<!DOCTYPE html PUBLIC "-//W3C//DTD XHTML 1.0 Transitional//EN" "http://www.w3.org/TR/xhtml1/DTD/xhtml1-transitional.dtd"> <html> <head> <title>UTas ePrints - Re-equilibration of melt inclusions trapped by magnesian olivine phenocrysts from subduction-related magmas: petrological implications</title> <script type="text/javascript" src="http://eprints.utas.edu.au/javascript/auto.js"><!-- padder --></script> <style type="text/css" media="screen">@import url(http://eprints.utas.edu.au/style/auto.css);</style> <style type="text/css" media="print">@import url(http://eprints.utas.edu.au/style/print.css);</style> <link rel="icon" href="/images/eprints/favicon.ico" type="image/x-icon" /> <link rel="shortcut icon" href="/images/eprints/favicon.ico" type="image/x-icon" /> <link rel="Top" href="http://eprints.utas.edu.au/" /> <link rel="Search" href="http://eprints.utas.edu.au/cgi/search" /> <meta content="Danyushevsky, L.V." name="eprints.creators_name" /> <meta content="Della-Pasqua, F.N." name="eprints.creators_name" /> <meta content="Sokolov, S." name="eprints.creators_name" /> <meta content="l.dan@utas.edu.au" name="eprints.creators_id" /> <meta content="" name="eprints.creators_id" /> <meta content="" name="eprints.creators_id" /> <meta content="article" name="eprints.type" /> <meta content="2007-02-14" name="eprints.datestamp" /> <meta content="2008-01-08 15:30:00" name="eprints.lastmod" /> <meta content="show" name="eprints.metadata_visibility" /> <meta content="Re-equilibration of melt inclusions trapped by magnesian olivine phenocrysts from subduction-related magmas: petrological implications" name="eprints.title" /> <meta content="pub" name="eprints.ispublished" /> <meta content="260101" name="eprints.subjects" /> <meta content="260102" name="eprints.subjects" /> <meta content="restricted" name="eprints.full_text_status" /> <meta content="melt inclusions, olivine, petrology, geochemistry, subduction, magmatism, re-equilibration" name="eprints.keywords" /> <meta content="The original publication is available at www.springerlink.com" name="eprints.note" /> <meta content="We describe and model a potential re-equili- bration process that can affect compositions of melt inclusions in magnesian olivine phenocrysts. This pro- cess, referred to as ``Fe-loss'', can operate during natural pre-eruptive cooling of host magma and results in lower FeOt and higher MgO contents within the initially trapped volume of inclusion. The extent of Fe-loss is enhanced by large temperature intervals of magma cooling before eruption. The compositions of homoge- nised melt inclusions in olivine phenocrysts from several subduction-related suites demonstrate that (1) Fe-loss is a common process, (2) the maximum observed degree of re-equilibration varies between suites, and (3) within a single sample, variable degrees of re-equilibration can be recorded by melt inclusions trapped in olivine pheno- crysts of identical composition. Our modelling also demonstrates that the re-equilibration process is fast going to completion, in the largest inclusions in the most magnesian phenocrysts it is completed within 2 years. The results we obtained indicate that the possibility of Fe-loss must be considered when estimating composi- tions of parental subduction-related magmas from nat- urally quenched glassy melt inclusions in magnesian olivine phenocrysts. Compositions calculated from glassy inclusions affected by Fe-loss will inherit not only erroneously low FeOt contents, but also low MgO due to the inherited higher Mg# of the residual melt in re- equilibrated inclusions. We also demonstrate that due to the higher MgO contents of homogenised melt inclu- sions affected by Fe-loss, homogenisation temperatures achieved in heating experiments will be higher than original trapping temperatures. The extent of overheat- ing will increase depending on the degree of re-equili- bration, and can reach up to 50 degrees C in cases where complete re-equilibration occurs over a cooling interval of 200 degrees C." name="eprints.abstract" /> <meta content="2000-01" name="eprints.date" /> <meta content="published" name="eprints.date_type" /> <meta content="Contributions to Mineralogy and Petrology" name="eprints.publication" /> <meta content="138" name="eprints.volume" /> <meta content="1" name="eprints.number" /> <meta content="68-83" name="eprints.pagerange" /> <meta content="10.1007/PL00007664" name="eprints.id_number" /> <meta content="UNSPECIFIED" name="eprints.thesis_type" /> <meta content="TRUE" name="eprints.refereed" /> <meta content="http://dx.doi.org/10.1007/PL00007664" name="eprints.official_url" /> <meta content="Anderson AT (1974) Evidence for a picritic, volatile-rich magma beneath Mt. Shasta, California. J Petrol 15: 243±267 BarsdellM(1988) Petrology and petrogenesis of clinopyroxene-rich tholeiitic lavas, Merelava volcano, Vanuatu. J Petrol 29: 927± 964 Bowen NL (1928) The evolution of the igneous rocks. Dover, New York, p 334 Chakraborty S (1997) Rates and mechanisms of Fe-Mg interdif- fusion in olivine at 980±1300 °C. J Geophy Res 102B: 12317± 12331 Crawford AJ, Falloon TJ, Eggins S (1987) The origin of island arc high-alumina basalts. Contrib Mineral Petrol 97: 417±430 Danyushevsky LV, Sobolev AV (1996) Ferric-ferrous ratio and oxygen fugacity calculations for primitive mantle-derived melts: calibration of an empirical technique. Mineral Petrol 57: 229± 241 Danyushevsky LV, Sobolev AV, Falloon TJ (1995) North Tongan high-Ca boninite petrogenesis: the role of Samoan plume and subduction zone-transform fault transition. J Geodynamics 20: 219±241 Danyushevsky LV, Sobolev AV, Kononkova NN (1992) Methods of studying melt inclusions in minerals during investigations on water-bearing primitive mantle melts (Tonga trench boninites). Geochem Int 29: 48±62 Della-Pasqua FN (1997) Primitive ankaramitic magmas in volcanic arcs: evidence from melt inclusions. PhD Thesis, University of Tasmania Della-Pasqua FN, Varne R (1997) Primitive ankaramitic magmas in volcanic arcs: a melt inclusion approach. Can Mineral 35: 291±312 Eggins S (1993) Origin and di€erentiation of picritic arc magmas, Ambae (Aoba), Vanuatu. Contrib Mineral Petrol 114: 79±100 Falloon TJ, Green DH (1986) Glass inclusions in magnesian olivine phenocrysts from Tonga: evidence for highly refractory paren- tal magmas in the Tonga arc. Earth Planet Sci Lett 81: 95±103 Foden JD (1983) The petrology of the calcalkaline lavas of Rinjani volcano, east Sunda arc: a model for island arc petrogenesis. J Petrol 24: 98±130 Ford CE, Russel DG, Craven JA, Fisk MR (1983) Olivine-liquid equilibria: temperature, pressure and composition dependence of the crystal/liquid cation partition coeÂÂÂcients for Mg, Fe2+, Ca and Mn. J Petrol 24: 256±265 Gurenko AA, Sobolev AV, Kononkova NN (1992) New petrolog- ical data on Icelandic rift alkali basalts. Geochem Int 29: 41±53 Gurenko AA, Sobolev AV, Polyakov AI, Kononkova NN (1988) Primary melt of rift tholeiites of Iceland: composition and conditions of crystallisation. Trans (Doklady) USSR Acad Sci 301(4): 109±113 Kamenetsky VS, Metrich N, Cioni R (1995a) Potassic primary melts of Vulsini (Roman Province): evidence from mineralogy and melt inclusions. Contrib Mineral Petrol 120: 186±196 Kamenetsky VS, Sobolev AV, Joron JL, Semet MP (1995b) Pe- trology and geochemistry of Cretaceous ultrama®c volcanics from eastern Kamchatka. J Petrol 36: 637±662 Kamenetsky VS, Crawford AJ, Eggins S, MuheR(1997) Phenocryst and melt inclusion chemistry of near-axis seamounts, Valu Fa Ridge, Lau Basin: insight into mantle wedge melting and addition of subduction components. Earth Planet Sci Lett 151: 205±223 Lange RA, Carmichael ISE (1987) Densities of Na2O-K2O-CaO- MgO-FeO-Fe2O3-Al2O3-TiO2-SiO2 liquids: new measurements and derived partial molar properties. Geochim Cosmochim Acta 51: 2931±2946 Lee J, Stern RJ (1998) Glass inclusions in Mariana Arc pheno- crysts: a new perspective on magmatic evolution in a typical intra-oceanic arc. J Geol 106: 19±33 Niu Y, Batiza R (1991) In situ densities of MORB melts and residual mantle: Implications for buoyancy forces beneath mid- ocean ridges. J Geol 99: 767±775 Portnyagin MV, Danyushevsky LV, Kamenetsky VS (1997) Co- existence of two distinct mantle sources during formation of ophiolites: a case study of primitive pillow-lavas from the lowest part of the volcanic section of the Troodos Ophiolite, Cyprus. Contrib Mineral Petrol 128: 287±301 Ramsay WRH, Crawford AJ, Foden JD (1984) Field setting, mineralogy, chemistry and genesis of arc picrites, New Georgia, Solomon Islands. Contrib Mineral Petrol 88: 386±402 Roedder E (1979) Origin and signi®cance of magmatic inclusion. Bull Mine ral 102: 487±510 Roedder E (1984) Fluid inclusions. Rev Mineral 12 Roeder PL, Emslie RF (1970) Olivine-liquid equilibrium. Contrib Mineral Petrol 29: 275±289 Scowen PAH, Roeder PL, Helz RT (1991) Reequilibration of chromite within Kilauea Iki lava lake, Hawaii. Contrib Mineral Petrol 107: 8±20 Sinton CW, Christie DM, Coombs VL, Nielsen RL, Fisk MR (1993) Near primary melt inclusions in anorthite phenocrysts from the Galapagos Platform. Earth Planet Sci Lett 119: 527± 537 Sisson TW, Bronto S (1998) Evidence for pressure-release melting beneath magmatic arcs from basalt at Galungnung, Indonesia. Nature 391: 883±886 Sisson TW, Layne GD (1993) H2O in basalt and basaltic andesite glass inclusions from four subduction-related volcanoes. Earth Planet Sci Lett 117: 619±635 Sobolev AV, Danyushevsky LV (1994) Petrology and geochemistry of boninites from the North termination of the Tonga trench: constraints on the generation conditions of primary high-Ca boninite magmas. J Petrol 35: 1183±1211 Sobolev AV, Slutskiy AB (1984) Composition and crystallisation conditions of the initial melt of the Siberian meimechites in relation to the general problem of the ultrabasic magmas. Sov Geol Geophys 25: 93±104 Sobolev AV, Dmitriev LV, Baruskov VL, Nevsorov VN, Slutsky AB (1980) The formation conditions of the high-magnesium olivines from the monomineralic fraction of Luna 24 regolith. Proceedings of the 11th Lunar Sci Conf, pp 105±116 Sobolev AV, Danyushevsky LV, Dmitriev LV, Suschevskaya NM (1989) High-alumina magnesian tholeiite as the primary basalt magma at Midocean ridge. Geochem Int 26: 128±133 Sobolev AV, Portnyagin MV, Dmitriev LV, Tsamerian OP, Danyushevsky LV, Kononkova NN, Shimizu N, Robinson PT (1993) Petrology of ultrama®c lavas and associated rocks of the Troodos Massif, Cyprus. Petrology 1: 331±361 Tait S (1992) Selective preservation of melt inclusions in igneous phenocrysts. Am Mineral 77: 146±155 Ulmer P (1989) The dependence of the Fe2+±Mg cation-parti- tioning between olivine and basaltic liquid on pressure, temperature and composition. An experimental study to 30 kbar. Contrib Mineral Petrol 101: 261±273 Walker DA, Cameron WE (1983) Boninite primary magmas: evi- dence from the Cape Vogel peninsula, PNG. Contrib Mineral Petrol 83: 150±158" name="eprints.referencetext" /> <meta content="Danyushevsky, L.V. and Della-Pasqua, F.N. and Sokolov, S. (2000) Re-equilibration of melt inclusions trapped by magnesian olivine phenocrysts from subduction-related magmas: petrological implications. Contributions to Mineralogy and Petrology, 138 (1). pp. 68-83." name="eprints.citation" /> <meta content="http://eprints.utas.edu.au/721/1/CMP2000.pdf" name="eprints.document_url" /> <link rel="schema.DC" href="http://purl.org/DC/elements/1.0/" /> <meta content="Re-equilibration of melt inclusions trapped by magnesian olivine phenocrysts from subduction-related magmas: petrological implications" name="DC.title" /> <meta content="Danyushevsky, L.V." name="DC.creator" /> <meta content="Della-Pasqua, F.N." name="DC.creator" /> <meta content="Sokolov, S." name="DC.creator" /> <meta content="260101 Mineralogy and Crystallography" name="DC.subject" /> <meta content="260102 Igneous and Metamorphic Petrology" name="DC.subject" /> <meta content="We describe and model a potential re-equili- bration process that can affect compositions of melt inclusions in magnesian olivine phenocrysts. This pro- cess, referred to as ``Fe-loss'', can operate during natural pre-eruptive cooling of host magma and results in lower FeOt and higher MgO contents within the initially trapped volume of inclusion. The extent of Fe-loss is enhanced by large temperature intervals of magma cooling before eruption. The compositions of homoge- nised melt inclusions in olivine phenocrysts from several subduction-related suites demonstrate that (1) Fe-loss is a common process, (2) the maximum observed degree of re-equilibration varies between suites, and (3) within a single sample, variable degrees of re-equilibration can be recorded by melt inclusions trapped in olivine pheno- crysts of identical composition. Our modelling also demonstrates that the re-equilibration process is fast going to completion, in the largest inclusions in the most magnesian phenocrysts it is completed within 2 years. The results we obtained indicate that the possibility of Fe-loss must be considered when estimating composi- tions of parental subduction-related magmas from nat- urally quenched glassy melt inclusions in magnesian olivine phenocrysts. Compositions calculated from glassy inclusions affected by Fe-loss will inherit not only erroneously low FeOt contents, but also low MgO due to the inherited higher Mg# of the residual melt in re- equilibrated inclusions. We also demonstrate that due to the higher MgO contents of homogenised melt inclu- sions affected by Fe-loss, homogenisation temperatures achieved in heating experiments will be higher than original trapping temperatures. The extent of overheat- ing will increase depending on the degree of re-equili- bration, and can reach up to 50 degrees C in cases where complete re-equilibration occurs over a cooling interval of 200 degrees C." name="DC.description" /> <meta content="2000-01" name="DC.date" /> <meta content="Article" name="DC.type" /> <meta content="PeerReviewed" name="DC.type" /> <meta content="application/pdf" name="DC.format" /> <meta content="http://eprints.utas.edu.au/721/1/CMP2000.pdf" name="DC.identifier" /> <meta content="http://dx.doi.org/10.1007/PL00007664" name="DC.relation" /> <meta content="Danyushevsky, L.V. and Della-Pasqua, F.N. and Sokolov, S. (2000) Re-equilibration of melt inclusions trapped by magnesian olivine phenocrysts from subduction-related magmas: petrological implications. 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border: solid 1px #ccc; padding: 3px"><tr> <td align="left"><a href="http://eprints.utas.edu.au/cgi/users/home">Login</a> | <a href="http://eprints.utas.edu.au/cgi/register">Create Account</a></td> <td align="right" style="white-space: nowrap"> <form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/search" style="display:inline"> <input class="ep_tm_searchbarbox" size="20" type="text" name="q" /> <input class="ep_tm_searchbarbutton" value="Search" type="submit" name="_action_search" /> <input type="hidden" name="_order" value="bytitle" /> <input type="hidden" name="basic_srchtype" value="ALL" /> <input type="hidden" name="_satisfyall" value="ALL" /> </form> </td> </tr></table></td></tr> <tr> <td class="toplinks"><!-- InstanceBeginEditable name="content" --> <div align="center"> <table width="720" class="ep_tm_main"><tr><td align="left"> <h1 class="ep_tm_pagetitle">Re-equilibration of melt inclusions trapped by magnesian olivine phenocrysts from subduction-related magmas: petrological implications</h1> <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Danyushevsky, L.V.</span> and <span class="person_name">Della-Pasqua, F.N.</span> and <span class="person_name">Sokolov, S.</span> (2000) <xhtml:em>Re-equilibration of melt inclusions trapped by magnesian olivine phenocrysts from subduction-related magmas: petrological implications.</xhtml:em> Contributions to Mineralogy and Petrology, 138 (1). pp. 68-83.</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/721/1/CMP2000.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/721/1/CMP2000.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />548Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input accept-charset="utf-8" value="731" name="docid" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1007/PL00007664">http://dx.doi.org/10.1007/PL00007664</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">We describe and model a potential re-equili- bration process that can affect compositions of melt inclusions in magnesian olivine phenocrysts. This pro- cess, referred to as ``Fe-loss'', can operate during natural pre-eruptive cooling of host magma and results in lower FeOt and higher MgO contents within the initially trapped volume of inclusion. The extent of Fe-loss is enhanced by large temperature intervals of magma cooling before eruption. The compositions of homoge- nised melt inclusions in olivine phenocrysts from several subduction-related suites demonstrate that (1) Fe-loss is a common process, (2) the maximum observed degree of re-equilibration varies between suites, and (3) within a single sample, variable degrees of re-equilibration can be recorded by melt inclusions trapped in olivine pheno- crysts of identical composition. Our modelling also demonstrates that the re-equilibration process is fast going to completion, in the largest inclusions in the most magnesian phenocrysts it is completed within 2 years. The results we obtained indicate that the possibility of Fe-loss must be considered when estimating composi- tions of parental subduction-related magmas from nat- urally quenched glassy melt inclusions in magnesian olivine phenocrysts. Compositions calculated from glassy inclusions affected by Fe-loss will inherit not only erroneously low FeOt contents, but also low MgO due to the inherited higher Mg# of the residual melt in re- equilibrated inclusions. We also demonstrate that due to the higher MgO contents of homogenised melt inclu- sions affected by Fe-loss, homogenisation temperatures achieved in heating experiments will be higher than original trapping temperatures. The extent of overheat- ing will increase depending on the degree of re-equili- bration, and can reach up to 50 degrees C in cases where complete re-equilibration occurs over a cooling interval of 200 degrees C.</p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Additional Information:</th><td valign="top" class="ep_row">The original publication is available at www.springerlink.com</td></tr><tr><th valign="top" class="ep_row">Keywords:</th><td valign="top" class="ep_row">melt inclusions, olivine, petrology, geochemistry, subduction, magmatism, re-equilibration</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/260101.html">260000 Earth Sciences > 260100 Geology > 260101 Mineralogy and Crystallography</a><br /><a href="http://eprints.utas.edu.au/view/subjects/260102.html">260000 Earth Sciences > 260100 Geology > 260102 Igneous and Metamorphic Petrology</a></td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">721</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Assoc. Prof Leonid Danyushevsky</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">14 Feb 2007</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">09 Jan 2008 02:30</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=721;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=721">item control page</a></p> </td></tr></table> </div> <!-- InstanceEndEditable --></td> </tr> <tr> <td><!-- #BeginLibraryItem "/Library/footer_eprints.lbi" --> <table width="795" border="0" align="left" cellpadding="0" class="footer"> <tr valign="top"> <td colspan="2"><div align="center"><a href="http://www.utas.edu.au">UTAS home</a> | <a href="http://www.utas.edu.au/library/">Library home</a> | <a href="/">ePrints home</a> | <a href="/contact.html">contact</a> | <a href="/information.html">about</a> | <a href="/view/">browse</a> | <a href="/perl/search/simple">search</a> | <a href="/perl/register">register</a> | <a href="/perl/users/home">user area</a> | <a href="/help/">help</a></div><br /></td> </tr> <tr><td colspan="2"><p><img src="/images/eprints/footerline.gif" width="100%" height="4" /></p></td></tr> <tr valign="top"> <td width="68%" class="footer">Authorised by the University Librarian<br /> © University of Tasmania ABN 30 764 374 782<br /> <a href="http://www.utas.edu.au/cricos/">CRICOS Provider Code 00586B</a> | <a href="http://www.utas.edu.au/copyright/copyright_disclaimers.html">Copyright & Disclaimers</a> | <a href="http://www.utas.edu.au/accessibility/index.html">Accessibility</a> | <a href="http://eprints.utas.edu.au/feedback/">Site Feedback</a> </td> <td width="32%"><div align="right"> <p align="right" class="NoPrint"><a href="http://www.utas.edu.au/"><img src="http://www.utas.edu.au/shared/logos/unioftasstrip.gif" alt="University of Tasmania Home Page" width="260" height="16" border="0" align="right" /></a></p> <p align="right" class="NoPrint"><a href="http://www.utas.edu.au/"><br /> </a></p> </div></td> </tr> <tr valign="top"> <td><p> </p></td> <td><div align="right"><span class="NoPrint"><a href="http://www.eprints.org/software/"><img src="/images/eprintslogo.gif" alt="ePrints logo" width="77" height="29" border="0" align="bottom" /></a></span></div></td> </tr> </table> <!-- #EndLibraryItem --> <div align="center"></div></td> </tr> </table> </body> </html>