<!DOCTYPE html PUBLIC "-//W3C//DTD XHTML 1.0 Transitional//EN" "http://www.w3.org/TR/xhtml1/DTD/xhtml1-transitional.dtd"> <html> <head> <title>UTas ePrints - Possible submarine advanced argillic alteration at the Basin Lake prospect, Western Tasmania, Australia</title> <script type="text/javascript" src="http://eprints.utas.edu.au/javascript/auto.js"><!-- padder --></script> <style type="text/css" media="screen">@import url(http://eprints.utas.edu.au/style/auto.css);</style> <style type="text/css" media="print">@import url(http://eprints.utas.edu.au/style/print.css);</style> <link rel="icon" href="/images/eprints/favicon.ico" type="image/x-icon" /> <link rel="shortcut icon" href="/images/eprints/favicon.ico" type="image/x-icon" /> <link rel="Top" href="http://eprints.utas.edu.au/" /> <link rel="Search" href="http://eprints.utas.edu.au/cgi/search" /> <meta content="Williams, N.C." name="eprints.creators_name" /> <meta content="Davidson, G.J." name="eprints.creators_name" /> <meta content="nwilliams@eos.ubc.ca" name="eprints.creators_id" /> <meta content="Garry.Davidson@utas.edu.au" name="eprints.creators_id" /> <meta content="article" name="eprints.type" /> <meta content="2007-10-09 17:01:34" name="eprints.datestamp" /> <meta content="2008-01-08 15:30:00" name="eprints.lastmod" /> <meta content="show" name="eprints.metadata_visibility" /> <meta content="Possible submarine advanced argillic alteration at the Basin Lake prospect, Western Tasmania, Australia" name="eprints.title" /> <meta content="pub" name="eprints.ispublished" /> <meta content="260100" name="eprints.subjects" /> <meta content="restricted" name="eprints.full_text_status" /> <meta content="stable isotopes, acid alteration,volcanic massive sulfides, Mt Read Volcanic Belt, Cambrian, enargite, silica replacement, copper, gold, barite" name="eprints.keywords" /> <meta content="The Basin Lake copper-gold prospect lies in western Tasmania’s Mount Read Volcanics and is hosted in a series of calc-alkaline andesites, quartz-feldspar porphyries, mudstones, carbonates, and sandstones between the Tyndall Group and the Central Volcanic Complex. Alteration at the Basin Lake prospect occurs over a strike length of 1.4 km and includes thin, strata-bound pyrophyllite-quartz-paragonite-kaolinite-pyrite-alunite alteration zones, up to 12 m wide and containing up to 50 wt percent pyrophyllite, with local fluorite veining. These zones grade out to paragonite-muscovite-kaolinite-quartz-pyrite and muscovite-carbonate-chlorite alteration zones. Extensive propylitic alteration (chlorite-carbonate-epidote) affects most other rocks outside these zones. Mineralization consists of thin strata-bound zones of massive and vein pyrite, tennantite, and chalcopyrite, with trace covellite and galena, hosted mainly within an intensely silicified core of the pyrophyllite-quartzsericite alteration zone. Pyrite has δ34S values of –1.4 to +6.9 per mil, although marginal vein pyrite in the propylitic zone has δ34S values around 12.4 per mil. Large silicified glacial erratic boulders at surface contain massive and vein pyrite, enargite, and tennantite, with minor barite, and trace covellite, stannoidite, and mawsonite. Pyrite and enargite have δ34S values of 1.7 to 6.8 per mil; barite has δ34S values around 35.2 per mil with 87Sr/86Sr around 0.7108. The alteration and mineralization at the Basin Lake prospect is similar to that associated with high-sulfidation copper-gold systems formed by acidic, relatively oxidized fluids. A new geochemical vector, here termed the “advanced argillic alteration index” [AAAI = 100 (SiO2)/(SiO2 + 10MgO + 10CaO + 10Na2O)], has been devised to help quantify the intensity of alteration. The values of the AAAI at Basin Lake are similar to those of several high-sulfidation epithermal deposits. The low sulfide δ34S values are similar to those at other sulfide occurrences in the Mount Read Volcanics that have previously been considered to be barren, are lower than those of nearby volcanic-hosted massive sulfide deposits, and may indicate a magmatic fluid component. However, the δ34S and 87Sr/86Sr values of Basin Lake barite at the assumed highest exposed level of the system and higher δ34S values in pyrite from marginal veins are similar to those of Cambrian volcanic-hosted massive sulfide systems, indicating the involvement of reduced seawater sulfate at these locations. Calcite carbon and oxygen isotope values, silicate oxygen isotope values, and the unusual abundance of carbonate close to advanced argillic alteration indicate fluid mixing and suggest that acidic, magmatic fluids were likely neutralized by seawater. This occurrence strengthens the case for prospecting the Mount Read Volcanics and other similar submarine volcanic belts for copper-gold and gold-only deposits that formed by the actions of hyperacid oxidized fluids." name="eprints.abstract" /> <meta content="2004-08" name="eprints.date" /> <meta content="published" name="eprints.date_type" /> <meta content="Economic Geology" name="eprints.publication" /> <meta content="99" name="eprints.volume" /> <meta content="5" name="eprints.number" /> <meta content="987-1002" name="eprints.pagerange" /> <meta content="10.2113/99.5.987" name="eprints.id_number" /> <meta content="TRUE" name="eprints.refereed" /> <meta content="0361-0128" name="eprints.issn" /> <meta content="http://dx.doi.org/10.2113/99.5.987" name="eprints.official_url" /> <meta content="Arribas, A., Jr., Cunningham, C.G., Rytuba, J.J., Rye, R.O., Kelly, W.C., Podwysocki, M.H., McKee, E.H., and Tosdal, R.M., 1995, Geology, geochronology, fluid inclusions, and isotope geochemistry of the Rodalquilar gold alunite deposit, Spain: ECONOMIC GEOLOGY, v. 90, p. 795–822. 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Gemmell, J.B., and Fulton, R., 2001, Geology, genesis, and exploration implications of the footwall and hanging-wall alteration associated with the Hellyer volcanic-hosted massive sulfide deposit, Tasmania, Australia: ECONOMIC GEOLOGY, v. 96, p. 1003–1036. Gemmell, J.B., and Large, R.R., 1992, Stringer system and alteration zones underlying the Hellyer volcanic-hosted massive sulfide deposit, Tasmania, Australia: ECONOMIC GEOLOGY, v. 92, p. 597–619. Gemmell, J.B., Binns, R.A., and Parr, J.M., 1999, Submarine, high sulfidation alteration within DESMOS caldera, Manus Basin, PNG: Biennial SGA Meeting, 5th, and Quadrennial IAGOD Symposium, 10th, London, August 1999, Proceedings, v. 1, p. 503–506. Gray, J.E., and Coolbaugh, M.F., 1994, Geology and geochemistry of Summitville, Colorado: An epithermal acid sulfate deposit in a volcanic dome: ECONOMIC GEOLOGY, v. 89, p. 1906–1923. 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Huston, D.L., and Kamprad, J., 2001, Zonation of alteration facies at Western Tharsis: Implications for the genesis of copper-gold deposits in the Mount Lyell field, western Tasmania: ECONOMIC GEOLOGY, v. 96, p. 1123–1132. Huston, D.L., Power, M., Gemmell, J.B., and Large, R.R., 1995, Design, calibration and geological application of the first operational Australian laser ablation sulfur isotope microprobe: Australian Journal of Earth Sciences, v. 45, p. 549–555. Ishikawa, Y., Sawaguchi, T., Iwaya, S., and Horiuchi, M., 1976, Delineation of prospecting targets for Kuroko deposits based on modes of volcanism of underlying dacite and alteration halos: Mining Geology, v. 26, p. 105–117 (in Japanese with English abs.). 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Large, R.R., Gemmell, J.B., Paulick, H., and Huston, D., 2001a, The alteration box plot: A simple approach to understanding the relationship between alteration mineralogy and lithogeochemistry associated with volcanic- hosted massive sulfide deposits: ECONOMIC GEOLOGY, v. 96, p. 957–972. Large, R.R., McPhie, J., Gemmell, J.B., Herrmann, W., and Davidson, G., 2001b, The spectrum of ore deposit types, volcanic environments, alteration halos and related exploration vectors in submarine volcanic successions: Some examples from Australia: ECONOMIC GEOLOGY, v. 96, p. 913–938. Meares, R.M.D., Hutton, M.J., and Komyshan, P., 1981, The Mount Lyell Mining and Railway Company Limited Exploration License 9/66, Tasmania, Annual Report: Mineral Resources Tasmania Open File Report, 40 p. Miller, C., Halley, S., Green, G., and Jones, M., 2001, Discovery of the West 45 volcanic-hosted massive sulfide deposit using oxygen isotopes and REE geochemistry: ECONOMIC GEOLOGY, v. 96, p. 1227–1238. 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Read Volcanics, western Tasmania: Australian Journal of Earth Sciences, v. 43, p. 147–159. White, N.C., and Hedenquist, J.W., 1990, Epithermal environments and styles of mineralization: Variation and their causes, and guidelines for exploration: Journal of Geochemical Exploration, v. 36, p. 445–474. Whitford, D.J., Crawford, A.J., Korsch, M.J., and Craven, S.J., 1990, Strontium and neodymium isotopic studies of the Mount Read Volcanics, Tasmania [abs.]: Geological Society of Australia Abstracts, v. 25, p. 215–216. Whitford, D.J., Korsch, M.J., and Solomon, M., 1992, Strontium isotope studies of barites: Implications for the origin of base metal mineralization in Tasmania: ECONOMIC GEOLOGY, v. 87, p. 953–959. Zheng, Y.-F., 1993, Calculation of oxygen-isotope fractionation in hydroxylbearing silicates: Earth and Planetary Science Letters, v. 120, p. 247–263. Zheng, Y.-F., and Hoefs, J., 1993, Carbon and oxygen isotopic covariations in hydrothermal calcites: Mineralium Deposita, v. 28, p. 79–89." name="eprints.referencetext" /> <meta content="Williams, N.C. and Davidson, G.J. (2004) Possible submarine advanced argillic alteration at the Basin Lake prospect, Western Tasmania, Australia. Economic Geology, 99 (5). pp. 987-1002. ISSN 0361-0128" name="eprints.citation" /> <meta content="http://eprints.utas.edu.au/2056/1/Williams.Davidson.ECONGEOL.2004.pdf" name="eprints.document_url" /> <link rel="schema.DC" href="http://purl.org/DC/elements/1.0/" /> <meta content="Possible submarine advanced argillic alteration at the Basin Lake prospect, Western Tasmania, Australia" name="DC.title" /> <meta content="Williams, N.C." name="DC.creator" /> <meta content="Davidson, G.J." name="DC.creator" /> <meta content="260100 Geology" name="DC.subject" /> <meta content="The Basin Lake copper-gold prospect lies in western Tasmania’s Mount Read Volcanics and is hosted in a series of calc-alkaline andesites, quartz-feldspar porphyries, mudstones, carbonates, and sandstones between the Tyndall Group and the Central Volcanic Complex. Alteration at the Basin Lake prospect occurs over a strike length of 1.4 km and includes thin, strata-bound pyrophyllite-quartz-paragonite-kaolinite-pyrite-alunite alteration zones, up to 12 m wide and containing up to 50 wt percent pyrophyllite, with local fluorite veining. These zones grade out to paragonite-muscovite-kaolinite-quartz-pyrite and muscovite-carbonate-chlorite alteration zones. Extensive propylitic alteration (chlorite-carbonate-epidote) affects most other rocks outside these zones. Mineralization consists of thin strata-bound zones of massive and vein pyrite, tennantite, and chalcopyrite, with trace covellite and galena, hosted mainly within an intensely silicified core of the pyrophyllite-quartzsericite alteration zone. Pyrite has δ34S values of –1.4 to +6.9 per mil, although marginal vein pyrite in the propylitic zone has δ34S values around 12.4 per mil. Large silicified glacial erratic boulders at surface contain massive and vein pyrite, enargite, and tennantite, with minor barite, and trace covellite, stannoidite, and mawsonite. Pyrite and enargite have δ34S values of 1.7 to 6.8 per mil; barite has δ34S values around 35.2 per mil with 87Sr/86Sr around 0.7108. The alteration and mineralization at the Basin Lake prospect is similar to that associated with high-sulfidation copper-gold systems formed by acidic, relatively oxidized fluids. A new geochemical vector, here termed the “advanced argillic alteration index” [AAAI = 100 (SiO2)/(SiO2 + 10MgO + 10CaO + 10Na2O)], has been devised to help quantify the intensity of alteration. The values of the AAAI at Basin Lake are similar to those of several high-sulfidation epithermal deposits. The low sulfide δ34S values are similar to those at other sulfide occurrences in the Mount Read Volcanics that have previously been considered to be barren, are lower than those of nearby volcanic-hosted massive sulfide deposits, and may indicate a magmatic fluid component. However, the δ34S and 87Sr/86Sr values of Basin Lake barite at the assumed highest exposed level of the system and higher δ34S values in pyrite from marginal veins are similar to those of Cambrian volcanic-hosted massive sulfide systems, indicating the involvement of reduced seawater sulfate at these locations. Calcite carbon and oxygen isotope values, silicate oxygen isotope values, and the unusual abundance of carbonate close to advanced argillic alteration indicate fluid mixing and suggest that acidic, magmatic fluids were likely neutralized by seawater. This occurrence strengthens the case for prospecting the Mount Read Volcanics and other similar submarine volcanic belts for copper-gold and gold-only deposits that formed by the actions of hyperacid oxidized fluids." name="DC.description" /> <meta content="2004-08" name="DC.date" /> <meta content="Article" name="DC.type" /> <meta content="PeerReviewed" name="DC.type" /> <meta content="application/pdf" name="DC.format" /> <meta content="http://eprints.utas.edu.au/2056/1/Williams.Davidson.ECONGEOL.2004.pdf" name="DC.identifier" /> <meta content="http://dx.doi.org/10.2113/99.5.987" name="DC.relation" /> <meta content="Williams, N.C. and Davidson, G.J. (2004) Possible submarine advanced argillic alteration at the Basin Lake prospect, Western Tasmania, Australia. Economic Geology, 99 (5). pp. 987-1002. 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border: solid 1px #ccc; padding: 3px"><tr> <td align="left"><a href="http://eprints.utas.edu.au/cgi/users/home">Login</a> | <a href="http://eprints.utas.edu.au/cgi/register">Create Account</a></td> <td align="right" style="white-space: nowrap"> <form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/search" style="display:inline"> <input class="ep_tm_searchbarbox" size="20" type="text" name="q" /> <input class="ep_tm_searchbarbutton" value="Search" type="submit" name="_action_search" /> <input type="hidden" name="_order" value="bytitle" /> <input type="hidden" name="basic_srchtype" value="ALL" /> <input type="hidden" name="_satisfyall" value="ALL" /> </form> </td> </tr></table></td></tr> <tr> <td class="toplinks"><!-- InstanceBeginEditable name="content" --> <div align="center"> <table width="720" class="ep_tm_main"><tr><td align="left"> <h1 class="ep_tm_pagetitle">Possible submarine advanced argillic alteration at the Basin Lake prospect, Western Tasmania, Australia</h1> <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Williams, N.C.</span> and <span class="person_name">Davidson, G.J.</span> (2004) <xhtml:em>Possible submarine advanced argillic alteration at the Basin Lake prospect, Western Tasmania, Australia.</xhtml:em> Economic Geology, 99 (5). pp. 987-1002. ISSN 0361-0128</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2056/1/Williams.Davidson.ECONGEOL.2004.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2056/1/Williams.Davidson.ECONGEOL.2004.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />583Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input accept-charset="utf-8" value="2595" name="docid" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.2113/99.5.987">http://dx.doi.org/10.2113/99.5.987</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">The Basin Lake copper-gold prospect lies in western Tasmania’s Mount Read Volcanics and is hosted in a series of calc-alkaline andesites, quartz-feldspar porphyries, mudstones, carbonates, and sandstones between the Tyndall Group and the Central Volcanic Complex. Alteration at the Basin Lake prospect occurs over a strike length of 1.4 km and includes thin, strata-bound pyrophyllite-quartz-paragonite-kaolinite-pyrite-alunite alteration zones, up to 12 m wide and containing up to 50 wt percent pyrophyllite, with local fluorite veining. These zones grade out to paragonite-muscovite-kaolinite-quartz-pyrite and muscovite-carbonate-chlorite alteration zones. Extensive propylitic alteration (chlorite-carbonate-epidote) affects most other rocks outside these zones. Mineralization consists of thin strata-bound zones of massive and vein pyrite, tennantite, and chalcopyrite, with trace covellite and galena, hosted mainly within an intensely silicified core of the pyrophyllite-quartzsericite alteration zone. Pyrite has δ34S values of –1.4 to +6.9 per mil, although marginal vein pyrite in the propylitic zone has δ34S values around 12.4 per mil. Large silicified glacial erratic boulders at surface contain massive and vein pyrite, enargite, and tennantite, with minor barite, and trace covellite, stannoidite, and mawsonite. Pyrite and enargite have δ34S values of 1.7 to 6.8 per mil; barite has δ34S values around 35.2 per mil with 87Sr/86Sr around 0.7108. The alteration and mineralization at the Basin Lake prospect is similar to that associated with high-sulfidation copper-gold systems formed by acidic, relatively oxidized fluids. A new geochemical vector, here termed the “advanced argillic alteration index” [AAAI = 100 (SiO2)/(SiO2 + 10MgO + 10CaO + 10Na2O)], has been devised to help quantify the intensity of alteration. The values of the AAAI at Basin Lake are similar to those of several high-sulfidation epithermal deposits. The low sulfide δ34S values are similar to those at other sulfide occurrences in the Mount Read Volcanics that have previously been considered to be barren, are lower than those of nearby volcanic-hosted massive sulfide deposits, and may indicate a magmatic fluid component. However, the δ34S and 87Sr/86Sr values of Basin Lake barite at the assumed highest exposed level of the system and higher δ34S values in pyrite from marginal veins are similar to those of Cambrian volcanic-hosted massive sulfide systems, indicating the involvement of reduced seawater sulfate at these locations. Calcite carbon and oxygen isotope values, silicate oxygen isotope values, and the unusual abundance of carbonate close to advanced argillic alteration indicate fluid mixing and suggest that acidic, magmatic fluids were likely neutralized by seawater. This occurrence strengthens the case for prospecting the Mount Read Volcanics and other similar submarine volcanic belts for copper-gold and gold-only deposits that formed by the actions of hyperacid oxidized fluids.</p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Keywords:</th><td valign="top" class="ep_row">stable isotopes, acid alteration,volcanic massive sulfides, Mt Read Volcanic Belt, Cambrian, enargite, silica replacement, copper, gold, barite</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/260100.html">260000 Earth Sciences > 260100 Geology</a></td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2056</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Mrs Katrina Keep</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">10 Oct 2007 04:01</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">09 Jan 2008 02:30</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2056;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=2056">item control page</a></p> </td></tr></table> </div> <!-- InstanceEndEditable --></td> </tr> <tr> <td><!-- #BeginLibraryItem "/Library/footer_eprints.lbi" --> <table width="795" border="0" align="left" cellpadding="0" class="footer"> <tr valign="top"> <td colspan="2"><div align="center"><a href="http://www.utas.edu.au">UTAS home</a> | <a href="http://www.utas.edu.au/library/">Library home</a> | <a href="/">ePrints home</a> | <a href="/contact.html">contact</a> | <a href="/information.html">about</a> | <a href="/view/">browse</a> | <a href="/perl/search/simple">search</a> | <a href="/perl/register">register</a> | <a href="/perl/users/home">user area</a> | <a href="/help/">help</a></div><br /></td> </tr> <tr><td colspan="2"><p><img src="/images/eprints/footerline.gif" width="100%" height="4" /></p></td></tr> <tr valign="top"> <td width="68%" class="footer">Authorised by the University Librarian<br /> © University of Tasmania ABN 30 764 374 782<br /> <a href="http://www.utas.edu.au/cricos/">CRICOS Provider Code 00586B</a> | <a href="http://www.utas.edu.au/copyright/copyright_disclaimers.html">Copyright & Disclaimers</a> | <a href="http://www.utas.edu.au/accessibility/index.html">Accessibility</a> | <a href="http://eprints.utas.edu.au/feedback/">Site Feedback</a> </td> <td width="32%"><div align="right"> <p align="right" class="NoPrint"><a href="http://www.utas.edu.au/"><img src="http://www.utas.edu.au/shared/logos/unioftasstrip.gif" alt="University of Tasmania Home Page" width="260" height="16" border="0" align="right" /></a></p> <p align="right" class="NoPrint"><a href="http://www.utas.edu.au/"><br /> </a></p> </div></td> </tr> <tr valign="top"> <td><p> </p></td> <td><div align="right"><span class="NoPrint"><a href="http://www.eprints.org/software/"><img src="/images/eprintslogo.gif" alt="ePrints logo" width="77" height="29" border="0" align="bottom" /></a></span></div></td> </tr> </table> <!-- #EndLibraryItem --> <div align="center"></div></td> </tr> </table> </body> </html>