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    <title>UTas ePrints - Co-ordination Chemistry of Dimethylgold(III). Synthesis, Spectroscopic, and Structural Studies of Complexes with Neutral Aromatic Nitrogen-donor Ligands</title>
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    <meta content="Canty, A.J." name="eprints.creators_name" />
<meta content="Minchin, N.J." name="eprints.creators_name" />
<meta content="Healy, P.C." name="eprints.creators_name" />
<meta content="White, A.H." name="eprints.creators_name" />
<meta content="allan.canty@utas.edu.au" name="eprints.creators_id" />
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<meta content="2008-01-04 03:26:42" name="eprints.datestamp" />
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<meta content="Co-ordination Chemistry of Dimethylgold(III). Synthesis,
Spectroscopic, and Structural Studies of Complexes with Neutral Aromatic Nitrogen-donor Ligands" name="eprints.title" />
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<meta content="Dimethylgold(III) nitrate reacts with neutral ligands to form the complexes [AuMe2(tpm)]N03.2H20 (tpm = tri-2-pyridylmethane) and [AuMe2L]N03 [L = tri-2-pyridylmethanol (tpmo), di-2-pyridylmethane (dpm), alpha, alpha-di-2-pyridyltoluene (dpt), di-1-pyrazolylmethane (dpzm), and
tri-1-pyrazolylmethane (tpzm)]. The crystal structures of complexes of tpzm, tpm, and dpt have been determined by single-crystal X-ray diffraction at 295 K and refined by least-squares methods to R = 0.033, 0.029, and 0.042 for 3043, 1616, and 2529 independent 'observed' reflections,
respectively. In these structures the [AuMe2L]+ cations have essentially cis-square-planar co-ordination for gold(III), AuC2N2, with Au-C 2.023(7)-2.041(12) A and Au-N
2.127(8)-2.142(8) A. In complexes of the potential tridentate ligands one pyridyl group is not co-ordinated in the tpm complex, and one pyrazolyl group is involved in a weak axial Au...N interaction [3.139(7) A] in the tpzm complex. Comparison of the 1H n.m.r. spectra of complexes of the potentially tridentate ligands (tpzm, tpm, and tpmo) with model complexes of bidentate ligands (dpzm, dpm, and dpt) suggests that the co-ordination behaviour of the ligands in methanol resembles that found in the solid state." name="eprints.abstract" />
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<meta content="Canty, A.J. and Minchin, N.J. and Healy, P.C. and White, A.H. (1982) Co-ordination Chemistry of Dimethylgold(III). Synthesis, Spectroscopic, and Structural Studies of Complexes with Neutral Aromatic Nitrogen-donor Ligands. Journal of the Chemical Society, Dalton Transactions . pp. 1795-1802. ISSN 1477-9226" name="eprints.citation" />
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<meta content="Minchin, N.J." name="DC.creator" />
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<meta content="Dimethylgold(III) nitrate reacts with neutral ligands to form the complexes [AuMe2(tpm)]N03.2H20 (tpm = tri-2-pyridylmethane) and [AuMe2L]N03 [L = tri-2-pyridylmethanol (tpmo), di-2-pyridylmethane (dpm), alpha, alpha-di-2-pyridyltoluene (dpt), di-1-pyrazolylmethane (dpzm), and
tri-1-pyrazolylmethane (tpzm)]. The crystal structures of complexes of tpzm, tpm, and dpt have been determined by single-crystal X-ray diffraction at 295 K and refined by least-squares methods to R = 0.033, 0.029, and 0.042 for 3043, 1616, and 2529 independent 'observed' reflections,
respectively. In these structures the [AuMe2L]+ cations have essentially cis-square-planar co-ordination for gold(III), AuC2N2, with Au-C 2.023(7)-2.041(12) A and Au-N
2.127(8)-2.142(8) A. In complexes of the potential tridentate ligands one pyridyl group is not co-ordinated in the tpm complex, and one pyrazolyl group is involved in a weak axial Au...N interaction [3.139(7) A] in the tpzm complex. Comparison of the 1H n.m.r. spectra of complexes of the potentially tridentate ligands (tpzm, tpm, and tpmo) with model complexes of bidentate ligands (dpzm, dpm, and dpt) suggests that the co-ordination behaviour of the ligands in methanol resembles that found in the solid state." name="DC.description" />
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    <h1 class="ep_tm_pagetitle">Co-ordination Chemistry of Dimethylgold(III). Synthesis, Spectroscopic, and Structural Studies of Complexes with Neutral Aromatic Nitrogen-donor Ligands</h1>
    <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Canty, A.J.</span> and <span class="person_name">Minchin, N.J.</span> and <span class="person_name">Healy, P.C.</span> and <span class="person_name">White, A.H.</span> (1982) <xhtml:em>Co-ordination Chemistry of Dimethylgold(III). Synthesis, Spectroscopic, and Structural Studies of Complexes with Neutral Aromatic Nitrogen-donor Ligands.</xhtml:em> Journal of the Chemical Society, Dalton Transactions . pp. 1795-1802. ISSN 1477-9226</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2849/1/Dalton1982_2C_1795.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2849/1/Dalton1982_2C_1795.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />840Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input accept-charset="utf-8" value="3848" name="docid" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://www.rsc.org/Publishing/Journals/">http://www.rsc.org/Publishing/Journals/</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">Dimethylgold(III) nitrate reacts with neutral ligands to form the complexes [AuMe2(tpm)]N03.2H20 (tpm = tri-2-pyridylmethane) and [AuMe2L]N03 [L = tri-2-pyridylmethanol (tpmo), di-2-pyridylmethane (dpm), alpha, alpha-di-2-pyridyltoluene (dpt), di-1-pyrazolylmethane (dpzm), and&#13;
tri-1-pyrazolylmethane (tpzm)]. The crystal structures of complexes of tpzm, tpm, and dpt have been determined by single-crystal X-ray diffraction at 295 K and refined by least-squares methods to R = 0.033, 0.029, and 0.042 for 3043, 1616, and 2529 independent 'observed' reflections,&#13;
respectively. In these structures the [AuMe2L]+ cations have essentially cis-square-planar co-ordination for gold(III), AuC2N2, with Au-C 2.023(7)-2.041(12) A and Au-N&#13;
2.127(8)-2.142(8) A. In complexes of the potential tridentate ligands one pyridyl group is not co-ordinated in the tpm complex, and one pyrazolyl group is involved in a weak axial Au...N interaction [3.139(7) A] in the tpzm complex. Comparison of the 1H n.m.r. spectra of complexes of the potentially tridentate ligands (tpzm, tpm, and tpmo) with model complexes of bidentate ligands (dpzm, dpm, and dpt) suggests that the co-ordination behaviour of the ligands in methanol resembles that found in the solid state.</p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/259901.html">250000 Chemical Sciences &gt; 259900 Other Chemical Sciences &gt; 259901 Organometallic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2849</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">04 Jan 2008 14:26</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">09 Jan 2008 02:30</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2849;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&amp;eprintid=2849">item control page</a></p>
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