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<meta content="Jones, R.C." name="eprints.creators_name" />
<meta content="Skelton, B.W." name="eprints.creators_name" />
<meta content="Tolhurst, V-A." name="eprints.creators_name" />
<meta content="White, A.H." name="eprints.creators_name" />
<meta content="Wilson, A.J." name="eprints.creators_name" />
<meta content="Canty, A.J." name="eprints.creators_name" />
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<meta content="2007-12-11 04:20:10" name="eprints.datestamp" />
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<meta content="Synthesis and solid-state structural characterisation of
Pt(II,IV) bromide complexes containing bidentate
organothiomethylpyridine heteroleptic ligands" name="eprints.title" />
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<meta content="250201" name="eprints.subjects" />
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<meta content="Platinum; Mixed donor ligands; Pyridine; Thioether; X-ray crystal structures" name="eprints.keywords" />
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<meta content="A convenient synthetic method for the preparation of organothiomethylpyridine ligands 2-(RSCH2)C5H4N (R = Ph (L1), Me (L2)), 2-MeS–6-Me-C5H3N (L3), and 2-MeS–4-Me-C5H3N (L4) via the initial lithiation of substituted 2-picolines followed by the nucleophilic reaction with a diorganyldisulfide is described. The complexes [PtBr2L] (L = L1–L4) have been prepared in good to high yields as yellow solids with low solubility in organic solvents. The solid state structures of the complexes have been determined, showing the spatial arrangement of the complexes to depend significantly upon varying substituents within the ligand. The complexes undergo oxidation by bromine to form the tetravalent complexes [PtBr4(L)] (L = L1–L4). The solid state structures of [PtBr4(L2)] and [PtBr4(L4)] have been determined, and shown to be monomeric with the ligand chelating the platinum centre." name="eprints.abstract" />
<meta content="2007" name="eprints.date" />
<meta content="published" name="eprints.date_type" />
<meta content="Polyhedron" name="eprints.publication" />
<meta content="26" name="eprints.volume" />
<meta content="3" name="eprints.number" />
<meta content="708-718" name="eprints.pagerange" />
<meta content="10.1016/j.poly.2006.09.001" name="eprints.id_number" />
<meta content="TRUE" name="eprints.refereed" />
<meta content="0277-5387" name="eprints.issn" />
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<meta content="Jones, R.C. and Skelton, B.W. and Tolhurst, V-A. and White, A.H. and Wilson, A.J. and Canty, A.J. (2007) Synthesis and solid-state structural characterisation of Pt(II,IV) bromide complexes containing bidentate organothiomethylpyridine heteroleptic ligands. Polyhedron, 26 (3). pp. 708-718. ISSN 0277-5387" name="eprints.citation" />
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<meta content="A convenient synthetic method for the preparation of organothiomethylpyridine ligands 2-(RSCH2)C5H4N (R = Ph (L1), Me (L2)), 2-MeS–6-Me-C5H3N (L3), and 2-MeS–4-Me-C5H3N (L4) via the initial lithiation of substituted 2-picolines followed by the nucleophilic reaction with a diorganyldisulfide is described. The complexes [PtBr2L] (L = L1–L4) have been prepared in good to high yields as yellow solids with low solubility in organic solvents. The solid state structures of the complexes have been determined, showing the spatial arrangement of the complexes to depend significantly upon varying substituents within the ligand. The complexes undergo oxidation by bromine to form the tetravalent complexes [PtBr4(L)] (L = L1–L4). The solid state structures of [PtBr4(L2)] and [PtBr4(L4)] have been determined, and shown to be monomeric with the ligand chelating the platinum centre." name="DC.description" />
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<h1 class="ep_tm_pagetitle">Synthesis and solid-state structural characterisation of Pt(II,IV) bromide complexes containing bidentate organothiomethylpyridine heteroleptic ligands</h1>
<p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Jones, R.C.</span> and <span class="person_name">Skelton, B.W.</span> and <span class="person_name">Tolhurst, V-A.</span> and <span class="person_name">White, A.H.</span> and <span class="person_name">Wilson, A.J.</span> and <span class="person_name">Canty, A.J.</span> (2007) <xhtml:em>Synthesis and solid-state structural characterisation of Pt(II,IV) bromide complexes containing bidentate organothiomethylpyridine heteroleptic ligands.</xhtml:em> Polyhedron, 26 (3). pp. 708-718. ISSN 0277-5387</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2652/1/Polyhedron_RCJ_2007.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" border="0" class="ep_doc_icon" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2652/1/Polyhedron_RCJ_2007.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />1024Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input value="3481" name="docid" accept-charset="utf-8" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1016/j.poly.2006.09.001">http://dx.doi.org/10.1016/j.poly.2006.09.001</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">A convenient synthetic method for the preparation of organothiomethylpyridine ligands 2-(RSCH2)C5H4N (R = Ph (L1), Me (L2)), 2-MeS–6-Me-C5H3N (L3), and 2-MeS–4-Me-C5H3N (L4) via the initial lithiation of substituted 2-picolines followed by the nucleophilic reaction with a diorganyldisulfide is described. The complexes [PtBr2L] (L = L1–L4) have been prepared in good to high yields as yellow solids with low solubility in organic solvents. The solid state structures of the complexes have been determined, showing the spatial arrangement of the complexes to depend significantly upon varying substituents within the ligand. The complexes undergo oxidation by bromine to form the tetravalent complexes [PtBr4(L)] (L = L1–L4). The solid state structures of [PtBr4(L2)] and [PtBr4(L4)] have been determined, and shown to be monomeric with the ligand chelating the platinum centre.</p></div><table style="margin-bottom: 1em" border="0" cellpadding="3" class="not_ep_block"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Additional Information:</th><td valign="top" class="ep_row">The definitive version is available at http://www.sciencedirect.com
</td></tr><tr><th valign="top" class="ep_row">Keywords:</th><td valign="top" class="ep_row">Platinum; Mixed donor ligands; Pyridine; Thioether; X-ray crystal structures</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/250201.html">250000 Chemical Sciences > 250200 Inorganic Chemistry > 250201 Transition Metal Chemistry</a></td></tr><tr><th valign="top" class="ep_row">Collections:</th><td valign="top" class="ep_row">UNSPECIFIED</td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2652</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">11 Dec 2007 15:20</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">17 Jan 2008 11:34</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2652;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=2652">item control page</a></p>
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