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<meta content="Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(p-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy=2,2'-bipyridine)" name="eprints.title" />
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<meta content="Organoplatinum; 2,2-Bipyridine; Diethylsulfide; Crystal structures" name="eprints.keywords" />
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<meta content="The complex trans-PtCl(p-Tol)(SEt2)2 is obtained from the reaction of [Pt(p-Tol)2(SEt2)]2 with PtCl2(SEt2)2 and SEt2 in mole ratio 1:2:2. The mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide react with 2,2'-bipyridine to form the complexes PtX(p-Tol)(bpy) (X=p-Tol, Cl) and are useful reagents for organoplatinum chemistry. X-ray crystal structures are presented for square planar PtCl(p-Tol)(bpy) and the centrosymmetric dimer [Pt(p-Tol)2(mu-SEt2)]2." name="eprints.abstract" />
<meta content="2002" name="eprints.date" />
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<meta content="Inorganica Chimica Acta" name="eprints.publication" />
<meta content="327" name="eprints.volume" />
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<meta content="15-19" name="eprints.pagerange" />
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<meta content="Casado Lacabra, M.A. and Canty, A.J. and Lutz, M. and Patel, J. and Spek, A.L. and Sun, H. and van Koten, G. (2002) Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(p-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy=2,2'-bipyridine). Inorganica Chimica Acta, 327 (1). pp. 15-19. ISSN 0020-1693" name="eprints.citation" />
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<h1 class="ep_tm_pagetitle">Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(p-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy=2,2'-bipyridine)</h1>
<p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Casado Lacabra, M.A.</span> and <span class="person_name">Canty, A.J.</span> and <span class="person_name">Lutz, M.</span> and <span class="person_name">Patel, J.</span> and <span class="person_name">Spek, A.L.</span> and <span class="person_name">Sun, H.</span> and <span class="person_name">van Koten, G.</span> (2002) <xhtml:em>Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(p-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy=2,2'-bipyridine).</xhtml:em> Inorganica Chimica Acta, 327 (1). pp. 15-19. ISSN 0020-1693</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2793/1/ICA327_2C_15.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2793/1/ICA327_2C_15.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />128Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input accept-charset="utf-8" value="3821" name="docid" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1016/S0020-1693(01)00681-8">http://dx.doi.org/10.1016/S0020-1693(01)00681-8</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">The complex trans-PtCl(p-Tol)(SEt2)2 is obtained from the reaction of [Pt(p-Tol)2(SEt2)]2 with PtCl2(SEt2)2 and SEt2 in mole ratio 1:2:2. The mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide react with 2,2'-bipyridine to form the complexes PtX(p-Tol)(bpy) (X=p-Tol, Cl) and are useful reagents for organoplatinum chemistry. X-ray crystal structures are presented for square planar PtCl(p-Tol)(bpy) and the centrosymmetric dimer [Pt(p-Tol)2(mu-SEt2)]2.</p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Additional Information:</th><td valign="top" class="ep_row">The definitive version is available at http://www.sciencedirect.com
</td></tr><tr><th valign="top" class="ep_row">Keywords:</th><td valign="top" class="ep_row">Organoplatinum; 2,2-Bipyridine; Diethylsulfide; Crystal structures</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/259901.html">250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2793</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">04 Jan 2008 09:19</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">09 Jan 2008 02:30</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2793;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=2793">item control page</a></p>
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