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<title>UTas ePrints - Entry to alkynylplatinum(IV) chemistry using hypervalent iodine(III) reagents, and the synthesis of triphenyl{4,4'-bis(tert-butyl)-2,2-bipyridine}iodoplatinum(IV)</title>
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<meta content="Çanty, A.J." name="eprints.creators_name" />
<meta content="Rodemann, T." name="eprints.creators_name" />
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<meta content="The reaction of phenyl(alkynyl)iodine(III) triflates with diorganoplatinum(II) complexes provides a general route for the synthesis of a new class of alkynylplatinum(IV) complexes containing PtIVR2(CBCR2) groups, e.g., the 4,4'-bis(tert-butyl)-2,2'-bipyridine complexes PtIR2(CCSiMe3)(But2bpy) (R = Me, Ph); IPh2(OTf) reacts with PtPh2(But2bpy) to form the first archetypal triarylplatinum(IV) complex PtIPh3(But2bpy)." name="eprints.abstract" />
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Puddephatt, Organometallics 21 (2002) 1257.
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Chem. 543 (1997) 233.
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Inorg. Chem. Commun. 3 (2000) 575.
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[15] M. Font-Bardıa, C. Gallego, M. Martinez, X. Solans, Organometallics
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<h1 class="ep_tm_pagetitle">Entry to alkynylplatinum(IV) chemistry using hypervalent iodine(III) reagents, and the synthesis of triphenyl{4,4'-bis(tert-butyl)-2,2-bipyridine}iodoplatinum(IV)</h1>
<p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Çanty, A.J.</span> and <span class="person_name">Rodemann, T.</span> (2003) <xhtml:em>Entry to alkynylplatinum(IV) chemistry using hypervalent iodine(III) reagents, and the synthesis of triphenyl{4,4'-bis(tert-butyl)-2,2-bipyridine}iodoplatinum(IV).</xhtml:em> Inorganic Chemistry Communications, 6 (11). pp. 1382-1384. ISSN 1387-7003</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2805/1/ICC20032C_1382.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2805/1/ICC20032C_1382.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />198Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input accept-charset="utf-8" value="3827" name="docid" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1016/j.inoche.2003.08.023">http://dx.doi.org/10.1016/j.inoche.2003.08.023</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">The reaction of phenyl(alkynyl)iodine(III) triflates with diorganoplatinum(II) complexes provides a general route for the synthesis of a new class of alkynylplatinum(IV) complexes containing PtIVR2(CBCR2) groups, e.g., the 4,4'-bis(tert-butyl)-2,2'-bipyridine complexes PtIR2(CCSiMe3)(But2bpy) (R = Me, Ph); IPh2(OTf) reacts with PtPh2(But2bpy) to form the first archetypal triarylplatinum(IV) complex PtIPh3(But2bpy).</p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Additional Information:</th><td valign="top" class="ep_row">The definitive version is available at http://www.sciencedirect.com
</td></tr><tr><th valign="top" class="ep_row">Keywords:</th><td valign="top" class="ep_row">Organoplatinum(IV); Triphenylplatinum(IV); 2,20-Bipyridine; Alkynyls; Iodonium; Iodine(III)</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/259901.html">250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2805</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">04 Jan 2008 10:55</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">09 Jan 2008 02:30</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2805;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=2805">item control page</a></p>
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