)2BH2]- = Bis(pyrazol-1-yl)borate)</h1>
  287. <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Canty, A.J.</span> and <span class="person_name">Hoare, J.L.</span> and <span class="person_name">Patel, J.</span> and <span class="person_name">Pfeffer, M.</span> and <span class="person_name">Skelton, B.W.</span> and <span class="person_name">White, A.H.</span> (1999) <xhtml:em>Organoplatinum(IV) and Palladium(IV) Complexes Containing Intramolecular Coordination Systems Based on the 8-Methylquinolinyl Group (mq), Including Structures of the Cation [Pt(mq)Me2(bpy)]+ (bpy = 2,2'-bipyridine) and the Palladium(IV) Complexes Pd(mq)MeR{(pz)2BH2} (R = Me, Ph; [(pz)2BH2]- = Bis(pyrazol-1-yl)borate).</xhtml:em> Organometallics, 18 (14). pp. 2660-2667. ISSN 0276-7333</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2884/1/Organomet1999_2C_2660.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" border="0" class="ep_doc_icon" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2884/1/Organomet1999_2C_2660.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />158Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input value="4138" name="docid" accept-charset="utf-8" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1021/om990130k">http://dx.doi.org/10.1021/om990130k</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">Oxidative addition of 8-(bromomethyl)quinoline (mqBr) to PdMeR(bpy) (R = Me, Ph; bpy = 2,2'-bipyridine) and [PdMeR{(pz)2BH2}]- (R = Me, Ph; [(pz)2BH2]- = bis(pyrazol-1-yl)borate]) has given the first isolable palladium(IV) complexes containing an intramolecular coordination system, [Pd(mq)MeR(bpy)]Br [R = Me (1), Ph (2)] and [Pd(mq)MeR{(pz)2BH2}- [R = Me (7), Ph (8)]. The pallada(IV)cyclic complex [Pd(CH2CH2CH2CH2)(mq)(bpy)]Br (6) has also been isolated. The first structural analysis of an arylpalladium(IV) complex, Pd(mq)MePh{(pz)2BH2} (8), is reported. Complex 8 occurs as two isomers and the one examined&#13;
  288. by X-ray crystallography has the fac-PdC3 configuration with the phenyl group trans to the quinoline nitrogen donor. NMR spectra of 8 indicate that the other isomer has the methyl group trans to the quinoline nitrogen donor. Similar geometric isomerism occurs for [Pd(mq)MePh(bpy)]BF4 (4). Structural studies of the dimethylpalladium(IV) complex Pd(mq)Me2{(pz)2BH2} (7) and the platinum(IV) cation in [Pt(mq)Me2(bpy)]BF4.0.75(CH2Cl2) (5) reveal&#13;
  289. similar structures. The cation [Pd(mq)Me2(bpy)]+ is less stable than the methyl(phenyl)palladium(IV) analogue (2), decomposing in (CD3)2CO by reductive elimination to form ethane and 8-ethylquinoline in ~1:2 ratio, together with the Pd(II) products [Pd(mq)(bpy)]Br and PdBrMe(bpy). A complex mixture of 8-substituted-quinolines (saturated and unsaturated substituents) were obtained as the major products of decomposition of [Pd(CH2CH2CH2CH2)(mq)(bpy)]Br (6), consistent with mq...CH2 coupling to give Pd(II) species that undergo further decomposition.</p></div><table style="margin-bottom: 1em" border="0" cellpadding="3" class="not_ep_block"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/259901.html">250000 Chemical Sciences &gt; 259900 Other Chemical Sciences &gt; 259901 Organometallic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">Collections:</th><td valign="top" class="ep_row">UNSPECIFIED</td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2884</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">16 Jan 2008 14:22</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">16 Jan 2008 14:34</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2884;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&amp;eprintid=2884">item control page</a></p>
  290. </td></tr></table>
  291. </div>
  292.  
  293.  
  294.  
  295. <!-- InstanceEndEditable --></td>
  296. </tr>
  297. <tr>
  298. <td><!-- #BeginLibraryItem "/Library/footer_eprints.lbi" -->
  299. <table width="795" border="0" align="left" cellpadding="0" class="footer">
  300. <tr valign="top">
  301. <td colspan="2"><div align="center"><a href="http://www.utas.edu.au">UTAS home</a> | <a href="http://www.utas.edu.au/library/">Library home</a> | <a href="/">ePrints home</a> | <a href="/contact.html">contact</a> | <a href="/information.html">about</a> | <a href="/view/">browse</a> | <a href="/perl/search/simple">search</a> | <a href="/perl/register">register</a> | <a href="/perl/users/home">user area</a> | <a href="/help/">help</a></div><br /></td>
  302. </tr>
  303. <tr><td colspan="2"><p><img src="/images/eprints/footerline.gif" width="100%" height="4" /></p></td></tr>
  304. <tr valign="top">
  305. <td width="68%" class="footer">Authorised by the University Librarian<br />
  306. © University of Tasmania ABN 30 764 374 782<br />
  307. <a href="http://www.utas.edu.au/cricos/">CRICOS Provider Code 00586B</a> | <a href="http://www.utas.edu.au/copyright/copyright_disclaimers.html">Copyright &amp; Disclaimers</a> | <a href="http://www.utas.edu.au/accessibility/index.html">Accessibility</a> | <a href="http://eprints.utas.edu.au/feedback/">Site Feedback</a>  </td>
  308. <td width="32%"><div align="right">
  309. <p align="right" class="NoPrint"><a href="http://www.utas.edu.au/"><img src="http://www.utas.edu.au/shared/logos/unioftasstrip.gif" alt="University of Tasmania Home Page" width="260" height="16" border="0" align="right" /></a></p>
  310. <p align="right" class="NoPrint"><a href="http://www.utas.edu.au/"><br />
  311. </a></p>
  312. </div></td>
  313. </tr>
  314. <tr valign="top">
  315. <td><p>  </p></td>
  316. <td><div align="right"><span class="NoPrint"><a href="http://www.eprints.org/software/"><img src="/images/eprintslogo.gif" alt="ePrints logo" width="77" height="29" border="0" align="bottom" /></a></span></div></td>
  317. </tr>
  318. </table>
  319. <!-- #EndLibraryItem -->
  320. <div align="center"></div></td>
  321. </tr>
  322. </table>
  323.  
  324. </body>
  325. </html>