<!DOCTYPE html PUBLIC "-//W3C//DTD XHTML 1.0 Transitional//EN" "http://www.w3.org/TR/xhtml1/DTD/xhtml1-transitional.dtd"> <html> <head> <title>UTas ePrints - Unsymmetric Tripod Ligands Related Totis (PYRAZOL-1-YL) Methane</title> <script type="text/javascript" src="http://eprints.utas.edu.au/javascript/auto.js"><!-- padder --></script> <style type="text/css" media="screen">@import url(http://eprints.utas.edu.au/style/auto.css);</style> <style type="text/css" media="print">@import url(http://eprints.utas.edu.au/style/print.css);</style> <link rel="icon" href="/images/eprints/favicon.ico" type="image/x-icon" /> <link rel="shortcut icon" href="/images/eprints/favicon.ico" type="image/x-icon" /> <link rel="Top" href="http://eprints.utas.edu.au/" /> <link rel="Search" href="http://eprints.utas.edu.au/cgi/search" /> <meta content="Byers, P.K." name="eprints.creators_name" /> <meta content="Canty, A.J." name="eprints.creators_name" /> <meta content="Honeyman, R.T." name="eprints.creators_name" /> <meta content="Gardinier, J.R." name="eprints.creators_name" /> <meta content="Reger, D.L." name="eprints.creators_name" /> <meta content="" name="eprints.creators_id" /> <meta content="allan.canty@utas.edu.au" name="eprints.creators_id" /> <meta content="" name="eprints.creators_id" /> <meta content="" name="eprints.creators_id" /> <meta content="" name="eprints.creators_id" /> <meta content="article" name="eprints.type" /> <meta content="2008-02-04T22:59:27Z" name="eprints.datestamp" /> <meta content="2008-02-04T22:59:27Z" name="eprints.lastmod" /> <meta content="show" name="eprints.metadata_visibility" /> <meta content="Unsymmetric Tripod Ligands Related Totis (PYRAZOL-1-YL) Methane" name="eprints.title" /> <meta content="pub" name="eprints.ispublished" /> <meta content="250301" name="eprints.subjects" /> <meta content="public" name="eprints.full_text_status" /> <meta content="The syntheses of tripodal ligands related to tris(pyrazol-1-yl)methane are described. The synthesis of bis(pyrazol-1-yl)methanone, N-methylimidazole-2-carbaldehyde, bis(pyrazol-1-yl)(pyridin-2-yl)methane and bis(pyrazol-1-yl)(N-methylimidazol-2-yl)methane are documented. The synthetic strategy relies on condensation of bis(pyrazol-1-yl)methanone, (pz)2C=O, with aldehydes, R(H)C=O, to give (pz)2(R)CH and carbon dioxide. " name="eprints.abstract" /> <meta content="2004" name="eprints.date" /> <meta content="published" name="eprints.date_type" /> <meta content="Inorganic Syntheses" name="eprints.publication" /> <meta content="34" name="eprints.volume" /> <meta content="30-34" name="eprints.pagerange" /> <meta content="TRUE" name="eprints.refereed" /> <meta content="0073-8077" name="eprints.issn" /> <meta content="http://www.wiley.com/WileyCDA/WileyTitle/productCd-0471208256.html" name="eprints.official_url" /> <meta content="Byers, P.K. and Canty, A.J. and Honeyman, R.T. and Gardinier, J.R. and Reger, D.L. (2004) Unsymmetric Tripod Ligands Related Totis (PYRAZOL-1-YL) Methane. Inorganic Syntheses, 34 . pp. 30-34. ISSN 0073-8077" name="eprints.citation" /> <meta content="http://eprints.utas.edu.au/3088/1/IS2004.pdf" name="eprints.document_url" /> <link rel="schema.DC" href="http://purl.org/DC/elements/1.0/" /> <meta content="Unsymmetric Tripod Ligands Related Totis (PYRAZOL-1-YL) Methane" name="DC.title" /> <meta content="Byers, P.K." name="DC.creator" /> <meta content="Canty, A.J." name="DC.creator" /> <meta content="Honeyman, R.T." name="DC.creator" /> <meta content="Gardinier, J.R." name="DC.creator" /> <meta content="Reger, D.L." name="DC.creator" /> <meta content="250301 Organic Chemical Synthesis" name="DC.subject" /> <meta content="The syntheses of tripodal ligands related to tris(pyrazol-1-yl)methane are described. The synthesis of bis(pyrazol-1-yl)methanone, N-methylimidazole-2-carbaldehyde, bis(pyrazol-1-yl)(pyridin-2-yl)methane and bis(pyrazol-1-yl)(N-methylimidazol-2-yl)methane are documented. The synthetic strategy relies on condensation of bis(pyrazol-1-yl)methanone, (pz)2C=O, with aldehydes, R(H)C=O, to give (pz)2(R)CH and carbon dioxide. " name="DC.description" /> <meta content="2004" name="DC.date" /> <meta content="Article" name="DC.type" /> <meta content="PeerReviewed" name="DC.type" /> <meta content="application/pdf" name="DC.format" /> <meta content="http://eprints.utas.edu.au/3088/1/IS2004.pdf" name="DC.identifier" /> <meta content="http://www.wiley.com/WileyCDA/WileyTitle/productCd-0471208256.html" name="DC.relation" /> <meta content="Byers, P.K. and Canty, A.J. and Honeyman, R.T. and Gardinier, J.R. and Reger, D.L. (2004) Unsymmetric Tripod Ligands Related Totis (PYRAZOL-1-YL) Methane. Inorganic Syntheses, 34 . pp. 30-34. 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1em" class="not_ep_block"><span class="person_name">Byers, P.K.</span> and <span class="person_name">Canty, A.J.</span> and <span class="person_name">Honeyman, R.T.</span> and <span class="person_name">Gardinier, J.R.</span> and <span class="person_name">Reger, D.L.</span> (2004) <xhtml:em>Unsymmetric Tripod Ligands Related Totis (PYRAZOL-1-YL) Methane.</xhtml:em> Inorganic Syntheses, 34 . pp. 30-34. ISSN 0073-8077</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a onmouseover="EPJS_ShowPreview( event, 'doc_preview_4240' );" href="http://eprints.utas.edu.au/3088/1/IS2004.pdf" onmouseout="EPJS_HidePreview( event, 'doc_preview_4240' );"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a><div class="ep_preview" id="doc_preview_4240"><table><tr><td><img alt="" src="http://eprints.utas.edu.au/3088/thumbnails/1/preview.png" class="ep_preview_image" border="0" /><div class="ep_preview_title">Preview</div></td></tr></table></div></td><td valign="top"><a href="http://eprints.utas.edu.au/3088/1/IS2004.pdf"><span class="ep_document_citation">PDF</span></a> - Requires a PDF viewer<br />282Kb</td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://www.wiley.com/WileyCDA/WileyTitle/productCd-0471208256.html">http://www.wiley.com/WileyCDA/WileyTitle/productCd-0471208256.html</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">The syntheses of tripodal ligands related to tris(pyrazol-1-yl)methane are described. The synthesis of bis(pyrazol-1-yl)methanone, N-methylimidazole-2-carbaldehyde, bis(pyrazol-1-yl)(pyridin-2-yl)methane and bis(pyrazol-1-yl)(N-methylimidazol-2-yl)methane are documented. The synthetic strategy relies on condensation of bis(pyrazol-1-yl)methanone, (pz)2C=O, with aldehydes, R(H)C=O, to give (pz)2(R)CH and carbon dioxide. </p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/250301.html">250000 Chemical Sciences > 250300 Organic Chemistry > 250301 Organic Chemical Synthesis</a></td></tr><tr><th valign="top" class="ep_row">Collections:</th><td valign="top" class="ep_row">UNSPECIFIED</td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">3088</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">05 Feb 2008 09:59</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">05 Feb 2008 09:59</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=3088;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=3088">item control page</a></p> </td></tr></table> </div> <!-- InstanceEndEditable --></td> </tr> <tr> <td><!-- #BeginLibraryItem "/Library/footer_eprints.lbi" --> <table width="795" border="0" align="left" cellpadding="0" class="footer"> <tr valign="top"> <td colspan="2"><div align="center"><a href="http://www.utas.edu.au">UTAS home</a> | <a href="http://www.utas.edu.au/library/">Library home</a> | <a href="/">ePrints home</a> | <a href="/contact.html">contact</a> | <a href="/information.html">about</a> | <a href="/view/">browse</a> | <a href="/perl/search/simple">search</a> | <a href="/perl/register">register</a> | <a href="/perl/users/home">user area</a> | <a href="/help/">help</a></div><br /></td> </tr> <tr><td colspan="2"><p><img src="/images/eprints/footerline.gif" width="100%" height="4" /></p></td></tr> <tr valign="top"> <td width="68%" class="footer">Authorised by the University Librarian<br /> © University of Tasmania ABN 30 764 374 782<br /> <a href="http://www.utas.edu.au/cricos/">CRICOS Provider Code 00586B</a> | <a href="http://www.utas.edu.au/copyright/copyright_disclaimers.html">Copyright & Disclaimers</a> | <a href="http://www.utas.edu.au/accessibility/index.html">Accessibility</a> | <a href="http://eprints.utas.edu.au/feedback/">Site Feedback</a> </td> <td width="32%"><div align="right"> <p align="right" class="NoPrint"><a href="http://www.utas.edu.au/"><img src="http://www.utas.edu.au/shared/logos/unioftasstrip.gif" alt="University of Tasmania Home Page" width="260" height="16" border="0" align="right" /></a></p> <p align="right" class="NoPrint"><a href="http://www.utas.edu.au/"><br /> </a></p> </div></td> </tr> <tr valign="top"> <td><p> </p></td> <td><div align="right"><span class="NoPrint"><a href="http://www.eprints.org/software/"><img src="/images/eprintslogo.gif" alt="ePrints logo" width="77" height="29" border="0" align="bottom" /></a></span></div></td> </tr> </table> <!-- #EndLibraryItem --> <div align="center"></div></td> </tr> </table> </body> </html>