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  5. <title>UTas ePrints - Possible submarine advanced argillic alteration at the Basin Lake prospect, Western Tasmania, Australia</title>
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  13. <meta content="Williams, N.C." name="eprints.creators_name" />
  14. <meta content="Davidson, G.J." name="eprints.creators_name" />
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  21. <meta content="Possible submarine advanced argillic alteration at the Basin Lake prospect, Western Tasmania, Australia" name="eprints.title" />
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  23. <meta content="260100" name="eprints.subjects" />
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  25. <meta content="stable isotopes, acid alteration,volcanic massive sulfides,
  26. Mt Read Volcanic Belt, Cambrian, enargite, silica replacement, copper, gold, barite" name="eprints.keywords" />
  27. <meta content="The Basin Lake copper-gold prospect lies in western Tasmania’s Mount Read Volcanics and is hosted in a series
  28. of calc-alkaline andesites, quartz-feldspar porphyries, mudstones, carbonates, and sandstones between the
  29. Tyndall Group and the Central Volcanic Complex. Alteration at the Basin Lake prospect occurs over a strike
  30. length of 1.4 km and includes thin, strata-bound pyrophyllite-quartz-paragonite-kaolinite-pyrite-alunite alteration
  31. zones, up to 12 m wide and containing up to 50 wt percent pyrophyllite, with local fluorite veining. These
  32. zones grade out to paragonite-muscovite-kaolinite-quartz-pyrite and muscovite-carbonate-chlorite alteration
  33. zones. Extensive propylitic alteration (chlorite-carbonate-epidote) affects most other rocks outside these zones.
  34. Mineralization consists of thin strata-bound zones of massive and vein pyrite, tennantite, and chalcopyrite,
  35. with trace covellite and galena, hosted mainly within an intensely silicified core of the pyrophyllite-quartzsericite
  36. alteration zone. Pyrite has δ34S values of –1.4 to +6.9 per mil, although marginal vein pyrite in the
  37. propylitic zone has δ34S values around 12.4 per mil. Large silicified glacial erratic boulders at surface contain
  38. massive and vein pyrite, enargite, and tennantite, with minor barite, and trace covellite, stannoidite, and mawsonite.
  39. Pyrite and enargite have δ34S values of 1.7 to 6.8 per mil; barite has δ34S values around 35.2 per mil with
  40. 87Sr/86Sr around 0.7108.
  41. The alteration and mineralization at the Basin Lake prospect is similar to that associated with high-sulfidation
  42. copper-gold systems formed by acidic, relatively oxidized fluids. A new geochemical vector, here termed the
  43. “advanced argillic alteration index” [AAAI = 100 (SiO2)/(SiO2 + 10MgO + 10CaO + 10Na2O)], has been devised
  44. to help quantify the intensity of alteration. The values of the AAAI at Basin Lake are similar to those of
  45. several high-sulfidation epithermal deposits. The low sulfide δ34S values are similar to those at other sulfide occurrences
  46. in the Mount Read Volcanics that have previously been considered to be barren, are lower than those
  47. of nearby volcanic-hosted massive sulfide deposits, and may indicate a magmatic fluid component. However,
  48. the δ34S and 87Sr/86Sr values of Basin Lake barite at the assumed highest exposed level of the system and higher
  49. δ34S values in pyrite from marginal veins are similar to those of Cambrian volcanic-hosted massive sulfide systems,
  50. indicating the involvement of reduced seawater sulfate at these locations. Calcite carbon and oxygen isotope
  51. values, silicate oxygen isotope values, and the unusual abundance of carbonate close to advanced argillic
  52. alteration indicate fluid mixing and suggest that acidic, magmatic fluids were likely neutralized by seawater.
  53. This occurrence strengthens the case for prospecting the Mount Read Volcanics and other similar submarine
  54. volcanic belts for copper-gold and gold-only deposits that formed by the actions of hyperacid oxidized fluids." name="eprints.abstract" />
  55. <meta content="2004-08" name="eprints.date" />
  56. <meta content="published" name="eprints.date_type" />
  57. <meta content="Economic Geology" name="eprints.publication" />
  58. <meta content="99" name="eprints.volume" />
  59. <meta content="5" name="eprints.number" />
  60. <meta content="987-1002" name="eprints.pagerange" />
  61. <meta content="10.2113/99.5.987" name="eprints.id_number" />
  62. <meta content="TRUE" name="eprints.refereed" />
  63. <meta content="0361-0128" name="eprints.issn" />
  64. <meta content="http://dx.doi.org/10.2113/99.5.987" name="eprints.official_url" />
  65. <meta content="Arribas, A., Jr., Cunningham, C.G., Rytuba, J.J., Rye, R.O., Kelly, W.C., Podwysocki,
  66. M.H., McKee, E.H., and Tosdal, R.M., 1995, Geology,
  67. geochronology, fluid inclusions, and isotope geochemistry of the Rodalquilar
  68. gold alunite deposit, Spain: ECONOMIC GEOLOGY, v. 90, p.
  69. 795–822.
  70. Berger, G., and Velde, B., 1992, Chemical parameters controlling the propylitic
  71. and argillic alteration process: European Journal of Mineralogy, v. 4, p.
  72. 1439–1454.
  73. Boda, S.P., 1991, The geology, structural setting and genesis of the Chester
  74. mine, northwest Tasmania: Unpublished honors thesis, Canberra, ACT,
  75. Australian National University, 111 p.
  76. Bowden, A.R., 1974, The glacial geomorphology of the Tyndall Mountains,
  77. western Tasmania: Unpublished honors thesis, Hobart, Tasmania, University
  78. of Tasmania, 80 p.
  79. Burke, W.H., Denison, R.E., Hetherington, E.A., Koepnik, R.B., Nelson,
  80. H.F., and Otto, J.B., 1982, Variation of seawater 87Sr/86Sr throughout
  81. Phanerozoic time: Geology, v. 10, p. 516–519.
  82. Callaghan, T., 1998, Geology and alteration of the Mt. Julia deposit, Henty
  83. gold mine, Tasmania: Unpublished master’s thesis, Hobart, Tasmania, University
  84. of Tasmania, 69 p.
  85. ——2001, Geology and host-rock alteration of the Henty and Mount Julia
  86. gold deposits, western Tasmania: ECONOMIC GEOLOGY, v. 96, p. 1073–
  87. 1088.
  88. Claypool, G.E., Holser, W.T., Kaplan, I.R., Sakai, H., and Zak, I., 1980, The
  89. age curves of sulfur and oxygen in marine sulfate and their initial interpretation:
  90. Chemical Geology, v. 28, p. 199–206.
  91. Clayton, R.N., and Mayeda, T.K., 1963, The use of bromine penta-fluoride in
  92. the extraction of oxygen from oxides and silicates for isotopic analysis:
  93. Geochimica et Cosmochimica Acta, v. 27, p. 43–52.
  94. Clayton, R.N., O’Neil, J.R., and Mayeda, T., 1972, Oxygen isotope exchange
  95. between quartz and water: Journal of Geophysical Research, v. 77, p.
  96. 3057–3067.
  97. Corbett, K.D., 1992, Stratigraphic-volcanic setting of massive sulfide deposits
  98. in the Cambrian Mount Read Volcanics, Tasmania: ECONOMIC GEOLOGY,
  99. v. 87, p. 564–586.
  100. ——2001, New mapping and interpretations of the Mount Lyell mining district,
  101. Tasmania: A large hybrid Cu-Au system with an exhalative Pb-Zn top:
  102. ECONOMIC GEOLOGY, v. 96, p. 1089–1122.
  103. Crawford, A.J., Corbett, K.D., and Everard, J.L., 1992, Geochemistry of the
  104. Cambrian volcanic-hosted massive sulfide-rich Mount Read Volcanics, Tasmania,
  105. and some tectonic implications: ECONOMIC GEOLOGY, v. 87, p.
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  107. Fritz, P., Drimmie, R.J., and Nowicki, V.K., 1974, Preparation of sulfur dioxide
  108. for mass spectrometer analyses by combustion of sulfides with copper
  109. oxide: Analytical Chemistry, v. 46, p. 164–166.
  110. Gemmell, J.B., and Fulton, R., 2001, Geology, genesis, and exploration implications
  111. of the footwall and hanging-wall alteration associated with the
  112. Hellyer volcanic-hosted massive sulfide deposit, Tasmania, Australia: ECONOMIC
  113. GEOLOGY, v. 96, p. 1003–1036.
  114. Gemmell, J.B., and Large, R.R., 1992, Stringer system and alteration zones
  115. underlying the Hellyer volcanic-hosted massive sulfide deposit, Tasmania,
  116. Australia: ECONOMIC GEOLOGY, v. 92, p. 597–619.
  117. Gemmell, J.B., Binns, R.A., and Parr, J.M., 1999, Submarine, high sulfidation
  118. alteration within DESMOS caldera, Manus Basin, PNG: Biennial SGA
  119. Meeting, 5th, and Quadrennial IAGOD Symposium, 10th, London, August
  120. 1999, Proceedings, v. 1, p. 503–506.
  121. Gray, J.E., and Coolbaugh, M.F., 1994, Geology and geochemistry of Summitville,
  122. Colorado: An epithermal acid sulfate deposit in a volcanic dome:
  123. ECONOMIC GEOLOGY, v. 89, p. 1906–1923.
  124. Green, G.R., and Taheri, J., 1992, Stable isotopes and geochemistry as exploration
  125. indicators: Bulletin of the Geological Survey of Tasmania, no. 70,
  126. p. 84–91.
  127. Green, G.R., Solomon, M., and Walshe, J.L., 1981, The formation of the volcanic-
  128. hosted massive sulfide ore deposit at Rosebery, Tasmania: ECONOMIC
  129. GEOLOGY, v. 76, p. 304–338.
  130. Halley, S.W., and Roberts, R.H., 1997, Henty: A shallow-water gold-rich volcanogenic
  131. massive sulfide deposit in western Tasmania: ECONOMIC GEOLOGY,
  132. v. 92, p. 438–447.
  133. Hannington, M.D., Poulsen, K.H., Thompson, J.F.H., and Sillitoe, R.H.,
  134. 1999, Volcanogenic gold in the massive sulfide environment: Reviews in
  135. Economic Geology, v. 8, p. 325–356.
  136. Hayba, D.O., Bethke, P.M., Heald, P., and Foley, N.K., 1985, Geologic, mineralogic,
  137. and geochemical characteristics of volcanic-hosted epithermal
  138. precious-metal deposits: Reviews in Economic Geology, v. 2, p. 129–167.
  139. Hedenquist, J.W., and Lowenstern, J.B., 1994, The role of magmas in the formation
  140. of hydrothermal ore deposits: Nature, v. 370, p. 519–526.
  141. Hedenquist, J.W., Matsuhisa, Y., Izawa, E., White, N.C., Giggenbach, W.F.,
  142. and Aoki, M., 1994, Geology, geochemistry, and origin of high sulfidation
  143. copper-gold mineralization in the Nansatsu district, Japan: ECONOMIC GEOLOGY,
  144. v. 89, p. 1–30.
  145. Hemley, J.J., Montoya, J.W., Marinenko, J.W., and Luce, R.W., 1980, Equilibria
  146. in the system Al2O3-SiO2-H2O and some general implications for alteration/
  147. mineralization processes: ECONOMIC GEOLOGY, v. 75, p. 220–228.
  148. Huston, D.L., 1999, Stable isotopes and their significance for understanding
  149. the genesis of volcanic-hosted massive sulfide deposits: A review: Reviews
  150. in Economic Geology, v. 8, p. 157–180.
  151. Huston, D.L., and Kamprad, J., 2001, Zonation of alteration facies at Western
  152. Tharsis: Implications for the genesis of copper-gold deposits in the
  153. Mount Lyell field, western Tasmania: ECONOMIC GEOLOGY, v. 96, p.
  154. 1123–1132.
  155. Huston, D.L., Power, M., Gemmell, J.B., and Large, R.R., 1995, Design, calibration
  156. and geological application of the first operational Australian laser
  157. ablation sulfur isotope microprobe: Australian Journal of Earth Sciences, v.
  158. 45, p. 549–555.
  159. Ishikawa, Y., Sawaguchi, T., Iwaya, S., and Horiuchi, M., 1976, Delineation
  160. of prospecting targets for Kuroko deposits based on modes of volcanism of
  161. underlying dacite and alteration halos: Mining Geology, v. 26, p. 105–117
  162. (in Japanese with English abs.).
  163. Khin Zaw, 1991, The effect of Devonian metamorphism and metasomatism
  164. on the mineralogy and geochemistry of the Cambrian volcanogenic massive
  165. sulfide deposits in the Rosebery-Hercules district, western Tasmania: Unpublished
  166. Ph.D. thesis, Hobart, Tasmania, University of Tasmania, 302 p.
  167. Knight, J.E., 1977, A thermochemical study of alunite, enargite, luzonite, and
  168. tennantite deposits: ECONOMIC GEOLOGY, v. 72, p. 1321–1336.
  169. Large, R.R., 1992, Australian volcanic-hosted massive sulfide deposits: Features,
  170. styles, and genetic models: ECONOMIC GEOLOGY, v. 87, p. 471–510.
  171. Large, R.R., McGoldrick, P.J., Berry, R.F., and Young, C.H., 1988, A tightly
  172. folded, gold-rich, massive sulfide deposit: Que River mine, Tasmania:
  173. ECONOMIC GEOLOGY, v. 83, p. 267–290.
  174. Large, R.R., Gemmell, J.B., Paulick, H., and Huston, D., 2001a, The alteration
  175. box plot: A simple approach to understanding the relationship between
  176. alteration mineralogy and lithogeochemistry associated with volcanic-
  177. hosted massive sulfide deposits: ECONOMIC GEOLOGY, v. 96, p.
  178. 957–972.
  179. Large, R.R., McPhie, J., Gemmell, J.B., Herrmann, W., and Davidson, G.,
  180. 2001b, The spectrum of ore deposit types, volcanic environments, alteration
  181. halos and related exploration vectors in submarine volcanic successions:
  182. Some examples from Australia: ECONOMIC GEOLOGY, v. 96, p.
  183. 913–938.
  184. Meares, R.M.D., Hutton, M.J., and Komyshan, P., 1981, The Mount Lyell
  185. Mining and Railway Company Limited Exploration License 9/66, Tasmania,
  186. Annual Report: Mineral Resources Tasmania Open File Report, 40 p.
  187. Miller, C., Halley, S., Green, G., and Jones, M., 2001, Discovery of the West
  188. 45 volcanic-hosted massive sulfide deposit using oxygen isotopes and REE
  189. geochemistry: ECONOMIC GEOLOGY, v. 96, p. 1227–1238.
  190. Offler, R., and Whitford, D.J., 1992, Wall-rock alteration and metamorphism
  191. of a volcanic-hosted massive sulfide deposit at Que River, Tasmania: Petrology
  192. and mineralogy: ECONOMIC GEOLOGY, v. 87, p. 686–705.
  193. Norrish, K., and Chappell, B.W., 1977, X-ray fluorescence spectrometry, in
  194. Zussman, J., ed., Physical methods in determinative mineralogy, 2nd ed.:
  195. London, Academic Press, p. 201–272.
  196. Placer Dome Inc., 2003, Placer Dome Gold 2003 Annual Report: Vancouver,
  197. British Columbia, Placer Dome Inc., 92 p.
  198. Rye, R.O., Bethke, P.M., and Wasserman, M.D., 1992, The stable isotope
  199. geochemistry of acid sulfate alteration: ECONOMIC GEOLOGY, v. 87, p.
  200. 225–262.
  201. Sheppard, S.M.F., Nielson, R.L., and Taylor, H.P., Jr., 1969, Oxygen and hydrogen
  202. isotope ratios of clay minerals from porphyry copper deposits: ECONOMIC
  203. GEOLOGY, v. 64, p. 755–777.
  204. Sillitoe, R.H., Hannington, M.D., and Thompson, J.F.H., 1996, High sulfidation
  205. deposits in the volcanogenic massive sulfide environment: ECONOMIC
  206. GEOLOGY, v. 91, p. 204–212.
  207. Solomon, M., Eastoe, C.J., Walshe, J.L., and Green, G.R., 1988, Mineral deposits
  208. and sulfur isotope abundances in the Mount Read Volcanics between
  209. Que River and Mount Darwin, Tasmania: ECONOMIC GEOLOGY, v. 83, p.
  210. 1307–1328.
  211. Veizer, J., and Hoefs, J., 1976, The nature of O18/O16 and C13/C12 secular
  212. trends in sedimentary carbonate rocks: Geochimica et Cosmochimica Acta,
  213. v. 40, p. 1387–1395.
  214. Vennemann, T.W., Muntean, J.L., Kesler, S.E., O’Neil, J.R., Valley, J.W., and
  215. Russell, N., 1993, Stable isotope evidence for magmatic fluids in the
  216. Pueblo Viejo epithermal acid sulfate Au-Ag deposit, Dominican Republic:
  217. ECONOMIC GEOLOGY, v. 88, p. 55–71.
  218. White, M.J., and McPhie, J., 1996, Stratigraphy and palaeovolcanology of the
  219. Cambrian Tyndall Group, Mt. Read Volcanics, western Tasmania: Australian
  220. Journal of Earth Sciences, v. 43, p. 147–159.
  221. White, N.C., and Hedenquist, J.W., 1990, Epithermal environments and
  222. styles of mineralization: Variation and their causes, and guidelines for exploration:
  223. Journal of Geochemical Exploration, v. 36, p. 445–474.
  224. Whitford, D.J., Crawford, A.J., Korsch, M.J., and Craven, S.J., 1990, Strontium
  225. and neodymium isotopic studies of the Mount Read Volcanics, Tasmania
  226. [abs.]: Geological Society of Australia Abstracts, v. 25, p. 215–216.
  227. Whitford, D.J., Korsch, M.J., and Solomon, M., 1992, Strontium isotope
  228. studies of barites: Implications for the origin of base metal mineralization
  229. in Tasmania: ECONOMIC GEOLOGY, v. 87, p. 953–959.
  230. Zheng, Y.-F., 1993, Calculation of oxygen-isotope fractionation in hydroxylbearing
  231. silicates: Earth and Planetary Science Letters, v. 120, p. 247–263.
  232. Zheng, Y.-F., and Hoefs, J., 1993, Carbon and oxygen isotopic covariations in
  233. hydrothermal calcites: Mineralium Deposita, v. 28, p. 79–89." name="eprints.referencetext" />
  234. <meta content="Williams, N.C. and Davidson, G.J. (2004) Possible submarine advanced argillic alteration at the Basin Lake prospect, Western Tasmania, Australia. Economic Geology, 99 (5). pp. 987-1002. ISSN 0361-0128" name="eprints.citation" />
  235. <meta content="http://eprints.utas.edu.au/2056/1/Williams.Davidson.ECONGEOL.2004.pdf" name="eprints.document_url" />
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  237. <meta content="Possible submarine advanced argillic alteration at the Basin Lake prospect, Western Tasmania, Australia" name="DC.title" />
  238. <meta content="Williams, N.C." name="DC.creator" />
  239. <meta content="Davidson, G.J." name="DC.creator" />
  240. <meta content="260100 Geology" name="DC.subject" />
  241. <meta content="The Basin Lake copper-gold prospect lies in western Tasmania’s Mount Read Volcanics and is hosted in a series
  242. of calc-alkaline andesites, quartz-feldspar porphyries, mudstones, carbonates, and sandstones between the
  243. Tyndall Group and the Central Volcanic Complex. Alteration at the Basin Lake prospect occurs over a strike
  244. length of 1.4 km and includes thin, strata-bound pyrophyllite-quartz-paragonite-kaolinite-pyrite-alunite alteration
  245. zones, up to 12 m wide and containing up to 50 wt percent pyrophyllite, with local fluorite veining. These
  246. zones grade out to paragonite-muscovite-kaolinite-quartz-pyrite and muscovite-carbonate-chlorite alteration
  247. zones. Extensive propylitic alteration (chlorite-carbonate-epidote) affects most other rocks outside these zones.
  248. Mineralization consists of thin strata-bound zones of massive and vein pyrite, tennantite, and chalcopyrite,
  249. with trace covellite and galena, hosted mainly within an intensely silicified core of the pyrophyllite-quartzsericite
  250. alteration zone. Pyrite has δ34S values of –1.4 to +6.9 per mil, although marginal vein pyrite in the
  251. propylitic zone has δ34S values around 12.4 per mil. Large silicified glacial erratic boulders at surface contain
  252. massive and vein pyrite, enargite, and tennantite, with minor barite, and trace covellite, stannoidite, and mawsonite.
  253. Pyrite and enargite have δ34S values of 1.7 to 6.8 per mil; barite has δ34S values around 35.2 per mil with
  254. 87Sr/86Sr around 0.7108.
  255. The alteration and mineralization at the Basin Lake prospect is similar to that associated with high-sulfidation
  256. copper-gold systems formed by acidic, relatively oxidized fluids. A new geochemical vector, here termed the
  257. “advanced argillic alteration index” [AAAI = 100 (SiO2)/(SiO2 + 10MgO + 10CaO + 10Na2O)], has been devised
  258. to help quantify the intensity of alteration. The values of the AAAI at Basin Lake are similar to those of
  259. several high-sulfidation epithermal deposits. The low sulfide δ34S values are similar to those at other sulfide occurrences
  260. in the Mount Read Volcanics that have previously been considered to be barren, are lower than those
  261. of nearby volcanic-hosted massive sulfide deposits, and may indicate a magmatic fluid component. However,
  262. the δ34S and 87Sr/86Sr values of Basin Lake barite at the assumed highest exposed level of the system and higher
  263. δ34S values in pyrite from marginal veins are similar to those of Cambrian volcanic-hosted massive sulfide systems,
  264. indicating the involvement of reduced seawater sulfate at these locations. Calcite carbon and oxygen isotope
  265. values, silicate oxygen isotope values, and the unusual abundance of carbonate close to advanced argillic
  266. alteration indicate fluid mixing and suggest that acidic, magmatic fluids were likely neutralized by seawater.
  267. This occurrence strengthens the case for prospecting the Mount Read Volcanics and other similar submarine
  268. volcanic belts for copper-gold and gold-only deposits that formed by the actions of hyperacid oxidized fluids." name="DC.description" />
  269. <meta content="2004-08" name="DC.date" />
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  380. <h1 class="ep_tm_pagetitle">Possible submarine advanced argillic alteration at the Basin Lake prospect, Western Tasmania, Australia</h1>
  381. <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Williams, N.C.</span> and <span class="person_name">Davidson, G.J.</span> (2004) <xhtml:em>Possible submarine advanced argillic alteration at the Basin Lake prospect, Western Tasmania, Australia.</xhtml:em> Economic Geology, 99 (5). pp. 987-1002. ISSN 0361-0128</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2056/1/Williams.Davidson.ECONGEOL.2004.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2056/1/Williams.Davidson.ECONGEOL.2004.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />583Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input accept-charset="utf-8" value="2595" name="docid" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.2113/99.5.987">http://dx.doi.org/10.2113/99.5.987</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">The Basin Lake copper-gold prospect lies in western Tasmania’s Mount Read Volcanics and is hosted in a series&#13;
  382. of calc-alkaline andesites, quartz-feldspar porphyries, mudstones, carbonates, and sandstones between the&#13;
  383. Tyndall Group and the Central Volcanic Complex. Alteration at the Basin Lake prospect occurs over a strike&#13;
  384. length of 1.4 km and includes thin, strata-bound pyrophyllite-quartz-paragonite-kaolinite-pyrite-alunite alteration&#13;
  385. zones, up to 12 m wide and containing up to 50 wt percent pyrophyllite, with local fluorite veining. These&#13;
  386. zones grade out to paragonite-muscovite-kaolinite-quartz-pyrite and muscovite-carbonate-chlorite alteration&#13;
  387. zones. Extensive propylitic alteration (chlorite-carbonate-epidote) affects most other rocks outside these zones.&#13;
  388. Mineralization consists of thin strata-bound zones of massive and vein pyrite, tennantite, and chalcopyrite,&#13;
  389. with trace covellite and galena, hosted mainly within an intensely silicified core of the pyrophyllite-quartzsericite&#13;
  390. alteration zone. Pyrite has δ34S values of –1.4 to +6.9 per mil, although marginal vein pyrite in the&#13;
  391. propylitic zone has δ34S values around 12.4 per mil. Large silicified glacial erratic boulders at surface contain&#13;
  392. massive and vein pyrite, enargite, and tennantite, with minor barite, and trace covellite, stannoidite, and mawsonite.&#13;
  393. Pyrite and enargite have δ34S values of 1.7 to 6.8 per mil; barite has δ34S values around 35.2 per mil with&#13;
  394. 87Sr/86Sr around 0.7108.&#13;
  395. The alteration and mineralization at the Basin Lake prospect is similar to that associated with high-sulfidation&#13;
  396. copper-gold systems formed by acidic, relatively oxidized fluids. A new geochemical vector, here termed the&#13;
  397. “advanced argillic alteration index” [AAAI = 100 (SiO2)/(SiO2 + 10MgO + 10CaO + 10Na2O)], has been devised&#13;
  398. to help quantify the intensity of alteration. The values of the AAAI at Basin Lake are similar to those of&#13;
  399. several high-sulfidation epithermal deposits. The low sulfide δ34S values are similar to those at other sulfide occurrences&#13;
  400. in the Mount Read Volcanics that have previously been considered to be barren, are lower than those&#13;
  401. of nearby volcanic-hosted massive sulfide deposits, and may indicate a magmatic fluid component. However,&#13;
  402. the δ34S and 87Sr/86Sr values of Basin Lake barite at the assumed highest exposed level of the system and higher&#13;
  403. δ34S values in pyrite from marginal veins are similar to those of Cambrian volcanic-hosted massive sulfide systems,&#13;
  404. indicating the involvement of reduced seawater sulfate at these locations. Calcite carbon and oxygen isotope&#13;
  405. values, silicate oxygen isotope values, and the unusual abundance of carbonate close to advanced argillic&#13;
  406. alteration indicate fluid mixing and suggest that acidic, magmatic fluids were likely neutralized by seawater.&#13;
  407. This occurrence strengthens the case for prospecting the Mount Read Volcanics and other similar submarine&#13;
  408. volcanic belts for copper-gold and gold-only deposits that formed by the actions of hyperacid oxidized fluids.</p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Keywords:</th><td valign="top" class="ep_row">stable isotopes, acid alteration,volcanic massive sulfides,&#13;
  409. Mt Read Volcanic Belt, Cambrian, enargite, silica replacement, copper, gold, barite</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/260100.html">260000 Earth Sciences &gt; 260100 Geology</a></td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2056</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Mrs Katrina Keep</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">10 Oct 2007 04:01</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">09 Jan 2008 02:30</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2056;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&amp;eprintid=2056">item control page</a></p>
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